Dynamical mean-field theory for bosons

We discuss the recently developed bosonic dynamical mean-field (B-DMFT) framework, which maps a bosonic lattice model onto the selfconsistent solution of a bosonic impurity model with coupling to a reservoir of normal and condensed bosons. The effective impurity action is derived in several ways: (i) as an approximation to the kinetic energy functional of the lattice problem, (ii) using a cavity approach, and (iii) by using an effective medium approach based on adding a one-loop correction to the selfconsistently defined condensate. To solve the impurity problem, we use a continuous-time Monte Carlo algorithm based on a sampling of a perturbation expansion in the hybridization functions and the condensate wave function. As applications of the formalism we present finite temperature B-DMFT phase diagrams for the bosonic Hubbard model on a 3d cubic and 2d square lattice, the condensate order parameter as a function of chemical potential, critical exponents for the condensate, the approach to the weakly interacting Bose gas regime for weak repulsions, and the kinetic energy as a function of temperature.Comment: 26 pages, 19 figure

Non-perturbative renormalization-group approach to zero-temperature Bose systems

We use a non-perturbative renormalization-group technique to study interacting bosons at zero temperature. Our approach reveals the instability of the Bogoliubov fixed point when $d\leq 3$ and yields the exact infrared behavior in all dimensions $d>1$ within a rather simple theoretical framework. It also enables to compute the low-energy properties in terms of the parameters of a microscopic model. In one-dimension and for not too strong interactions, it yields a good picture of the Luttinger-liquid behavior of the superfluid phase.Comment: v1) 6 pages, 8 figures; v2) added references; v3) corrected typo

Phase separation of Bose-Einstein condensates

The zero-temperature system of two dilute overlapping Bose-Einstein condensates is unstable against long wavelength excitations if the interaction strength between the distinguishable bosons exceeds the geometric mean of the like-boson interaction strengths. If the condensates attract each other, the instability is similar to the instability of the negative scattering length condensates. If the condensates repel, they separate spatially into condensates of equal pressure. We estimate the boundary size, surface tension and energy of the phase separated condensate system and we discuss the implications for double condensates in atomic traps.Comment: 11 pages, 1 figur

Theory of Bose-Einstein condensation for trapped atoms

We outline the general features of the conventional mean-field theory for the description of Bose-Einstein condensates at near zero temperatures. This approach, based on a phenomenological model, appears to give excellent agreement with experimental data. We argue, however, that such an approach is not rigorous and cannot contain the full effect of collisional dynamics due to the presence of the mean-field. We thus discuss an alternative microscopic approach and explain, within our new formalism, the physical origin of these effects. Furthermore, we discuss the potential formulation of a consistent finite-temperature mean-field theory, which we claim necessiates an analysis beyond the conventional treatment.Comment: 12 pages. To appear in Phil. Trans. R. Soc. Lond. A 355 (1997

Ground state at high density

Weak limits as the density tends to infinity of classical ground states of integrable pair potentials are shown to minimize the mean-field energy functional. By studying the latter we derive global properties of high-density ground state configurations in bounded domains and in infinite space. Our main result is a theorem stating that for interactions having a strictly positive Fourier transform the distribution of particles tends to be uniform as the density increases, while high-density ground states show some pattern if the Fourier transform is partially negative. The latter confirms the conclusion of earlier studies by Vlasov (1945), Kirzhnits and Nepomnyashchii (1971), and Likos et al. (2007). Other results include the proof that there is no Bravais lattice among high-density ground states of interactions whose Fourier transform has a negative part and the potential diverges or has a cusp at zero. We also show that in the ground state configurations of the penetrable sphere model particles are superposed on the sites of a close-packed lattice.Comment: Note adde

Influence of the Aggregation of a Carbazole Thiophene Cyanoacrylate Sensitizer on Sensitized Photocurrents on ZnO Single Crystals

Dye sensitization of zinc oxide single crystals by a carbazole thiophene cyanoacrylate (MK-2) sensitizer deposited from THF and mixtures of THF and water was investigated. AFM images show the formation of larger aggregates, with the maximum size of 20–30 nm from mixtures of THF and water, compared with 8–12 nm from pure THF. Sensitized photocurrent spectra were correlated with the morphological results from AFM imaging and indicate that aggregation in water results in less efficient sensitization of the ZnO substrate. The presence of the aggregation in solution due to water content was confirmed by absorbance and fluorescence spectroscopies