2 research outputs found
Aqueous-Phase Secondary Organic Aerosol and Organosulfate Formation in Atmospheric Aerosols: A Modeling Study
We have examined aqueous-phase secondary organic aerosol
(SOA)
and organosulfate (OS) formation in atmospheric aerosols using a photochemical
box model with coupled gas-phase chemistry and detailed aqueous aerosol
chemistry. SOA formation in deliquesced ammonium sulfate aerosol is
highest under low-NO<i><sub>x</sub></i> conditions, with
acidic aerosol (pH = 1) and low ambient relative humidity (40%). Under
these conditions, with an initial sulfate loading of 4.0 μg
m<sup>–3</sup>, 0.9 μg m<sup>–3</sup> SOA is predicted
after 12 h. Low-NO<i><sub>x</sub></i> aqueous-aerosol SOA
(aaSOA) and OS formation is dominated by isoprene-derived epoxydiol
(IEPOX) pathways; 69% or more of aaSOA is composed of IEPOX, 2-methyltetrol,
and 2-methyltetrol sulfate ester. 2-Methyltetrol sulfate ester comprises
>99% of OS mass (66 ng m<sup>–3</sup> at 40% RH and pH 1).
In urban (high-NO<sub><i>x</i></sub>) environments, aaSOA
is primarily formed via reversible glyoxal uptake, with 0.12 μg
m<sup>–3</sup> formed after 12 h at 80% RH, with 20 μg
m<sup>–3</sup> initial sulfate. OS formation under all conditions
studied is maximum at low pH and lower relative humidities (<60%
RH), i.e., when the aerosol is more concentrated. Therefore, OS species
are expected to be good tracer compounds for aqueous aerosol-phase
chemistry (vs cloudwater processing)