Effect of autogenous GTAW on the reciprocating sliding wear behavior of a carbon martensitic steel

Martensitic steels have been successfully employed in resource-based industries where components must endure aggressive conditions. In industrial practice, many parts of these components are joined by welding techniques. The aim of this work was to understand the influence of welding on the wear resistance of quenched and tempered carbon martensitic steel subjected to dry linear reciprocating sliding micro-wear tests. Weld-joints were produced using autogenous Gas Tungsten Arc Welding process (GTAW). Micro-wear tests were performed at base metal (BM), weld metal (WM), coarse grained heat affected zone (CG-HAZ) and lowest hardness region of heat affected zone (LHR-HAZ). LHR-HAZ was softened during welding process so plastic deformation was facilitated, and consequently adhesion, material displacement and micro-ploughing. WM and CG-HAZ presented a similar martensitic structure, which explain the similarities found on wear behavior. These regions presented the lowest worn volume average values (w). It was interesting to note that despite its highestmicrohardness value, the highest wwas observed for BM. For some BM samples, debris had a key role promoting material loss by micro-cutting which causes great extent of material removal compared to other micro-wear mechanisms as micro-ploughing and adhesion. Due to debris action BM also presented a great dispersion in wresults. The results suggest that material loss of welded joint and BM was strongly controlled by micro-wear mechanisms

Optimizing the selective precipitation of iron to produce yellow pigment from acid mine drainage

Acid mine drainage (AMD) in the coal mining industry is recognized as one of the major sources of environmental damage. The active treatment of AMD involves adding alkaline reagents to wastewater so as to raise pH and to precipitate dissolved metals in the form of oxides/hydroxides. Studies have shown that yellow pigment (goethite) can be produced from the iron present in AMD. However, the presence of other metals can prevent the formation of pigment. Therefore, this paper seeks to evaluate several processes for purifying iron sludge so as to obtain raw material that can be recovered from AMD and thereby obtain a good quality of yellow pigment. The experiments were carried out by causing precipitation with strong and weak bases and removing other metals from the sludge by washing and filtering the sludge or by centrifugation. The results show that the color, type and morphology of the compounds changed, depending on the number of contaminants, and that these factors are strongly dependent on the type of reagent and less dependent on the separation process and the repetition of washes.Peer ReviewedPostprint (author's final draft

Microestrutura e Propriedades de Desgaste do Aço Bainítico de Resfriamento Contínuo DIN 18MnCrSiMo6-4 Nitretado a Plasma em Diferentes Temperaturas

Os novos aços bainíticos de resfriamento contínuo (CCBS) são uma excelente alternativa quando se requer elevada dureza, tenacidade e resistência à fadiga. Contudo, estima-se que a taxa de desgaste dos CCBS seja insuficiente para aplicação em componentes com alta solicitação mecânica, sendo necessário aprimorar suas propriedades de superfície. O objetivo deste estudo é o de analisar os efeitos da nitretação a plasma sobre à microestrutura e propriedades de desgaste do aço bainítico de resfriamento contínuo DIN18MnCrSiMo6-4. Portanto, tratamentos com duração de 6 horas foram conduzidos com pressão de 3 mbar, mistura gasosa composta por 76% N2 + 24% H2, e temperaturas de 400, 450, 500 e 550 °C, respectivamente. As amostras foram analisadas através de microscopia eletrônica de varredura, difração de raios-X, microdureza e ensaios de desgaste por deslizamento recíproco. Nas condições investigadas, foi possível obter uma camada de compostos e atingir um aumento de até 393% na dureza superficial, entretanto, o uso de temperaturas mais elevadas durante os tratamentos favoreceu a formação de camadas mais profundas. Em todas as amostras nitretadas, constatou-se a formação predominante da fase de nitretos ε-Fe2-3N e, em menor quantidade, da fase de nitretos γ’-Fe4N. Nos ensaios de deslizamento recíproco houve diminuição do desgaste das amostras nitretadas na temperatura de 550°C. Palavras-chave: Aços Bainíticos de Resfriamento Contínuo, Nitretação a Plasma, Microestrutura e Propriedades de Desgaste

Estudo da corrosao do aco ABNT 1010 em alcool etilico adicionado de inibidores

Estudou-se o comportamento do aço AISI 1010 em AISI 1010 em àlcool etílico puro com 3,5% H20 e diferentes aditivos (acetato de sódio, um aditivo comercial e trietanolamina) em meio arejado e desarejado, com e sem agitação. Os resultados experimentais mostram que os aditivos usados exercem efeito inibidor da corrosão no aço. A água (3,5%) origina um período de incubação até o aparecimento de pite. A reação de redução catódica do oxigênio apresenta duas ondas, o que permite dizer que a presença de algum filme modifica a mesma. Os ensaios em etanol carburante, a longo prazo, apresentaram corrosão localizada em meio arejado (a qual é evitada com adição de 10-² M de acetato de sódio), e corrosão generalizada em meio desarejado.The behavior of the steel AIS1 1010 in deaerated and aerated pure ethyl alcoohol with 3,5% H2O and several additives (sodium acetate, a commercial additive and triethanolamine) has been studied. The experimentals results showed that the used additives play an inhibitory effect with relation to corrosion of the steel. The presence of the water gives place to an incubation period until the appearance of pitting. A cathodic reduction reaction of the oxygen shows two waves, wich allows one to say the same film modifies it. The tests in comercial ethanol, in the long range, presents localized corrosion in aerated medium (wich could be avoided with the addition of 10-² M of sodium acetate) and a generalized corrosion in deaerated medium

Avaliação eletroquímica do Al 7075 em soluções contaminadas com microrganismos isolados de combustíveis

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Estudo eletroquímico de cobre em água : influência de componentes orgânicos

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Corrosão do latão em água de mar

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Corrosão de um aço-carbono em óleo diesel

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