2 research outputs found
Microscopic Movement of Slow-Diffusing Nanoparticles in Cylindrical Nanopores Studied with Three-Dimensional Tracking
To study slow mass transport in confined
environments, we developed
a three-dimensional (3D) single-particle localization technique to
track their microscopic movements in cylindrical nanopores. Under
two model conditions, particles are retained much longer inside the
pores: (1) increased solvent viscosity, which slows down the particle
throughout the whole pore, and (2) increased pore wall affinity, which
slows down the particle only at the wall. In viscous solvents, the
particle steps decrease proportionally to the increment of the viscosity,
leading to macroscopically slow diffusion. As a contrast, the particles
in sticky pores are microscopically active by showing limited reduction
of step sizes. A restricted diffusion mode, possibly caused by the
heterogeneous environment in sticky pores, is the main reason for
macroscopically slow diffusion. This study shows that it is possible
to differentiate slow diffusion in confined environments caused by
different mechanisms
Harnessing Hot Electrons from Near IR Light for Hydrogen Production Using Pt-End-Capped-AuNRs
Gold
nanorods show great potential in harvesting natural sunlight and generating
hot charge carriers that can be employed to produce electrical or
chemical energies. We show that photochemical reduction of PtÂ(IV)
to Pt metal mainly takes place at the ends of gold nanorods (AuNRs),
suggesting photon-induced hot electrons are localized in a time-averaged
manner at AuNR ends. To use these hot electrons efficiently, a novel
synthetic method to selectively overgrow Pt at the ends of AuNRs has
been developed. These Pt-end-capped AuNRs show relatively high activity
for the production of hydrogen gas using artificial white light, natural
sunlight, and more importantly, near IR light at 976 nm. Tuning of
the surface plasmon resonance (SPR) wavelength of AuNRs changes the
hydrogen gas production rate, indicating that SPR is involved in hot
electron generation and photoreduction of hydrogen ions. This study
shows that gold nanorods are excellent for converting low-energy photons
into high-energy hot electrons, which can be used to drive chemical
reactions at their surfaces