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Multifunctional Compound Combining Conductivity and Single-Molecule Magnetism in the Same Temperature Range
No full textWe report the first
highly conducting single-molecule magnet, (BEDO)<sub>4</sub>[ReF<sub>6</sub>]·6H<sub>2</sub>O [<b>1</b>; BEDO = bis(ethylenedioxo)tetrathiafulvalene],
whose conductivity and single-molecule magnetism coexist in the same
temperature range. The compound was synthesized by BEDO electrocrystallization
in the presence of (Ph<sub>4</sub>P)<sub>2</sub>[ReF<sub>6</sub>]·2H<sub>2</sub>O and characterized by crystallography and measurements of
the conductivity and alternating-current magnetic susceptibility
