Radiation grafted poly(vinylidene fluoride)-graftpolystyrene sulfonic acid membranes for fuel cells: Structure-property relationships

Structure-property relationships for poly(vinylidene fluoride)-graft-polystyrene sulfonic acid (PVDF-g-PSSA) fuel cell membranes prepared by a single step method involving radiation-induced grafting of sodium styrene sulfonate (SSS) onto electron beam (EB) irradiated poly(vinylidene fluoride) (PVDF) films were established. The physico-chemical properties of the membranes such as ion exchange capacity, water swelling and proton conductivity were correlated with the degree of grafting (G, %) and the structural changes taking place in the membrane matrix during the preparation procedure. The variation in the crystallinity and the thermal stability of membranes was studied by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. The membranes were found to undergo substantial structural changes in forms of ionic sites increase, hydrophilicity enhancement, hydrophobicity reduction and crystallinity decrease with the variation in G (%) and the preparation method. The structural and thermal properties of the obtained membranes were also compared with their counterparts prepared by a conventional two-steps method i.e. radiation induced grafting of styrene onto EB irradiated PVDF films followed by sulfonation. The PVDF-g-PSSA membranes obtained by a single-step method were found to have superior properties compared to those obtained by the conventional two-steps method

Preparation of composite polymer electrolytes by electron beam-induced grafting : proton and lithium ion-conducting membranes

Two classes of composite polymer electrolyte membranes, one conducting lithium ions (Li+) and the other conducting protons (H+) were prepared using simultaneous electron beam-induced grafting. Porous poly(vinylidene fluoride) (PVDF) films were impregnated with styrene and subjected to electron beam (EB) irradiation to obtain polystyrene (PS) filled PVDF precursor films that were subsequently treated with either chlorosulfonic acid/1,1,2,2-tetrachloroethane mixture to obtain H+-conducting composite membranes or LiPH6/EC/DEC liquid electrolyte to obtain Li+-conducting composite membranes. The properties of the obtained membranes were evaluated using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and AC impedance measurements. The obtained membranes were found to achieve grafting content up to 46% with superior Li+-conductivity of 1.91 × 10-3 S/cm and H+-conductivity of 5.95 × 10-2 S/cm. The results of this work show that simultaneous radiation-induced grafting with EB is a promising method to prepare high quality ion-conducting membranes for possible use in fuel cells and lithium batteries