15 research outputs found

    Deciphering patterns of triadism in the Hindu epics

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    Religious Studies and ArabicD. Litt. et Phil. (Religious Studies

    Anti-corrosion behavior of olmesartan for soft-cast steel in 1 mol dm−3 HCL.

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    This study discusses the effects of temperature on corrosion inhibition for soft-cast steel by the pharmaceutically active drug olmesartan in 1 mol dm−3 HCl. The sufficient number of electron-rich elements and non-bonding π electrons in its structure favored a good capability for coating onto the electron-deficient steel surfaces. Theoretical and electrochemical measurements were carried out at the temperature region of 303 K to 333 K. Therefore, the experiment suggests that the inhibition efficiency of olmesartan increases with its increasing concentrations due to the adsorption. Additionally, even at a higher temperature of 333 K, the inhibitor molecules attain their stability towards corrosion resistance of steel surfaces. The adsorption of inhibitors on steel surfaces is spontaneously found to include the mixture of physisorption and chemisorption, and it obeys Temkin’s adsorption isotherm model. Theoretical and computational considerations were made using quantum chemical parameters and molecular dynamics simulations, which confirmed that the olmesartan has a suitable corrosion inhibitive capability intended for soft-cast steel in 1 mol dm−3 HCl. Additionally, scanning electron microscopic measurement was used to obtain a visual idea of the inhibitive action of the inhibitor attained by forming an adsorbed protective layer onto the steel surfaces. The minute concentration of olmesartan of about 10–50 ppm shows high inhibition efficiency of ~80%, even at elevated temperatures

    ANTICORROSION POTENTIAL OF HYDRALAZINE FOR CORROSION OF MILD STEEL IN 1M HYDROCHLORIC ACID SOLUTION

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    Anticorrosion potential of mild steel by Hydralazine as corrosion inhibitor for mild steel in 1M hydrochloric acid was investigated by chemical and electrochemical measurements at 303-333 K temperature. The maximum inhibition efficiency of inhibitor by Weight loss method is around 90%, Tafel polarization method is around 85%; electrochemical impedance spectroscopy measurement around 90% at 1250 ppm of Hydralazine in. The result shows that the inhibition efficiency increases with I 1M hydrochloric acid. Hydralazine acts as a mixed type inhibitor which inhibits the corrosion of mild steel due to the adsorption on metal surface. This adsorption system obeys the Langmuir adsorption isotherm.Activation parameters explains the effect of temperature with inhibition efficiency of inhibitor molecule.SEM images of inhibited mild steel strips shows a formation of passive protective film over the surface

    Anthranilic Acid as Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Media

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    AbstractThe inhibition effect of Anthranilic acid on corrosion of mild steel in 1M HCl solution was investigated by using traditional weight loss method, Polarization measurements and Electrochemical Impedance Spectroscopy (EIS) measurements. Small amount such as500ppm of the Inhibitor shows good inhibition efficiency. Polarisation measurements infer inhibitor acts as mixed type inhibitor. Weight loss, Polarisation and Electrochemical impedance results are gives same order of inhibition efficienc

    CORROSION INHIBITION BEHAVIOR OF KETOSULFONE FOR ZINC IN ACIDIC MEDIUM

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    The corrosion inhibition behavior of Ketosulfone for zinc is investigated by polarization and AC-impedance techniques at 303-333K. The Tafel plots indicates that the Ketosulfone is a mixed type inhibitor. The interaction between metal and inhibitor is explained by Langmuir adsorption isotherm. G0ads and H0ads value indicates the electrostatic interactions between metal and inhibitor. Calculated activation parameters explains the corrosion process. SEM images show the difference between inhibited solutions and blank solution
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