Organosulfur compounds in carbonaceous chondrites: Implications for organic reaction pathways in the meteorite parent bodies

The Tenth Symposium on Polar Science/Special session: [OA] Antarctic meteorites, Thur. 5 Dec. / 3F Multipurpose conference room, National Institute of Polar Researc

The Asuka-87 and Asuka-88 collections of Antarctic meteorites: Search, discoveries, initial processing, and preliminary identification and classification

Over 2400 pieces were collected by the Asuka wintering party of the 29th Japanese Antarctic Research Expedition (JARE-29,1987-89) on the bare icefields around the S∅r Rondane Mountains in Queen Maud Land, East Antarctica. The Asuka party searched almost all of the bare icefields around the mountains in the 1987-88 and 1988-89 field seasons. About 110 pieces (Asuka-87) of meteorites were collected on the bare ice around Mt. Balchen in the eastern part of the mountains in January and February 1988. In the first reconnaissance, about 240 pieces of meteorites (also Asuka-87) were recovered from the Nansenisen Icefield in February and March 1988. The Asuka-88 meteorites, over 2100 pieces, were found during the systematic search of this icefield during November 1988 and January 1989. The specimens were named officially the Asuka (A)-87001 to A-87352,and A-880001 to A-882124,in order of discovery. The Asuka-87 and Asuka-88 meteorite collections were filed as the National Institute of Polar Research (NIPR) meteorites with details of date of find, weight, dimensions and comments. According to the initial processing, the Asuka-87 meteorites comprise one iron, one stony-iron, 9 achondrites, 3 carbonaceous chondrites and over 300 ordinary chondrites, the total weight being 120kg. The largest specimen in the Asuka-87 collections is an LL-group chondrite of about 46kg. The Asuka-88 meteorites comprise 7 irons, 5 stony-irons, over 50 achondrites, 31 carbonaceous chondrites and over 2000 ordinary chondirtes. The total weight is about 400kg. Two specimens in the Asuka-88 collection were tentatively identified as a very coarse-grained and unbrecciated gabbroic meteorite and an olivine-fassaite-plagioclase achondrite with crystalline texture

Detection of Soluble Organic Matter in Antarctic Micrometeorites

The Tenth Symposium on Polar Science/Poster presentations: [OA] Antarctic meteorites, Wed. 4 Dec. / Entrance Hall (1st floor), National Institute of Polar Researc

Source identification of Malaysian atmospheric polycyclic aromatic hydrocarbons nearby forest fires using molecular and isotopic compositions

We report measurements of molecular and carbon isotopic compositions of Malaysian atmospheric polycyclic aromatic hydrocarbons (PAHs) in smoke haze from the 1997 Indonesian forest fire. Comparison of the carbon isotopic compositions (δ13C) of individual PAHs from the smoke haze, with those from other PAHs sources (soot collected from gasoline and diesel vehicle muffler, woodburning smoke), enables us to discriminate among the diverse sources of atmospheric PAHs. Soot PAHs extracted from gasoline and diesel vehicles show heavy isotopic signatures with a large inter-species δ13C variation from −12.9‰ to −26.6‰, compared to soot PAHs extracted from woodburning smoke which are isotopically light, and have a small inter-species δ13C variation from −26.8‰ to −31.6‰. Values from −17.7‰ to −27.9‰ were obtained for the corresponding PAHs extracted from the smoke haze, indicating that they are derived mainly from automotive exhaust. Molecular and isotopic compositions of PAHs extracted from smoke haze were similar to those extracted from non-haze aerosol. Quantitative estimation shows that woodburning contribution to Malaysian atmospheric PAHs ranges from 25% to 35% with no relation to haze intensity, while automotive contribution ranges from 65% to 75%. These results suggest that the major contributor of PAHs in Malaysian air is automotive exhaust whether smoke haze is observed or not

H, C, and N isotopic compositions of Hayabusa category 3 organic samples

Since isotopic ratios of H, C, and N are sensitive indicators for determining extraterrestrial organics, we have measured these isotopes of Hayabusa category 3 organic samples of RB-QD04-0047-02, RA-QD02-0120, and RB-QD04-0001 with ion imaging using a NanoSIMS ion microprobe. All samples have H, C, and N isotopic compositions that are terrestrial within errors (approximately ±50‰ for H, approximately ±9‰ for C, and approximately ±2‰ for N). None of these samples contain micrometer-sized hot spots with anomalous H, C, and N isotopic compositions, unlike previous isotope data for extraterrestrial organic materials, i.e., insoluble organic matters (IOMs) and nano-globules in chondrites, interplanetary dust particles (IDPs), and cometary dust particles. We, therefore, cannot conclude whether these Hayabusa category 3 samples are terrestrial contaminants or extraterrestrial materials because of the H, C, and N isotopic data. A coordinated study using microanalysis techniques including Fourier transform infrared spectrometry (FT-IR), time-of-flight secondary ion mass spectrometry (ToF-SIMS), NanoSIMS ion microprobe, Raman spectroscopy, X-ray absorption near edge spectroscopy (XANES), and transmission electron microscopy/scanning transmission electron microscopy (TEM/STEM) is required to characterize Hayabusa category 3 samples in more detail for exploring their origin and nature.This research was supported by the JSPS Strategic Fund for Strengthening Leading-edge Research and Development to the JAMSTEC

H, C, and N isotopic compositions of Hayabusa category 3 organic samples

Since isotopic ratios of H, C, and N are sensitive indicators for determining extraterrestrial organics, we have measured these isotopes of Hayabusa category 3 organic samples of RB-QD04-0047-02, RA-QD02-0120, and RB-QD04-0001 with ion imaging using a NanoSIMS ion microprobe. All samples have H, C, and N isotopic compositions that are terrestrial within errors (approximately ±50‰ for H, approximately ±9‰ for C, and approximately ±2‰ for N). None of these samples contain micrometer-sized hot spots with anomalous H, C, and N isotopic compositions, unlike previous isotope data for extraterrestrial organic materials, i.e., insoluble organic matters (IOMs) and nano-globules in chondrites, interplanetary dust particles (IDPs), and cometary dust particles. We, therefore, cannot conclude whether these Hayabusa category 3 samples are terrestrial contaminants or extraterrestrial materials because of the H, C, and N isotopic data. A coordinated study using microanalysis techniques including Fourier transform infrared spectrometry (FT-IR), time-of-flight secondary ion mass spectrometry (ToF-SIMS), NanoSIMS ion microprobe, Raman spectroscopy, X-ray absorption near edge spectroscopy (XANES), and transmission electron microscopy/scanning transmission electron microscopy (TEM/STEM) is required to characterize Hayabusa category 3 samples in more detail for exploring their origin and nature.This research was supported by the JSPS Strategic Fund for Strengthening Leading-edge Research and Development to the JAMSTEC

ToF-SIMS analysis of carbonaceous particles in the sample catcher of the Hayabusa spacecraft

Three carbonaceous category 3 particles (RA-QD02-0180, RB-QD04-0037-01, and RB-QD04-0047-02) returned in the sample catcher from the Hayabusa spacecraft were analyzed by time of flight-secondary ion mass spectrometry (ToF-SIMS) to establish an analytical procedure for determination of their origins. By the different analytical schemes, the three particles gave distinct elemental and molecular ions, in which the organic carbons commonly appear to be associated with nitrogen, silicon, and/or fluorine. The particles could be debris of silicon rubber and fluorinated compounds and are therefore man-made artifacts rather than natural organic matter

Sequential analysis of carbonaceous materials in Hayabusa-returned samples for the determination of their origin

Preliminary results of the analyses of five carbonaceous materials (particle size of approximately 50 μm) from the Hayabusa spacecraft sample catcher, including their texture, chemistry, and chemical/isotopic compositions, are summarized. The carbonaceous particles underwent sequential analysis using a series of microanalytical instruments located at several research institutes and universities. Collected particles were initially classified into four categories: two categories containing extraterrestrial silicate particles, one category containing metal and quartz particles consistent with contamination from the sample catcher or sample manipulation tools, and a final category containing carbonaceous particles. Analysis of this final category was the main focus of this study. Through examination of the carbonaceous materials, the appropriate analytical processes for sample transportation and handling were optimized to minimize sample damage and terrestrial contamination. Particles were investigated by transmission electron microscopy/scanning transmission electron microscopy, and Ca-carbonate inclusions were found in one particle. In a different particle, a heterogeneous distribution of silicon in a uniform C, N, and O matrix was found. Though further analysis is required for a strict determination of particle origin, the differences in the microstructure and elemental distribution of the carbonaceous particles suggest multiple origins.TEM analyses were performed at JEOL Ltd. XANES analysis was conducted in UVSOR Facility in Institute for Molecular Science, supported by Nanotechnology Platform Program (Molecule and Material Synthesis) of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan

X-ray absorption near edge structure spectroscopic study of Hayabusa category 3 carbonaceous particles

Analyses with a scanning transmission x-ray microscope (STXM) using x-ray absorption near edge structure (XANES) spectroscopy were applied for the molecular characterization of two kinds of carbonaceous particles of unknown origin, termed category 3, which were collected from the Hayabusa spacecraft sample catcher. Carbon-XANES spectra of the category 3 particles displayed typical spectral patterns of heterogeneous organic macromolecules; peaks corresponding to aromatic/olefinic carbon, heterocyclic nitrogen and/or nitrile, and carboxyl carbon were all detected. Nitrogen-XANES spectra of the particles showed the presence of N-functional groups such as imine, nitrile, aromatic nitrogen, amide, pyrrole, and amine. An oxygen-XANES spectrum of one of the particles showed a ketone group. Differences in carbon- and nitrogen-XANES spectra of the category 3 particles before and after transmission electron microscopic (TEM) observations were observed, which demonstrates that the carbonaceous materials are electron beam sensitive. Calcium-XANES spectroscopy and elemental contrast mapping identified a calcium carbonate grain from one of the category 3 particles. No fluorine-containing molecular species were detected in fluorine-XANES spectra of the particles. The organic macromolecular features of the category 3 particles were distinct from commercial and/or biological ‘fresh (non-degraded)’ polymers, but the category 3 molecular features could possibly reflect degradation of contaminant polymer materials or polymer materials used on the Hayabusa spacecraft. However, an extraterrestrial origin for these materials cannot currently be ruled out