12,940 research outputs found
Memory and superposition in a spin glass
Non-equilibrium dynamics in a Ag(Mn) spin glass are investigated by
measurements of the temperature dependence of the remanent magnetisation. Using
specific cooling protocols before recording the thermo- or isothermal remanent
magnetisations on re-heating, it is found that the measured curves effectively
disclose non-equilibrium spin glass characteristics such as ageing and memory
phenomena as well as an extended validity of the superposition principle for
the relaxation. The usefulness of this "simple" dc-method is discussed, as well
as its applicability to other disordered magnetic systems.Comment: REVTeX style; 8 pages, 4 figure
Stereocontrolled enantioselective total synthesis of the [2+2] quadrigemine alkaloids.
A unified strategy for enantioselective total synthesis of all stereoisomers of the 2+2 family of quadrigemine alkaloids is reported. In this approach, two enantioselective intramolecular Heck reactions are carried out at the same time on precursors fashioned in four steps from either meso- or (+)-chimonanthine to form the two critical quaternary carbons of the peripheral cyclotryptamine rings of these products. Useful levels of catalyst control are realized in either desymmetrizing a meso precursor or controlling diastereoselectivity in elaborating C2-symmetic intermediates. None of the synthetic quadrigemines are identical with alkaloids isolated previously and referred to as quadrigemines A and E. In addition, we report improvements in our previous total syntheses of (+)- or (-)-quadrigemine C that shortened the synthetic sequence to 10 steps and provided these products in 2.2% overall yield from tryptamine
Effects of selective dilution on the magnetic properties of La_{0.7}Sr_{0.3}Mn_{1-x}M'_xO_3 (M' = Al, Ti)
The magnetic lattice of mixed-valence Mn ions in
LaSrMnO is selectively diluted by partial substitution of
Al or Ti for Mn. The ferromagnetic transition temperature and
the saturation magnetization both decrease with substitution. By
presenting the data in terms of selective dilution, in the
low-doping region is found to follow the relation
, where refers to
the undiluted system and is the dilution concentration defined
as or for Al or Ti,
respectively. The scaling behavior of can be
analyzed in the framework of the molecular-field theory and still valid when Mn
is substituted by both Al and Ti. The results are discussed with respect to the
contributions from ferromagnetic double exchange and other possible
antiferromagnetic superexchange interactions coexisting in the material.Comment: Revtex4, 4 pages, 4 figures, 2006 Halong Conference Repor
Inverse velocity statistics in two dimensional turbulence
We present a numerical study of two-dimensional turbulent flows in the
enstrophy cascade regime, with different large-scale forcings and energy sinks.
In particular, we study the statistics of more-than-differentiable velocity
fluctuations by means of two recently introduced sets of statistical
estimators, namely {\it inverse statistics} and {\it second order differences}.
We show that the 2D turbulent velocity field, , cannot be simply
characterized by its spectrum behavior, . There
exists a whole set of exponents associated to the non-trivial smooth
fluctuations of the velocity field at all scales. We also present a numerical
investigation of the temporal properties of measured in different
spatial locations.Comment: 9 pages, 12 figure
Temperature memory and resistive glassy behaviors of a perovskite manganite
This paper reports the observations of long-time relaxation, aging, and
temperature memory behaviors of resistance and magnetization in the
ferromagnetic state of a polycrystalline La0.7Ca0.3Mn0.925Ti0.075O3 compound.
The observed glassy dynamics of the electrical transport appears to be
magnetically originated and has a very close association with the magnetic
glassiness of the sample. Phase separation and strong correlation between
magnetic interactions and electronic conduction play the essential roles in
producing such a resistive glassiness. We explain the observed effects in terms
of a coexistence of two competing thermomagnetic processes, domain growth and
magnetic freezing, and propose that hole-doped perovskite manganites can be
considered as "resistive glasses".Comment: Submitted to PR
Selective dilution and magnetic properties of La_{0.7}Sr_{0.3}Mn_{1-x}M'_xO_3 (M' = Al, Ti)
The magnetic lattice of mixed-valence Mn ions in LaSrMnO
is selectively diluted by partial substitution of Mn by Al or Ti. The
ferromagnetic transition temperature and the saturation moment decreases with
substitution in both series. The volume fraction of the non-ferromagnetic
phases evolves non-linearly with the substitution concentration and faster than
theoretically expected. By presenting the data in terms of selective dilutions,
the reduction of is found to be scaled by the relative ionic
concentrations and is consistent with a prediction derived from molecular-field
theory.Comment: 6 pages, 5 figures, REVTex4.0. Submitted to PR
Short range ferromagnetism and spin glass state in
Dynamic magnetic properties of are
reported. The system appears to attain local ferromagnetic order at
K. Below this temperature the low field
magnetization becomes history dependent, i.e. the zero field cooled (ZFC) and
field cooled (FC) magnetization deviate from each other and closely logarithmic
relaxation appears at our experimental time scales (0.3- sec). The zero
field cooled magnetization has a maximum at K,
whereas the field cooled magnetization continues to increase, although less
sharply, also below this temperature. Surprisingly, the dynamics of the system
shows non-equilibrium spin glass (SG) features not only below the maximum in
the ZFC magnetization, but also in the temperature region between this maximum
and . The aging and temperature cycling experiments show only
quantitative differences in the dynamic behavior above and below the maximum in
the ZFC-magnetization; similarly, memory effects are observed in both
temperature regions. We attribute the high temperature behavior to the
existence of clusters of short range ferromagnetic order below
; the configuration evolves into a conventional spin glass
state at temperatures below .Comment: REVTeX style; 8 pages, 8 figure
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