Impacts of future urban expansion on urban heat island effects during heatwave events in the city of Melbourne in southeast Australia

The city of Melbourne in southeast Australia is planning to expand urban areas substantially by the year 2050 and this expansion has the potential to alter the Urban Heat Island (UHI), that is, higher temperatures in urban areas as compared to surrounding rural areas. Moreover, Melbourne has been experiencing more frequent heatwaves for last two decades, and the intensity and duration of heatwaves is expected to increase in the future, which could exacerbate the UHI. This study evaluates the potential impacts of future urban expansion on the urban meteorology in Melbourne city during four of the most severe heatwave events during the period 2000–2009. Urban expansion is implemented as high‐density urban with a high urban fraction of 0.9 to investigate the maximum possible impact. Simulations are carried out using the Weather Research and Forecasting model coupled with the Single‐Layer Urban Canopy Model with current land‐use and future urban expansion scenarios. Urban expansion increases the near‐surface (2‐m) UHI (UHI2) by 0.75 to 2.80 °C and the skin‐surface UHI (UHIsk) by 1.9 to 5.4 °C over the expanded urban areas during the night, with no changes in existing urban areas. No substantial changes in UHI2 and UHIsk occur during the day over both existing and expanded urban areas. This is largely driven by changes in the storage heat flux, with an increase in storage heat at night and a decrease during the day; that is, excess storage heat accumulated during the day is released at night, which causes a slower decrease of near‐surface temperature and increase in the UHI. Urban expansion did not affect human thermal comfort (HTC) in existing urban areas and there were no marked differences in HTC between existing and expanded urban areas

US hegemony and the origins of Japanese nuclear power : the politics of consent

This paper deploys the Gramscian concepts of hegemony and consent in order to explore the process whereby nuclear power was brought to Japan. The core argument is that nuclear power was brought to Japan as a consequence of US hegemony. Rather than a simple manifestation of one state exerting material ‘power over' another, bringing nuclear power to Japan involved a series of compromises worked out within and between state and civil society in both Japan and the USA. Ideologies of nationalism, imperialism and modernity underpinned the process, coalescing in post-war debates about the future trajectory of Japanese society, Japan's Cold War alliance with the USA and the role of nuclear power in both. Consent to nuclear power was secured through the generation of a psychological state in the public mind combining the fear of nuclear attack and the hope of unlimited consumption in a nuclear-fuelled post-modern world

Culture, health and the emergency

Available from British Library Document Supply Centre-DSC:DXN052536 / BLDSC - British Library Document Supply CentreSIGLEGBUnited Kingdo

(N-Benzyl-bis-N',N''-salicylidene)-cis-1,3,5-triaminocyclohexane copper(II): a novel catalyst for the aerobic oxidation of benzyl alcohol

Reaction of Cu(BF4)2·6H2O with the N3O2 donor ligand H2L (where H2L = N-benzyl-N,N-di-tert-butyl-disalicyl-triaminocyclohexane) results in the formation of a novel CuIIL complex, 1. X-Ray crystallography of 1 shows the CuII centre coordinated by two phenolate oxygens and two imine nitrogens in a distorted square plane with an elongated bond to the amine nitrogen (2.512 Å) in the axial position. EPR spectroscopy of 1 gives g values of g1 = 2.277, g2 = 2.100, g3 = 2.025, and A1 = 15.6 mT which are consistent with the distorted square pyramidal coordination environment determined from the X-ray structure. UV/visible and electrochemical analysis of 1 shows that it undergoes two reversible processes assigned to the successive oxidation of the phenolate oxygens to phenoxyl radicals, the first at E½ = 0.89 V (E = 81 mV, vs. Ag/AgCl) and the second at E½ = 1.13V (E = 84 mV, vs. Ag/AgCl). Chemical oxidation of 1 results in the formation of a species, assigned as [ 1]+ which is EPR silent due to antiferromagnetic coupling between the CuII centre and the bound phenoxyl radical. The oxidised species catalyses the oxidation of benzyl alcohol to benzaldehyde

Zero-tolerance biosecurity protects high-conservation-value island nature reserve

Barrow Island, north-west coast of Australia, is one of the world's significant conservation areas, harboring marsupials that have become extinct or threatened on mainland Australia as well as a rich diversity of plants and animals, some endemic. Access to construct a Liquefied Natural Gas (LNG) plant, Australia's largest infrastructure development, on the island was conditional on no non-indigenous species (NIS) becoming established. We developed a comprehensive biosecurity system to protect the island's biodiversity. From 2009 to 2015 more than 0.5 million passengers and 12.2 million tonnes of freight were transported to the island under the biosecurity system, requiring 1.5 million hrs of inspections. No establishments of NIS were detected. We made four observations that will assist development of biosecurity systems. Firstly, the frequency of detections of organisms corresponded best to a mixture log-normal distribution including the high number of zero inspections and extreme values involving rare incursions. Secondly, comprehensive knowledge of the island's biota allowed estimation of false positive detections (62% native species). Thirdly, detections at the border did not predict incursions on the island. Fourthly, the workforce detected more than half post-border incursions (59%). Similar approaches can and should be implemented for all areas of significant conservation value. Keyword