Vertical geochemical variations and arsenic mobilization in the shallow alluvial aquifers of the Chapai-Nawabganj District, northwestern Bangladesh: implication of siderite precipitation

Core sediments from three disturbed boreholes JOR, GHAT, and RAJ) and two undisturbed boreholes (DW1 and DW2) were collected in the study area of the Chapai-Nawabganj district of northwestern Bangladesh for geochemical analyses. In the study area, groundwater samples from fourteen As-contained private wells and five nested piezometers at both the DW1 and DW2 boreholes were also collected and analyzed. The groundwater arsenic concentrations in the uppermost aquifer (10–40 m of depth) range from 3 to 315 lg/L (mean 47.73 ± 73.41 lg/L), while the arsenic content in sediments range from 2 to 14 mg/kg (mean 4.36 ± 3.34 mg/kg). An environmental scanning electron microscope (ESEM) with an energy dispersive X-ray spectrometer was used to investigate the presence of major and trace elements in the sediments. Groundwaters in the study area are generally the Ca–HCO3 type with high concentrations of As, but low levels of Fe, Mn, NO3 - and SO4 -2. The concentrations of As, Fe, Mn decrease with depth in the groundwater, showing vertical geochemical variations in the study area. Statistical analysis clearly shows that As is closely associated with Fe and Mn in the sediments of the JOR core (r = 0.87, p\0.05 for Fe and r = 0.78, p\0.05 for Mn) and GHAT core (r = 0.95, p\0.05 for Fe and r = 0.93, p\0.05 for Mn), while As is not correlated with Fe and Mn in groundwater. The comparatively low Fe and Mn concentrations in some groundwater and the ESEM image revealed that siderite precipitated as a secondary mineral on the surface of the sediment particles. The correlations along with results of sequential extraction experiments indicated that reductive dissolution of FeOOH and MnOOH represents a mechanism for releasing arsenic into the groundwater

Environmental controls and facies architecture of a jurassic carbonate episode La Manga Formation), Mendoza Province, Neuquén Basin

La Manga Formation is a vast carbonate system developed in the Neuquén Basin. The age is based in ammonite faunas, ranging from Early Callovian (Bodenbenderi-Proximum Zone) to Middle Oxfordian (Cordatum Standard Zone to Transversarium Standard Zone, and probably to the lower part of the Bifurcatus Standard Zone). A stratigraphical and sedimentological analysis, in the outcrops exposed in the south of Mendoza province, enabled the recognition of five facies associations of a carbonate ramp corresponding to (1) distal outer ramp, (2) proximal outer to distal middle ramp, (3) proximal middle ramp, (4) inner ramp deposits (shoreface, shoal, patch reef, shallow subtidal lagoon and tidal flat) and (5) paleokarstic facies. These facies correspond to homoclinal to distally steepened carbonate ramp. The facies associations are included into three third-order depositional sequences (DS-1, DS-2, DS-3) represented by transgressive and highstand systems tracts with sequence boundaries of regional character. Different controlling factors can be recognised in the deposition of this unit. The abrupt changes of facies, as well as paleokarst and epikarst discontinuity surfaces in the successions provide important evidence in terms of depositional environment and vertical evolution of the carbonate ramp. Facies patterns are variable across the outcrop area and vertically through time because of a combination of ramp morphology, siliciclastic supply, sea level changes and tectonic effects. In the southern sections, siliciclastic influx influenced the deposition of proximal middle ramp facies later overlain by scleractinian patch reefs which grew up throughout progressive stages from aggradational to progradational facies in response to climate controls and nutrient levels influence. In northern outcrops, tectonic controls affected the ramp topography and influenced the development of distal deep marine facies. Shallow subtidal and peritidal cycles indicate a combination of allocyclic and autocyclic processes controlling accommodation space and sediment accumulation.Fil: Palma, Ricardo Manuel. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Bressan, Graciela Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Estudios Andinos "Don Pablo Groeber". Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Estudios Andinos "Don Pablo Groeber"; ArgentinaFil: Riccardi, Alberto Carlos. Universidad Nacional de La Plata. Facultad de Ciencias Naturales y Museo; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: López Gómez, José. Universidad Complutense de Madrid; España. Consejo Superior de Investigaciones Científicas; EspañaFil: Martín Chivelet, Javier. Consejo Superior de Investigaciones Científicas; España. Universidad Complutense de Madrid; Españ