Hexaazide octahedral molybdenum cluster complexes: synthesis, properties and the evidence of hydrolysis

This article reports the synthesis, crystal structure of new molybdenum hexaazide cluster complex (ⁿBu₄N)₂[{Mo₆I₈}(N₃)₆] (3) and comparison of its photophysical and electrochemical properties to those of earlier reported analogues (ⁿBu₄N)₂[{M₆X₈}(N₃)₆] (X = Cl, Br). Additionally, the dimerisation of 3 as a result of hydrolysis was revealed by mass spectrometry and single crystal X-Ray diffraction. Indeed, the structurally characterised compound (ⁿBu₄N)₄[{Mo₆I₈}(N₃)₅)₂O] represents the first example of oxo-bridged dimer of octahedral molybdenum clusters complexes

Form Factors of Composite Systems by Generalized Wigner-Eckart Theorem for Poincar\'e group

The relativistic approach to electroweak properties of two-particle composite systems developed previously is generalized here to the case of nonzero spin. This approach is based on the instant form of relativistic Hamiltonian dynamics. A special mathematical technique is used for the parametrization of matrix elements of electroweak current operators in terms of form factors. The parametrization is a realization of the generalized Wigner--Eckart theorem on the Poincar\'e group, form factors are corresponding reduced matrix elements and they have the sense of distributions (generalized functions). The electroweak current matrix element satisfies the relativistic covariance conditions and in the case of electromagnetic current it also automatically satisfies the conservation law.Comment: Submitted to Theor. Math. Phy

A comparative study of optical properties and X-ray induced luminescence of octahedral molybdenum and tungsten cluster complexes

© 2017 The Royal Society of Chemistry. Octahedral metal cluster complexes have high potential for biomedical applications. In order to evaluate the benefits of these moieties for combined CT/X-ray luminescence computed tomography, this paper compares photoluminescence, radiodensity and X-ray induced luminescence properties of eight related octahedral molybdenum and tungsten cluster complexes [{M 6 I 8 }L 6 ] n (where M is Mo or W and L is I - , NO 3 - , OTs - or OH - /H 2 O). This article demonstrates that despite the fact that molybdenum cluster complexes are better photoluminescence emitters, tungsten cluster complexes, in particular (Bu 4 N) 2 [{W 6 I 8 }I 6 ], demonstrate significantly higher X-ray induced luminescence due to a combination of relatively good photoluminescence properties and high X-ray attenuation. Additionally, photo-degradation of [{M 6 I 8 }(NO 3 ) 6 ] 2- was evaluated

THE FIRST EXPERIENCE WITH TISSUCOL AT MOSCOW CITY CANCER HOSPITAL SIXTY-TWO

The paper describes the first experience with the fibrin sealant Tissucol at Moscow City Cancer Hospital Sixty-Two. The authors used this agent in different clinical situations. However, Tissucol showed the highest efficacy in arresting long-term severe lymphorrhea. The described clinical case clearly demonstrates the abilities of this agent and allows it to be recommended for use in other areas of oncology

Chiral anomaly for local boundary conditions

It is known that in the zeta function regularization and in the Fujikawa method chiral anomaly is defined through a coefficient in the heat kernel expansion for the Dirac operator. In this paper we apply the heat kernel methods to calculate boundary contributions to the chiral anomaly for local (bag) boundary conditions. As a by-product some new results on the heat trace asymptotics are also obtained.Comment: 20 p., late

Interactions of a j=1j=1 boson in the 2(2j+1)2(2j+1) component theory

The amplitudes for boson-boson and fermion-boson interactions are calculated in the second order of perturbation theory in the Lobachevsky space. An essential ingredient of the used model is the Weinberg's $2(2j+1)$ component formalism for describing a particle of spin $j$, recently developed substantially. The boson-boson amplitude is then compared with the two-fermion amplitude obtained long ago by Skachkov on the ground of the hamiltonian formulation of quantum field theory on the mass hyperboloid, $p_0^2 -{\bf p}^2=M^2$, proposed by Kadyshevsky. The parametrization of the amplitudes by means of the momentum transfer in the Lobachevsky space leads to same spin structures in the expressions of $T$ matrices for the fermion and the boson cases. However, certain differences are found. Possible physical applications are discussed.Comment: REVTeX 3.0 file. 12pp. Substantially revised version of IFUNAM preprints FT-93-24, FT-93-3

A cosmological constant from the QCD trace anomaly?

According to recent astrophysical observations the large scale mean pressure of our present universe is negative suggesting a positive cosmological constant like term. This article addresses the question of whether non-perturbative effects of self-interacting quantum fields in curved space-times may yield a significant contribution. Focusing on the trace anomaly of quantum chromo-dynamics (QCD), a preliminary estimate of the expected order of magnitude yields a remarkable coincidence with the empirical data, indicating the potential relevance of this effect. PACS: 04.62.+v, 12.38.Aw, 12.38.Lg, 98.80.Es.Comment: 4 pages, RevTe