Topological Phases in the Single-Layer FeSe

A distinct electronic structure was observed in the single-layer FeSe which shows surprising high temperature superconductivity over 65k. Here we demonstrate that the electronic structure can be explained by the strain effect due to substrates. More importantly, we find that this electronic structure can be tuned into robust topological phases from a topologically trivial metallic phase by the spin-orbital interaction and couplings to substrates. The topological phase is robust against any perturbations that preserve the time-reversal symmetry. Our studies suggest that topological phases and topologically related properties such as Majorana Fermions can be realized in iron-based high T$_{c}$ superconductors.Comment: 9 pages, 5 figue

Oriented gap opening in the magnetically ordered state of Iron-pnicitides: an impact of intrinsic unit cell doubling on the FeFe square lattice by AsAs atoms

We show that the complicated band reconstruction near Fermi surfaces in the magnetically ordered state of iron-pnictides observed by angle-resolved photoemission spectroscopies (ARPES) can be understood in a meanfield level if the \emph{intrinsic unit cell doubling} due to As atoms is properly considered as shown in the recently constructed S$_{4}$ microscopic effective model. The (0,$\pi$) or ($\pi$,0) col-linear antiferromagnetic (C-AFM) order does not open gaps between two points at Fermi surfaces linked by the ordered wave vector but forces a band reconstruction involving four points in unfolded Brillouin zone (BZ) and gives rise to small pockets or hot spots. The S$_4$ symmetry naturally chooses a staggered orbital order over a ferro-orbital order to coexist with the C-AFM order. These results strongly suggest that the kinematics based on the S$_{4}$ symmetry captures the essential low energy physics of iron-based superconductors.Comment: 5 figures, 5 page

Enhanced mechanical, thermal and flame retardant properties by combining graphene nanosheets and metal hydroxide nanorods for Acrylonitrile–Butadiene–Styrene copolymer composite

Three metal hydroxide nanorods (MHR) with uniform diameters were synthesized, and then combined with graphene nanosheets (GNS) to prepare acrylonitrile–butadiene–styrene (ABS) copolymer composites. An excellent dispersion of exfoliated two-dimensional (2-D) GNS and 1-D MHR in the ABS matrix was achieved. The effects of combined GNS and MHR on the mechanical, thermal and flame retardant properties of the ABS composites were investigated. With the addition of 2 wt% GNS and 4 wt% Co(OH)2, the tensile strength, bending strength and storage modulus of the ABS composites were increased by 45.1%, 40.5% and 42.3% respectively. The ABS/GNS/Co(OH)2 ternary composite shows the lowest maximum weight loss rate and highest residue yield. Noticeable reduction in the flammability was achieved with the addition of GNS and Co(OH)2, due to the formation of more continuous and compact charred layers that retarded the mass and heat transfer between the flame and the polymer matrix

Combustion Catalyst: Nano‐Fe2O3 and Nano‐Thermite Al/ Fe2O3 with Different Shapes

In order to enable the energetic materials to possess a more powerful performance, adding combustion catalysts is a quite effective method. Granular, oval, and polyhedral Fe2O3 particles have been prepared by the hydrothermal method and used to fabricate Al/Fe2O3 thermites. All the Fe2O3 and Al/Fe2O3 thermite samples were characterized using a combination of experimental techniques including scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), X‐ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), transmission electron microscope (TEM), and high‐resolution TEM (HRTEM). The non‐isothermal decomposition kinetics of the composites and nitrocellulose (NC) can be modeled by the Avrami‐Erofeev equation f(α)=3(1–α)[–ln(1–α)]1/3/2 in differential form. Through the thermogravimetric analysis infrared (TG‐IR) analysis of decomposition processes and products, it is speculated that Fe2O3 and Al/Fe2O3 can effectively accelerate the thermal decomposition reaction rate of NC by promoting the O‐NO2 bond cleavage. Adding oxides or thermites can distinctly increase the burning rate, decrease the burning rate pressure exponent, increase the flame temperature, and improve the combustion wave structures of the ammonium perchlorate/hydroxyl‐terminated polybutadiene (AP/HTPB) propellants. Among the three studied, different shapes of Fe2O3, the granular Fe2O3, and its corresponding thermites (Al/Fe2O3(H)) exhibit the highest burning rate due to larger surface area associated with smaller particle size. Moreover, Al/Fe2O3(H) thermites have more effective combustion‐supporting ability for AP/HTPB propellants than Fe2O3 structures and the other two as‐prepared Al/Fe2O3 thermites

Effect of Functionalized Graphene Oxide with Hyper-Branched Flame Retardant on Flammability and Thermal Stability of Cross-Linked Polyethylene

In this work, GO was functionalized by a hyper-branched flame retardant, which was synthesized by the reaction of N-aminoethyl piperazine and di(acryloyloxyethyl)methylphosphonate. Subsequently, the resultant functionalized GO (FGO) was incorporated into the cross-linked polyethylene (XLPE) to enhance the flame retardancy of the matrix. Transmission electron spectroscopy images indicated that FGO exhibited uniform dispersion in XLPE matrix and strong adhesion with the matrix by cross-linking, which improved barrier effect due to reduced heat release and the free radical transfer between the matrix and graphene nanosheets. The incorporation of FGO into XLPE matrix endowed polymer composites with flame retardancy and thermal stability. In addition, the homogeneous dispersion of functionalized GO with a hyper-branched flame retardant in the polymer matrix improved the antioxidation and mechanical properties of XLPE-FGO nanocomposites compared to the XLPE-GO samples, as demonstrated through the oxidative induction temperature and time test, oven aging test and mechanical test. © 2014 American Chemical Society