Interfacial adhesion of laser clad functionally graded materials

Specially designed samples of laser clad AlSi40 functionally graded materials (FGM) are made for evaluating the interfacial adhesion. To obtain the interfacial bond strength notches are made right at the interface of the FGMs. In-situ microstructural observations during straining in a field-emission gun environmental scanning electron microscopy reveal different failure modes of the FGMs and substrate. Mapping of strain fields using digital imaging correlation shows a gradual transition of deformation over the interface region and softening effects in the heat-affected zones of the FGM tracks. The strengthening of the FGM is dominated by the size of the Al halos around the particles, in accordance with a dislocation pile-up model.

Sliding Wear Behavior of Al2O3-TiO2 Coatings Fabricated by the Suspension Plasma Spraying Technique

[EN] The friction and dry sliding wear behavior of alumina and alumina-titania near-nanometric coatings were examined. Coatings were obtained by the suspension plasma spraying technique. Dry sliding wear tests were performed on a ball-on-disk tribometer, with an Al2O3 ball as counterpart material, a normal load of 2 N, a sliding distance of 1200 m and a sliding speed of 0.1 m/s. The effect of including TiO2 in the fabricated coatings on friction coefficient behavior, wear rates and wear damage patterns was determined. The addition of TiO2 to the coatings was found to greatly increase wear resistance by, for example, 2.6-fold for 40 wt% of TiO2. The analysis of the wear surface was correlated with microstructural parameters, mechanical properties and wear rates.The authors wish to thank for the Spanish Ministry of Economy and Competitiveness (MAT2012-38364-C03) and the Autonomous Government of Valencia for funding for the stay in SPCTS-UMR CNRS (France), and the French FCENANOSURF consortium funded by the French Ministry and Industry and local governments of Region Centre and Region Limousin.Klyatskina, E.; Espinosa Fernández, L.; Darut, G.; Segovia López, EF.; Salvador Moya, MD.; Montavon, G.; Agorges, H. (2015). Sliding Wear Behavior of Al2O3-TiO2 Coatings Fabricated by the Suspension Plasma Spraying Technique. Tribology Letters. 59(1):1-9. https://doi.org/10.1007/s11249-015-0530-5S19591Pawlowski, L.: The Science and Engineering of Thermal Spray Coatings. Wiley: Hoboken (2008)Lampe, Th, Eisenberg, S., Cabeo, E.R.: Plasma surface engineering in the automotive industry—trends and future prospective. Surf. Coat. 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Coatings with laser melt injection of ceramic particles

The conditions for a successful Laser Melt Injection (LMI) of SiC and WC particles into the melt pool of Al8Si and Ti6Al4V alloys were studied experimentally and theoretically by FEM calculations. The laser employed is a high power Nd:YAG The formation of a relatively thick aluminium oxide layer on Al melt surface was confirmed during in-situ melting in an Environmental Scanning Electron Microscope (ESEM) at temperatures above 900 degreesC. This oxide layer acts as a barrier for particle penetration but it can be dissolved in the melt at temperatures above 1250 degreesC and consequently it opens a "window" for particles injection The finite element analysis of the laser melting process of Al-Si alloy leads to the conclusions, that the laser scan velocity has only a small influence on the substrate temperature distribution in the vicinity of the laser beam and that the size of extended part of laser melt pool (which is the best place for injection) is extremely small. Therefore, in contrast to Ti-alloys an extension of a melt pool size behind the laser beam, which serves as an effective instrument for successful LMI of ceramic particles, is not a successful processing route in the case of Al alloys. Further, the relationship between microstructure, tensile and wear properties has been investigated for SiC/Al-Si and WC/Ti-Al-V metal matrix composite layers. Although the presence of hard and brittle phases formed during the laser processing decreases the tensile strength in comparison with substrate materials, a massive improvement of wear resistance of both layers is confirmed. As in-situ (ESEM) tensile tests show the crack initiation process in WC/Ti-Al-V layer strongly depends on a type of WC powder used in laser melt injection process