10 research outputs found
In situ redox reactions facilitate the assembly of a mixed-valence metal-organic nanocapsule
Get PDFC-alkylpyrogallol[4]arenes (PgCs) have been studied for their ability to form metal-organic nanocapsules (MONCs) through coordination to appropriate metal ions. Here we present the synthesis and characterization of an MnII/MnIII-seamed MONC in addition to its electrochemical and magnetic behavior. This MONC assembles from 24 manganese ions and 6 PgCs, while an additional metal ion is located on the capsule interior, anchored through the introduction of bridging nitrite ions. The latter originate from an in situ redox reaction that occurs during the self-assembly process, thus representing a new route to otherwise unobtainable nanocapsules
Oxygen Reduction on Methanol-Tolerant Carbon-Supported PtxSy Nanoparticles Prepared by a Single-Step Low-Temperature Method
No full textEnhanced Electrocatalytic Performance for Oxygen Reduction via Active Interfaces of Layer-By-Layered Titanium Nitride/Titanium Carbonitride Structures
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Effects of Crystallographic Structures of Metal-Phthalocyanine on Electrocatalytic Properties of Oxygen Reduction in Acidic Condition
No full textInfluences of Electrode Potential on Mechanism of Oxygen Reduction Reaction on Pd-Skin/Pd3Fe(111) Electrocatalyst: Insights from DFT-Based Calculations
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