50 research outputs found
Enrichment of CH3F nuclear spin isomers by resonant microwave radiation
Theoretical model of the coherent control of nuclear spin isomers by
microwave radiation has been developed. Model accounts the M-degeneracy of
molecular states and molecular center-of-mass motion. The model has been
applied to the 13CH3F molecules. Microwave radiation excites the para state
(J=11,K=1) which is mixed by the nuclear spin-spin interaction with the ortho
state (9,3). Dependencies of the isomer enrichment and conversion rates on the
radiation frequency have been calculated. Both spectra consist of two
resonances situated at the centers of allowed and forbidden (by nuclear spin)
transitions in the molecule. Larger enrichment, up to 7%, can be produced by
strong radiation resonant to the forbidden transition. The spin conversion rate
can be increased by 2 orders of magnitude at this resonance.Comment: REVTEX, 14 pages + 6 eps figure