835 research outputs found
Interplay between lattice, orbital, and magnetic degrees of freedom in the chain-polymer Cu(II) breathing crystals
The chain-polymer Cu(II) breathing crystals C21H19CuF12N4O6 were studied
using the x-ray diffraction and ab initio band structure calculations. We show
that the crystal structure modification at T=146 K, associated with the spin
crossover transition, induces the changes of the orbital order in half of the
Cu sites. This in turn results in the switch of the magnetic interaction sign
in accordance with the Goodenough-Kanamori-Andersen theory of the coupling
between the orbital and spin degrees of freedom.Comment: 6 pages, 7 figure
Increasing the Adaptive Capacity of the Organism When Exposed to Adverse Environmental Factors Through Phytoadaptogens
The Problem of improving the quality of life of the population in modern conditions is the most relevant. The level of human health largely depends on the quality of the environment. Of special importance are the risk factors for the spread of diseases like environmental pollution, social conditions and bad habits. To the emergence of ecologically dependent diseases leads the combined impact of technogenic, social-economic, natural-climatic factors. The introduction of the principles of biotechnology, nanotechnology and innovations in industrial processing of plant resources, especially natural adaptogens, contributes to the production of balanced, ecologically clean food products functional purpose, the use of which will significantly minimize the adverse effects of the environment on humans
Synthesis of nitroxyl radical by direct nucleophilic functionalization of a C-H bond in the azadiene systems
Cyclic dinitrones underwent nucleophilic substitution of the hydrogen atom in the reaction with a paramagnetic carbanion, the lithium derivative of 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide, to give polyfunctional nitronyl nitroxyls. Β© 2012 Springer Science+Business Media New York
- β¦