39 research outputs found
Disentangling the conductivity spectra of two-dimensional organic conductors
The optical spectrum of a κ -phase organic conductor is thoroughly analyzed for the example of κ -(BEDT-TTF) 2 Cu [ N(CN) 2 ] Br 0.85 Cl 0.15 in order to identify its various contributions. It is shown how the complex spectra can be decomposed using different approaches; the intradimer and interdimer contributions are discussed. In particular the fingerprints of electronic correlations in these spectra are considered
Origin of Low-Energy Excitations in Charge-Ordered Manganites
The low-energy excitations in the charge-ordered phase of polycrystalline
La0.25Ca0.75MnO3 are explored by frequency-domain terahertz spectroscopy. In
the frequency range from 4 cm^-1 to 700 cm^-1 (energies 0.4 meV to 90 meV) and
at temperatures down to 5 K, we do not detect any feature that can be
associated with the collective response of the spatially modulated charge
continuum. In the antiferromagnetically ordered phase, broad absorption bands
appear in the conductivity and permittivity spectra around 30 cm^-1 and 100
cm^-1 which are assigned to former acoustic phonons optically activated due to
a fourfold superstructure in the crystal lattice. Our results indicate that
characteristic energies of collective excitations of the charge-ordered phase
in La0:25Ca0:75MnO3, if any, lie below 1 meV. At our lowest frequencies of only
few wavenumbers a strong relaxation is observed above 100 K connected to the
formation of the charge-ordered state.Comment: 5 pages, 3 figure
Charge-transfer processes in radical ion molecular conductors κ-(BEDT-TTF)2Cu[N(CN)2]Br x Cl1 − x : The superconductor (x = 0.9) and the conductor with the metal-insulator transition (x = 0)
Optical spectral investigations of low-dimensional organic molecular conductors κ-(BEDT-TTF)2Cu[N(CN)2]Br x Cl1 − x with x = 0.9 (the superconductor with T c = 11.3 K) and x = 0 (the metal with the metal-insulator transition at T < 50 K) are performed in the range 50–6000 cm−1 (6 meV–0.74 eV) at temperatures from 300 to 20 K. The optical conductivity spectra are quantitatively analyzed in terms of the proposed model, according to which the charge transfer involves two types of charge carriers, i.e., electrons (holes) localized on clusters (dimers and tetramers formed by BEDT-TTF molecules) and quasi-free charge carriers, with the use of the tetramer “cluster“ model based on the Hubbard Hamiltonian for correlated electrons and the Drude model for quasi-free charge carriers. Physical parameters of the model, such as the energy of Coulomb repulsion between two electrons (holes) in one molecule, the transfer integrals between molecules inside the dimer and between dimers, and the electron-molecular vibration coupling constants, are determined. The anisotropy of the spectra in the conducting plane is explained. The inference is made that only electrons localized on clusters couple with intramolecular vibrations
Nonlinear acousto-electric transport in a two-dimensional electron system
We study both theoretically and experimentally the nonlinear interaction
between an intense surface acoustic wave and a two-dimensional electron plasma
in semiconductor-piezocrystal hybrid structures. The experiments on hybrid
systems exhibit strongly nonlinear acousto-electric effects. The plasma turns
into moving electron stripes, the acousto-electric current reaches its maximum,
and the sound absorption strongly decreases. To describe the nonlinear
phenomena, we develop a coupled-amplitude method for a two-dimensional system
in the strongly nonlinear regime of interaction. At low electron densities the
absorption coefficient decreases with increasing sound intensity, whereas at
high electron density the absorption coefficient is not a monotonous function
of the sound intensity. High-harmonic generation coefficients as a function of
the sound intensity have a nontrivial behavior. Theory and experiment are found
to be in a good agreement.Comment: 27 pages, 6 figure
Bandwidth-controlled Mott transition in kappa-(BEDT-TTF)2Cu[N(CN)2]Br{x}Cl{1-x}: Optical studies of correlated carriers
In the two-dimensional organic charge-transfer salts
kappa-(BEDT-TTF)2Cu[N(CN)2]Br{x}Cl{1-x} a systematic variation of the Br
content from x = 0 to 0.9 allows us to tune the Mott transition by increasing
the bandwidth. At temperatures below 50 K, an energy gap develops in the
Cl-rich samples and grows to approximately 1000 cm-1 for T -> 0. With
increasing Br concentration spectral weight shifts into the gap region and
eventually fills it up completely. As the samples with x = 0.73, 0.85 and 0.9
become metallic at low temperatures, a Drude-like response develops due to the
coherent quasiparticles. Here, the quasiparticle scattering rate shows a
omega^2 dependence and the effective mass of the carriers is enhanced in
agreement with the predictions for a Fermi liquid. These typical signatures of
strong electron-electron interactions are more pronounced for compositions
close to the critical value x_c \approx 0.7 where the metal-to-insulator
transition occurs.Comment: 11 pages, 12 figure