Synthesis of superconducting pyrochlore RbOs2O6

RbOs2O6, the third superconducting pyrochlore oxide (known so far), has been synthesized by encapsulation and by high pressure techniques. Suitable post chemical treatment of the as-prepared sample allowed us to eliminate the impurity phases. Bulk superconductivity with Tc=6.4 K was observed in magnetisation and specific heat measurements. The transition temperature of RbOs2O6 was found to be the same for both preparation methods. Structural investigations showed that Rb atoms occupy the 8b site in the pyrochlore lattice with a lattice parameter of 10.1137(1) A.Comment: 12 pages, 5 figures, correction to one author name and Figure

Determination of the local structure of Sr2−x_{2-x}Mx_xIrO4_4 (M = K, La) as a function of doping and temperature

The local structure of correlated spin-orbit insulator Sr$_{2-x}$M$_x$IrO$_4$ (M = K, La) has been investigated by Ir L$_3$-edge extended x-ray absorption fine structure measurements. The measurements were performed as a function of temperature for different dopings induced by substitution of Sr with La or K. It is found that Ir-O bonds have strong covalency and they hardly show any change across the N\'eel temperature. In the studied doping range, neither Ir-O bonds nor their dynamics, measured by their mean square relative displacements, show any appreciable change upon carrier doping, indicating possibility of a nanoscale phase separation in the doped system. On the other hand, there is a large increase of the static disorder in Ir-Sr correlation, larger for K doping than La doping. Similarities and differences with respect to the local lattice displacements in cuprates are briefly discussed.Comment: Main text: 6 pages, 4 figures, Supplemental information: 2 pages, 2 figure

Arc-like distribution of high CO(J=3-2)/CO(J=1-0) ratio gas surrounding the central star cluster of the supergiant HII region NGC 604

We report the discovery of a high CO(J=3-2)/CO(J=1-0) ratio gas with an arc-like distribution (``high-ratio gas arc'') surrounding the central star cluster of the supergiant HII region NGC 604 in the nearby spiral galaxy M 33, based on multi-J CO observations of a 5' $\times$ 5' region of NGC 604 conducted using the ASTE 10-m and NRO 45-m telescopes. The discovered ``high-ratio gas arc'' extends to the south-east to north-west direction with a size of $\sim$ 200 pc. The western part of the high-ratio gas arc closely coincides well with the shells of the HII regions traced by H$\alpha$ and radio continuum peaks. The CO(J=3-2)/CO(J=1-0) ratio, R_{3-2/1-0}, ranges between 0.3 and 1.2 in the observed region, and the R_{3-2/1-0} values of the high-ratio gas arc are around or higher than unity, indicating very warm (T_kin > 60 K) and dense (n(H_2) > 10^{3-4} cm^{-3}) conditions of the high-ratio gas arc. We suggest that the dense gas formation and second-generation star formation occur in the surrounding gas compressed by the stellar wind and/or supernova of the first-generation stars of NGC 604, i.e., the central star cluster of NGC 604.Comment: 4 pages, 4 figures. The Astrophysical Journal Letters, in pres

Phosphorus efficiency in brazilian soybean cultivars.

The primary goal of this study was to evaluate the phosphorus uptake and use efficiency in Brazilian soybean cultivars, besides root morphology and architecture characteristics related to phosphorus uptake, carrying out two greenhouse experiments. The experiment 1 was completely randomised, with 56 treatments (soybean cultivars) and 3 replicates. Experiment 2 was completely randomised design with three replicates, and the ten cultivars (greater and lower efficiency) were selected for this assay according to their ability to absorb phosphorus less available determined in experiment 1. The study was carried out at Center of Nuclear Energy in Agriculture, University of São Paulo, Brazil, between February 2011 and August 2012. The isotopic dilution technique was used in the first experiment to assess the phosphorus availability in the soil and to determine the ability of plants to access labile phosphorus by measuring the specific activity of plants grown in soil labeled with radioactive phosphorus. Nine cultivars showed greater phosphorus uptake and used efficiency. The second experiment evaluated the root morphology and architecture. The cultivars with greater uptake efficiency have root morphology and architecture characteristics that favour acquisition of phosphorus from soil compartments that are inaccessible to other cultivars. Phosphorus uptake by plants was not affected by soybean seeds phosphorus content. Identification of these cultivars is very important because it could enable soybean farming in low fertility soils, reducing fertiliser dependence

Tracing star formation in galaxies with molecular line and continuum observations

We report our recent progress on extragalactic spectroscopic and continuum observations, including HCN(J=1-0), HCO$^+$(J=1-0), and CN(N=1-0) imaging surveys of local Seyfert and starburst galaxies using the Nobeyama Millimeter Array, high-J CO observations (J=3-2 observations using the Atacama Submillimeter Telescope Experiment (ASTE) and J=2-1 observations with the Submillimeter Array) of galaxies, and $\lambda$ 1.1 mm continuum observations of high-z violent starburst galaxies using the bolometer camera AzTEC mounted on ASTE.Comment: 6 pages, 5 figures, To appear in proceedings of "Far-Infrared and Submillimeter Emission of the Interstellar Medium", EAS Publication Series, Bad Honnef, November 2007, Eds. C. Kramer, S. Aalto, R. Simon. See http://www.nro.nao.ac.jp/~f0212kk/FIR07/kk-ver20.pdf for a version with high resolution figure

Preparation and characterization of epitaxial Fe2-xTixO3 films with various Ti concentrations (0.5 < x < 1.0)

An ilmenite-hematite solid solution ( Fe2-xTixO3 ) is one of the candidates for practical magnetic semiconductors with a high Curie temperature. We have prepared well-crystallized epitaxial Fe2-xTixO3 films with a wide range of Ti concentrations - x=0.50, 0.60, 0.65, 0.76, 0.87, and 0.94 - on &#945;-Al2O3(001) substrates. The films are prepared by a reactive helicon plasma sputtering technique to evaporate Fe and TiO targets simultaneously under optimized oxygen pressure conditions. The structural characterizations of the films reveal that all films have a single phase of the ordered structure with R3 symmetry, where Ti-rich and Fe-rich layers are stacked alternately along the c axis. All films have large ferrimagnetic moments at low temperature, and room temperature magnetization is clearly observed at x&#60;0.7. The inverse temperature dependence of the resistivities of the films indicates their semiconducting behavior. The film resistivities decrease with decreasing Ti concentration.</p