422 research outputs found
Highly Dispersed Palladium on Carbon Nanofibers for Hydrogenation of Nitrocompounds to Amines
The effect of palladium dispersion and nature of the support on catalytic performance in hydrogenation of nitrobenzene to aniline was studied. It was shown that the type of the support and modification of palladium with phosphorus make it possible to stabilize highly dispersed (1.5-2 nm) palladium particles in the metallic state, thus increasing the efficiency of new catalysts
Spin-flop transition in uniaxial antiferromagnets: magnetic phases, reorientation effects, multidomain states
The classical spin-flop is the field-driven first-order reorientation
transition in easy-axis antiferromagnets. A comprehensive phenomenological
theory of easy-axis antiferromagnets displaying spin-flops is developed. It is
shown how the hierarchy of magnetic coupling strengths in these
antiferromagnets causes a strongly pronounced two-scale character in their
magnetic phase structure. In contrast to the major part of the magnetic phase
diagram, these antiferromagnets near the spin-flop region are described by an
effective model akin to uniaxial ferromagnets. For a consistent theoretical
description both higher-order anisotropy contributions and dipolar stray-fields
have to be taken into account near the spin-flop. In particular,
thermodynamically stable multidomain states exist in the spin-flop region,
owing to the phase coexistence at this first-order transition. For this region,
equilibrium spin-configurations and parameters of the multidomain states are
derived as functions of the external magnetic field. The components of the
magnetic susceptibility tensor are calculated for homogeneous and multidomain
states in the vicinity of the spin-flop. The remarkable anomalies in these
measurable quantities provide an efficient method to investigate magnetic
states and to determine materials parameters in bulk and confined
antiferromagnets, as well as in nanoscale synthetic antiferromagnets. The
method is demonstrated for experimental data on the magnetic properties near
the spin-flop region in the orthorhombic layered antiferromagnet
(C_2H_5NH_3)_2CuCl_4.Comment: (15 pages, 12 figures; 2nd version: improved notation and figures,
correction of various typos
Permutable entire functions satisfying algebraic differential equations
It is shown that if two transcendental entire functions permute, and if one
of them satisfies an algebraic differential equation, then so does the other
one.Comment: 5 page
Symmetry Analysis of Second Harmonic Generation at Surfaces of Antiferromagnets
Using group theory we classify the nonlinear magneto-optical response at
low-index surfaces of fcc antiferromagnets, such as NiO. Structures consisting
of one atomic layer are discussed in detail. We find that optical second
harmonic generation is sensitive to surface antiferromagnetism in many cases.
We discuss the influence of a second type of magnetic atoms, and also of a
possible oxygen sublattice distortion on the output signal. Finally, our
symmetry analysis yields the possibility of antiferromagnetic surface domain
imaging even in the presence of magnetic unit-cell doubling.Comment: 23 pages, 10 figures incorporated. Accepted to Phys. Rev. B,
scheduled for July'9
On the possibility of magneto-structural correlations: detailed studies of di-nickel carboxylate complexes
A series of water-bridged dinickel complexes of the general formula [Ni<sub>2</sub>(Ό<sub>2</sub>-OH<sub>2</sub>)(Ό2-
O<sub>2</sub>C<sup>t</sup>Bu)<sub>2</sub>(O<sub>2</sub>C<sup>t</sup>Bu)2(L)(L0)] (L = HO<sub>2</sub>C<sup>t</sup>Bu, L0 = HO<sub>2</sub>C<sup>t</sup>Bu (1), pyridine (2),
3-methylpyridine (4); L = L0 = pyridine (3), 3-methylpyridine (5)) has been synthesized
and structurally characterized by X-ray crystallography. The magnetic properties
have been probed by magnetometry and EPR spectroscopy, and detailed measurements
show that the axial zero-field splitting, D, of the nickel(ii) ions is on the same order as
the isotropic exchange interaction, J, between the nickel sites. The isotropic exchange
interaction can be related to the angle between the nickel centers and the bridging
water molecule, while the magnitude of D can be related to the coordination sphere at
the nickel sites
Preoperative and perioperative use of levosimendan in cardiac surgery: European expert opinion
In cardiac surgery, postoperative low cardiac output has been shown to correlate with increased rates of organ failure and mortality. Catecholamines have been the standard therapy for many years, although they carry substantial risk for adverse cardiac and systemic effects, and have been reported to be associated with increased mortality. On the other hand, the calcium sensitiser and potassium channel opener levosimendan has been shown to improve cardiac function with no imbalance in oxygen consumption, and to have protective effects in other organs. Numerous clinical trials have indicated favourable cardiac and non-cardiac effects of preoperative and perioperative administration of levosimendan. A panel of 27 experts from 18 countries has now reviewed the literature on the use of levosimendan in on-pump and off-pump coronary artery bypass grafting and in heart valve surgery. This panel discussed the published evidence in these various settings, and agreed to vote on a set of questions related to the cardioprotective effects of levosimendan when administered preoperatively, with the purpose of reaching a consensus on which patients could benefit from the preoperative use of levosimendan and in which kind of procedures, and at which doses and timing should levosimendan be administered. Here, we present a systematic review of the literature to report on the completed and ongoing studies on levosimendan, including the newly commenced LEVO-CTS phase III study (NCT02025621), and on the consensus reached on the recommendations proposed for the use of preoperative levosimendan
The Julia sets and complex singularities in hierarchical Ising models
We study the analytical continuation in the complex plane of free energy of
the Ising model on diamond-like hierarchical lattices. It is known that the
singularities of free energy of this model lie on the Julia set of some
rational endomorphism related to the action of the Migdal-Kadanoff
renorm-group. We study the asymptotics of free energy when temperature goes
along hyperbolic geodesics to the boundary of an attractive basin of . We
prove that for almost all (with respect to the harmonic measure) geodesics the
complex critical exponent is common, and compute it
Coupling of the lattice and superlattice deformations and hysteresis in thermal expansion for the quasi one-dimensional conductor TaS
An original interferometer-based setup for measurements of length of
needle-like samples is developed, and thermal expansion of o-TaS crystals
is studied. Below the Peierls transition the temperature hysteresis of length
is observed, the width of the hysteresis loop being up to . The behavior of the loop is anomalous: the length changes so
that it is in front of its equilibrium value. The hysteresis loop couples with
that of conductivity. The sign and the value of the length hysteresis are
consistent with the strain dependence of the charge-density waves (CDW) wave
vector. With lowering temperature down to 100 K the CDW elastic modulus grows
achieving a value comparable with the lattice Young modulus. Our results could
be helpful in consideration of different systems with intrinsic
superstructures.Comment: 4 pages, 3 figures. Phys. Rev. Lett., accepted for publicatio
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