Formation of hydrogen peroxide and water from the reaction of cold hydrogen atoms with solid oxygen at 10K

The reactions of cold H atoms with solid O2 molecules were investigated at 10 K. The formation of H2O2 and H2O has been confirmed by in-situ infrared spectroscopy. We found that the reaction proceeds very efficiently and obtained the effective reaction rates. This is the first clear experimental evidence of the formation of water molecules under conditions mimicking those found in cold interstellar molecular clouds. Based on the experimental results, we discuss the reaction mechanism and astrophysical implications.Comment: 12 pages, 3 Postscript figures, use package amsmath, amssymb, graphic

Mineral Chemistry and Reflectance Spectra for the Anorthosite Clast in Lunar Meteorite Dhofar 489 with Reference to Lunar Farside Crust.

第2回極域科学シンポジウム/第34回南極隕石シンポジウム 11月18日（金） 国立国語研究所 2階講

Propagation of a hole on a Neel background

We analyze the motion of a single hole on a N\'eel background, neglecting spin fluctuations. Brinkman and Rice studied this problem on a cubic lattice, introducing the retraceable-path approximation for the hole Green's function, exact in a one-dimensional lattice. Metzner et al. showed that the approximationalso becomes exact in the infinite-dimensional limit. We introduce a new approach to this problem by resumming the Nagaoka expansion of the propagator in terms of non-retraceable skeleton-paths dressed by retraceable-path insertions. This resummation opens the way to an almost quantitative solution of the problemin all dimensions and, in particular sheds new light on the question of the position of the band-edges. We studied the motion of the hole on a double chain and a square lattice, for which deviations from the retraceable-path approximation are expected to be most pronounced. The density of states is mostly adequately accounted for by the retra\-ce\-able-path approximation. Our band-edge determination points towards an absence of band tails extending to the Nagaoka energy in the spectrums of the double chain and the square lattice. We also evaluated the spectral density and the self-energy, exhibiting k-dependence due to finite dimensionality. We find good agreement with recent numerical results obtained by Sorella et al. with the Lanczos spectra decoding method. The method we employ enables us to identify the hole paths which are responsible for the various features present in the density of states and the spectral density.Comment: 26 pages,Revte

Decay of Superconducting and Magnetic Correlations in One- and Two-Dimensional Hubbard Models

In a general class of one and two dimensional Hubbard models, we prove upper bounds for the two-point correlation functions at finite temperatures for electrons, for electron pairs, and for spins. The upper bounds decay exponentially in one dimension, and with power laws in two dimensions. The bounds rule out the possibility of the corresponding condensation of superconducting electron pairs, and of the corresponding magnetic ordering. Our method is general enough to cover other models such as the t-J model.Comment: LaTeX, 8 pages, no figures. A reference appeared after the publication is adde

Mott-Hubbard insulators for systems with orbital degeneracy

We study how the electron hopping reduces the Mott-Hubbard band gap in the limit of a large Coulomb interaction U and as a function of the orbital degeneracy N. The results support the conclusion that the hopping contribution grows as roughly \sqrt{N}W, where W is the one-particle band width, but in certain models a crossover to a \sim NW behavior is found for a sufficiently large N.Comment: 7 pages, revtex, 6 figures more information at http://www.mpi-stuttgart.mpg.de/dokumente/andersen/fullerene

Two quantum analogues of Fisher information from a large deviation viewpoint of quantum estimation

We discuss two quantum analogues of Fisher information, symmetric logarithmic derivative (SLD) Fisher information and Kubo-Mori-Bogoljubov (KMB) Fisher information from a large deviation viewpoint of quantum estimation and prove that the former gives the true bound and the latter gives the bound of consistent superefficient estimators. In another comparison, it is shown that the difference between them is characterized by the change of the order of limits.Comment: LaTeX with iopart.cls, iopart12.clo, iopams.st

Pseudospin SU(2) Symmetry Breaking, Charge Density Wave and Superconductivity in the Hubbard Model

In this paper, we discuss physical consequences of pseudospin SU(2) symmetry breaking in the negative-U Hubbard model at half-filling. If pseudospin symmetry is spontaneously broken while its unique subgroup U(1) remains invariant, it will lead to the charge density wave (CDW) ground state. Furthermore, if the U(1) symmetry is also broken, the ground state will have the off-diagonal long range order (ODLRO), signaling a superconductor. In this case, CDW and superconductivity coexist to form a supersolid. Finally, we show that CDW suppresses, but does not destroy superconductivity.Comment: 7 page

Gauge Invariance and Hall Terms in the Quasiclassical Equations of Superconductivity

This paper presents a careful derivation of the quasiclassical equations of superconductivity so that a manifest gauge invariance is retained with respect to the space-time arguments of the quasiclassical Green's function $\hat{g}$. The terms responsible for the Hall effect naturally appear from the derivation. The equations are applicable to clean as well as dirty superconductors for an arbitrary external frequency much smaller than the Fermi energy. Thus, they will form a basis toward a complete microscopic understanding of the Hall effect in type-II superconductors.Comment: 9 pages, 1 figur

Ferromagnetism in the two dimensional t-t' Hubbard model at the Van Hove density

Using an improved version of the projection quantum Monte Carlo technique, we study the square-lattice Hubbard model with nearest-neighbor hopping t and next-nearest-neighbor hopping t', by simulation of lattices with up to 20 X 20 sites. For a given R=2t'/t, we consider that filling which leads to a singular density of states of the noninteracting problem. For repulsive interactions, we find an itinerant ferromagnet (antiferromagnet) for R=0.94 (R=0.2). This is consistent with the prediction of the T-matrix approximation, which sums the most singular set of diagrams.Comment: 10 pages, RevTeX 3.0 + a single postscript file with all figure