Fingerprints of angulon instabilities in the spectra of matrix-isolated molecules

The formation of vortices is usually considered to be the main mechanism of angular momentum disposal in superfluids. Recently, it was predicted that a superfluid can acquire angular momentum via an alternative, microscopic route -- namely, through interaction with rotating impurities, forming so-called `angulon quasiparticles' [Phys. Rev. Lett. 114, 203001 (2015)]. The angulon instabilities correspond to transfer of a small number of angular momentum quanta from the impurity to the superfluid, as opposed to vortex instabilities, where angular momentum is quantized in units of $\hbar$ per atom. Furthermore, since conventional impurities (such as molecules) represent three-dimensional (3D) rotors, the angular momentum transferred is intrinsically 3D as well, as opposed to a merely planar rotation which is inherent to vortices. Herein we show that the angulon theory can explain the anomalous broadening of the spectroscopic lines observed for CH$_3$ and NH$_3$ molecules in superfluid helium nanodroplets, thereby providing a fingerprint of the emerging angulon instabilities in experiment.Comment: 7 pages + supplemen

An analytic model of rotationally inelastic collisions of polar molecules in electric fields

We present an analytic model of thermal state-to-state rotationally inelastic collisions of polar molecules in electric fields. The model is based on the Fraunhofer scattering of matter waves and requires Legendre moments characterizing the "shape" of the target in the body-fixed frame as its input. The electric field orients the target in the space-fixed frame and thereby effects a striking alteration of the dynamical observables: both the phase and amplitude of the oscillations in the partial differential cross sections undergo characteristic field-dependent changes that transgress into the partial integral cross sections. As the cross sections can be evaluated for a field applied parallel or perpendicular to the relative velocity, the model also offers predictions about steric asymmetry. We exemplify the field-dependent quantum collision dynamics with the behavior of the Ne-OCS($^{1}\Sigma$) and Ar-NO($^2\Pi$) systems. A comparison with the close-coupling calculations available for the latter system [Chem. Phys. Lett. \textbf{313}, 491 (1999)] demonstrates the model's ability to qualitatively explain the field dependence of all the scattering features observed

Sensitive imaging of electromagnetic fields with paramagnetic polar molecules

We propose a method for sensitive parallel detection of low-frequency electromagnetic fields based on the fine structure interactions in paramagnetic polar molecules. Compared to the recently implemented scheme employing ultracold $^{87}$Rb atoms [B{\"o}hi \textit{et al.}, Appl. Phys. Lett. \textbf{97}, 051101 (2010)], the technique based on molecules offers a 100-fold higher sensitivity, the possibility to measure both the electric and magnetic field components, and a probe of a wide range of frequencies from the dc limit to the THz regime

The Methods to Improve Quality of Service by Accounting Secure Parameters

A solution to the problem of ensuring quality of service, providing a greater number of services with higher efficiency taking into account network security is proposed. In this paper, experiments were conducted to analyze the effect of self-similarity and attacks on the quality of service parameters. Method of buffering and control of channel capacity and calculating of routing cost method in the network, which take into account the parameters of traffic multifractality and the probability of detecting attacks in telecommunications networks were proposed. The both proposed methods accounting the given restrictions on the delay time and the number of lost packets for every type quality of service traffic. During simulation the parameters of transmitted traffic (self-similarity, intensity) and the parameters of network (current channel load, node buffer size) were changed and the maximum allowable load of network was determined. The results of analysis show that occurrence of overload when transmitting traffic over a switched channel associated with multifractal traffic characteristics and presence of attack. It was shown that proposed methods can reduce the lost data and improve the efficiency of network resources.Comment: 10 pages, 1 figure, 1 equation, 1 table. arXiv admin note: text overlap with arXiv:1904.0520

Organizational and Pedagogical Problems of Additional Professional Education

The paper analyzes the basic requirements of professional and public accreditation to the organizational and pedagogical component of additional professional education. The research aims to analyze and characterize the main trends that determine the change in the requirements for the content evaluation and implementation of additional professional programs as one of the aspects of the professional education teacher. Based on the current trend analysis, the necessity of changes in additional professional programs is justified by (1) revision of the approach to the structure and content of additional professional programs, to teaching staff training ensuring their implementation; (2) solving the problem of the invariant and variable ratio of educational programs components; (3) considering the changes in qualification requirements, demands of the labor market, and employers to ensure the anticipatory character of specialists development

Multiple scattering of matter waves: an analytic model of the refractive index for atomic and molecular gases

We present an analytic model of the refractive index for matter waves propagating through atomic or molecular gases. The model, which combines a WKB treatment of the long range attraction with the Fraunhofer model treatment of the short range repulsion, furnishes a refractive index in compelling agreement with recent experiments of Jacquey et al. [Phys. Rev. Lett. 98, 240405 (2007)] on Li atom matter waves passing through dilute noble gases. We show that the diffractive contribution, which arises from scattering by a two dimensional "hard core" of the potential, is essential for obtaining a correct imaginary part of the refractive index.Comment: 5 pages, 1 figure, 2 table

Excited rotational states of molecules in a superfluid

We combine experimental and theoretical approaches to explore excited rotational states of molecules embedded in helium nanodroplets using CS$_2$ and I$_2$ as examples. Laser-induced nonadiabatic molecular alignment is employed to measure spectral lines for rotational states extending beyond those initially populated at the 0.37 K droplet temperature. We construct a simple quantum mechanical model, based on a linear rotor coupled to a single-mode bosonic bath, to determine the rotational energy structure in its entirety. The calculated and measured spectral lines are in good agreement. We show that the effect of the surrounding superfluid on molecular rotation can be rationalized by a single quantity -- the angular momentum, transferred from the molecule to the droplet.Comment: 5 pages, 4 figures; 5 pages, 3 figure

Rotational coherence spectroscopy of molecules in helium nanodroplets: Reconciling the time and the frequency domains

Alignment of OCS, CS$_2$ and I$_2$ molecules embedded in helium nanodroplets is measured as a function of time following rotational excitation by a non-resonant, comparatively weak ps laser pulse. The distinct peaks in the power spectra, obtained by Fourier analysis, are used to determine the rotational, B, and centrifugal distortion, D, constants. For OCS, B and D match the values known from IR spectroscopy. For CS$_2$ and I$_2$, they are the first experimental results reported. The alignment dynamics calculated from the gas-phase rotational Schr\"{o}dinger equation, using the experimental in-droplet B and D values, agree in detail with the measurement for all three molecules. The rotational spectroscopy technique for molecules in helium droplets introduced here should apply to a range of molecules and complexes.Comment: ASC and LC contributed equally. 7 pages, 3 figure

Features of silicon saturation of austenite pipe steel samples with different operating time

In the oil refining and petrochemical industries, the problem of premature failure of furnace equipment operating at high operating temperatures due to diffusion saturation of metal with structural elements with carbon is quite acute. Sections of coils of reaction furnaces operating under severe temperature conditions are especially often rejected due to carburization. The carbon saturation of the surface layers of the metal of the pipes to different depths leads to a change in the chemical composition and mechanical properties, and as a result, to a significant deterioration in plasticity, which increases the tendency to crack. One of the most significant causes of carburization of the metal of furnace tubes is coco-deposition along the inner surface of the tubes and this leads to a more intensive rotation of the mechanism of diffusion of carbon into the metal from coke. The rate and degree of carburization can be reduced or in some cases even prevented from forming surface modified silicon-based layers since it is silicon that is a carbon antagonist. In this regard, the current topic is the study of the features of silicon saturation of the surface layer of samples of austenitic pipe steel with different operating time