Yang--Mills sphalerons in all even spacetime dimensions d=2kd=2k, k>2k>2 : kk=3,4

The classical solutions to higher dimensional Yang--Mills (YM) systems, which are integral parts of higher dimensional Einstein--YM (EYM) systems, are studied. These are the gravity decoupling limits of the fully gravitating EYM solutions. In odd spacetime dimensions, depending on the choice of gauge group, these are either topologically stable or unstable. Both cases are analysed, the latter numerically only. In even spacetime dimensions they are always unstable, describing saddle points of the energy, and can be described as {\it sphalerons}. This instability is analysed by constructing the noncontractible loops and calculating the Chern--Simons (CS) charges, and also perturbatively by numerically constructing the negative modes. This study is restricted to the simplest YM system in spacetime dimensions $d=6,7,8$, which is amply illustrative of the generic case.Comment: 16 pages, 3 figures ; comments added, to appear in J. Phys.

Particle-like solutions to higher order curvature Einstein--Yang-Mills systems in d dimensions

We consider the superposition of the first two members of the gravitational hierarchy (Einstein plus first Gauss-Bonnet(GB)) interacting with the superposition of the first two members of the $SO_{(\pm)}(d)$ Yang--Mills hierarchy, in $d$ dimensions. Such systems can occur in the low energy effective action of string theory. Particle-like solutions %for the systems with only an Einstein term, and with only a GB term, in dimensions $d=6,8$ are constructed respectively. Our results reveal qualitatively new properties featuring double-valued solutions with critical behaviour. In this preliminary study, we have restricted ourselves to one-node solutions.Comment: 10 pages, 11 figure

Verbenone—the universal bark beetle repellent? Its origin, effects, and ecological roles

Bark beetles (Curculionidae: Scolytinae) spend most of their life in tissues of host plants, with several species representing economically relevant pests. Their behaviour is largely guided by complex olfactory cues. The compound verbenone was discovered early in the history of bark beetle pheromone research and is now sometimes referred to as a ‘universal bark beetle repellent’. However, some studies aiming to protect trees with verbenone have failed. In fact, most research effort has gone into applied studies, leaving many questions regarding the ecological functions of verbenone for various species unanswered. Here, we review and analyse the scientific literature from more than 50 years. Behavioural responses to verbenone are common among pest bark beetles (< 1% of scolytine species studied so far). Indeed, attraction is inhibited in 38 species from 16 genera, while some secondary species are unaffected or even attracted to verbenone. It is not clear whether the beetles can control the biosynthesis of verbenone; its release may not be an active signal by the beetles, but a passive cue resulting from microorganisms during host colonisation. In this context, we advocate to recognise a bark beetle and its microbiome as an entity (‘holobiont’), to better understand temporal release patterns and deduce the specific function of verbenone for a given species. Surprisingly, natural enemies are not commonly attracted by verbenone, but more taxa need to be studied. A better understanding of the ecological functions of verbenone will help to make verbenone-based tools more effective and improve integrated pest management strategies

1D Chains of Diruthenium Tetracarbonyl Sawhorse Complexes

The syntheses of five 1D coordination polymers containing the sawhorse‐type unit [Ru2(µ‐OAc)2(CO)4] linked by various bridging N,N‐donor ligands are reported. Various π‐conjugated linkers, such as trans‐[1,2‐bis(N‐methyl)imidazol‐2‐yl]ethylene (trans‐bie), pyrazine (pyz), 4,4′‐bipyridine (4,4′‐bipy) and 1,2‐bis(4‐pyridyl)ethylene (bpe) as well as the aliphatic linker 1,4‐diazabicyclo[2.2.2]octane (DABCO), were applied in the syntheses. The formation of 1D coordination polymers was proven by crystal structure determinations of two of the polymeric materials. The geometries and electronic structures of all polymers were analysed further by CASSCF/CASPT2 and DFT calculations based on monomeric model compounds. Finally, first attempts regarding deposition of the 1D chain, the sawhorse fragment and/or the ligands on a highly ordered pyrolytic graphite surface, analysed by STM measurements, are also reported