42 research outputs found

    Synthesis of functionalized diaryl alkanes from azines

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    146-151Substituted diaryl alkanes are synthesized from benzalazines and acetophenone/propiophenone azines via Friedel Craft`s reaction with substituted mono- and poly-nuclear aromatic hydrocarbons. Diaryl methanes/ethanes and propanes are obtained by reaction with benzalazine, N,N'-bis (1-phenyl) azine and N, N’-bis (1-propyl) azine, respectively

    A facile synthesis of 3,5,7-trisubstituted-4<i style="mso-bidi-font-style:normal">H</i>-[1,2]diazepines by microwave irradiation

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    1613-1618A novel approach for the synthesis of 3,5,7-trisubstituted-4H-[1,2]diazepine 5a-p from α,β-unsaturated 1,5-diketone 4 by the condensation of substituted acetophenones 1 with 1,3-dicarbonyl compound 3 in the presence of sodium tertiary butoxide has been described. The intermediate 4 reacts smoothly with hydrazine hydrate catalysed by PSSA in water under microwave irradiation to yield the product 5
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