Si Microwire Solar Cells: Improved Efficiency with a Conformal SiO₂ Layer

Silicon microwire arrays have attracted considerable attention recently due to the opportunity they present as highly efficient and cost-effective solar cells. In this study, we report on efficient Si microwire array solar cells with areas of 1 cm² and Air Mass 1.5 Global conversion efficiencies of up to 10.6%. These solar cells show an open-circuit voltage of 0.56 V, a short-circuit current density of 25.2 mA/cm², and a fill factor of 75.2%, with a silicon absorption region that is only 25 μm thick. In particular, the maximum overall efficiency of the champion device is improved from 8.71% to 10.6% by conformally coating the wires with a 200 nm thick SiO₂ layer. Optical measurements reveal that the layer reduces reflection significantly over the entire visible range

Filter-Free Image Sensor Pixels Comprising Silicon Nanowires with Selective Color Absorption

The organic dye filters of conventional color image sensors achieve the red/green/blue response needed for color imaging, but have disadvantages related to durability, low absorption coefficient, and fabrication complexity. Here, we report a new paradigm for color imaging based on all-silicon nanowire devices and no filters. We fabricate pixels consisting of vertical silicon nanowires with integrated photodetectors, demonstrate that their spectral sensitivities are governed by nanowire radius, and perform color imaging. Our approach is conceptually different from filter-based methods, as absorbed light is converted to photocurrent, ultimately presenting the opportunity for very high photon efficiency