47 research outputs found
{6,6′-Dimethoxy-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato}cobalt(II) dichloromethane disolvate
The title compound, [Co(C22H18N2O4)]·2CH2Cl2, was isolated from the reaction of N,N′(o-phenylene)bis(vanillalimine) (H2
L) with Co(SCN)2. The crystal structure contains a CoII ion surrounded by the L
2− ligand in a slightly distorted square-planar fashion. Intermolecular C—H⋯O hydrogen-bonding contacts between the dichloromethane solvent molecules and the methoxy or carboxylate O atoms are observed in the crystal structure. The planar complex molecules stack through inversion related π–π interactions between the six-membered rings of the vanillalimine half ligands. The distance between centroids is 3.498 (2) Å and the perpendicular distance is 3.345 Å. A partial stacking is observed with a centroid–centroid distance of 3.830 (2) Å, a perpendicular distance of 3.350 Å and a slippage of 1.856 Å
シンコバルトサンソサクタイ
京都大学0048新制・課程博士理学博士甲第1135号理博第225号新制||理||146(附属図書館)3153UT51-46-G120京都大学大学院理学研究科化学専攻(主査)教授 重松 恒信, 教授 藤永 太一郎, 教授 波多野 博行学位規則第5条第1項該当Kyoto UniversityDA