The contribution of electron collisions to rotational excitations of cometary water

The e-H2O collisional rate for exciting rotational transitions in cometary water is evaluated for conditions found in comet Halley during the Giotto spacecraft encounter. In the case of the O(sub 00) yields 1(sub 11) rotational transition, the e-H2O collisional rate exceeds that for excitation by neutral-neutral collisions at distances exceeding 3000 km from the cometary nucleus. Thus, the rotational temperature of the water molecule in the intermediate coma may be controlled by collisions with electrons rather than with neutral collisions, and the rotational temperature retrieved from high resolution infrared spectra of water in comet Halley may reflect electron temperatures rather than neutral gas temperature in the intermediate coma

The effect of electron collisions on rotational excitation of cometary water

The e-H2O collisional rate for exciting rotational transitions in cometary water is evaluated for conditions found in Comet Halley. The e-H2O collisional rate exceeds that for excitation by neutral-neutral collisions at distances exceeding 3000 km from the cometary nucleus, in the case of the O sub 00 yields 1 sub 11 transition. The estimates are based on theoretical and experimental studies of e-H2O collisions, on ion and electron parameters acquired in-situ by instruments on the Giotto and Vega spacecraft, and on results obtained from models of the cometary ionosphere. The contribution of electron collisions may explain the need for large water-water cross-sections in models which neglect the effect of electrons. The importance of electron collisions is enhanced for populations of water molecules in regions where their rotational lines are optically thick

The Search for Life on Mars

For centuries, the planet Mars has been regarded as a possible abode for life. Serious searches for the signatures of life began in the 19th century, and continue via telescopic investigations and landed missions. While early work focused on phenomenology and bordered on fantasy, modern scientific inquiry has emphasized the search for chemical signatures of life in the soil and rocks at the planet's surface, and the search for biomarker gases in the atmosphere. Living systems produce more than 90% of Earth's atmospheric methane; the balance is of geochemical origin. The discovery of methane on Mars will be described, along with the ongoing extended search for clues to its origins. The possible origins of Mars methane will be discussed in the context of terrestrial analogue sites where geologic and biologic methane production now occurs - ranging from sub-permafrost zones in the arctic to hydrothermal vents in the deep ocean. Terrestrial organisms that could prosper on Mars today will be mentioned. I will briefly touch upon experiments conducted by landed spacecraft, ranging from the Viking Life Science Experiments in 1976 to the impending Mars Science laboratory, and the Trace Gas Orbiter and ExoMars missions now being developed for flight in the coming decade

Messengers from the Early Solar System - Comets as Carriers of Cosmic Information

Viewed from a cosmic perspective, Earth is a dry planet yet its oceans are enriched in deuterium by a large factor relative to nebular hydrogen. Can comets have delivered Earth s water? The question of exogenous delivery of water and organics to Earth and other young planets is of critical importance for understanding the origin of Earth s water, and for assessing the possible existence of exo-planets similar to Earth. Strong gradients in temperature and chemistry in the proto-planetary disk, coupled with dynamical models, imply that comets from the Oort Cloud and Kuiper Disk reservoirs should have diverse composition. The primary volatiles in comets (ices native to the nucleus) provide the preferred metric, and taxonomies based on them are now beginning to emerge [1, 2, 3]. The measurement of cosmic parameters such as the nuclear spin temperatures for H2O, NH3, and CH4, and of enrichment factors for isotopologues (D/H in water and hydrogen cyanide, N-14/N-15 in CN and hydrogen cyanide) provide additional important tests for the origin of cometary material

The contribution of methanol to the 3.4 micron feature in comets

With the advent of improved detectors and improved moderate resolution spectrometers several interesting features have been seen in the infrared spectra of comets. In particular, an emission excess at 3.52 microns was observed in several comets, and has recently been tentatively assigned to the nu 3 band of methanol (CH3OH). Using a developed model it is possible to calculate the relative strengths of the CH3OH features. The 3.52 microns emission strengths were used in a number of comets to retrieve methanol amounts, and the model was used to predict the fraction of the 3.4 micron flux which is contributed by the species. Implications for cometary formation are discussed

The Search for Life on Mars - Current Knowledge, Earth Analogues, and Principal Issues

For centuries, the planet Mars has been imagined as a possible abode for life. Serious searches for life's signatures began in the 19th century via ground-based visual astronomy that stimulated a vibrant fantasy literature but little lasting scientific knowledge. Modern scientific inquiry has emphasized the search for chemical signatures of life in the soil and rocks at the planet's surface, and via biomarker gases in the atmosphere. Today, investigations are based on high-resolution spectroscopy at Earth's largest telescopes along with planet orbiting and landed space missions. Methane has assumed central importance in these searches. Living systems produce more than 900/0 of Earth's atmospheric methane; the balance is of geochemical origin. Abundant methane is not expected in an oxidizing atmosphere such as Mars', and its presence would imply recent release - whether biological or geochemical. F or that reason, the quest for methane on Mars has been a continuing thread in the fabric of searches conducted since 1969. I will review aspects of the discovery and distribution of methane on Mars, and will mention ongoing extended searches for clues to its origin and destruction. On Earth, hydrogen (generated via serpentinization or radiolysis of water) provides an important 'fuel' for carbonate-reducing and sulphate-reducing biota (CH4 and H2S producers, respectively). Several such communities are known to reside at depth in continental domains (e.g., Lidy Hot Springs, Idaho; Witwatersrand Basin, S. Africa). If similar conditions exist in favourable locations on Mars, organisms similar to these could likely prosper there. Geologic (abiotic) production will also be mentioned, especially abiotic methane production associated with low-temperature serpentinization (e.g., terrestrial ophiolites). It is vitally important to pursue evidence for geochemical and biological production with equal vigour and intellectual weight lest unwanted and unintended bias contaminate the results. Finally, I will touch upon unresolved questions and issues posed by the methane detections

Messengers from the Early Solar System - The Similarity and Diversity of Comets

Viewed from a cosmic perspective, Earth is a dry planet yet its oceans are enriched in deuterium by a large factor relative to nebular hydrogen. Can comets have delivered Earth's water? The question of exogenous delivery of water and organics to Earth and other young planets is of critical importance for understanding the origin of Earth's water, and for assessing the possible existence of exo-planets similar to Earth. Strong gradients in temperature and chemistry in the proto-planetary disk, coupled with dynamical models, imply that comets from the Oort Cloud and Kuiper Disk reservoirs should have diverse composition. The primary volatiles in comets (ices native to the nucleus) provide the preferred metric, and taxonomies based on them are now beginning to emerge [1,2,3]. The measurement of cosmic parameters such as the nuclear spin temperatures for H2O, NH3, and CH4, and of enrichment factors for isotopologues (D/H in water and hydrogen cyanide, N-14/N-15 in CN and hydrogen cyanide provide additional important tests for the origin of cometary material. I will provide an overview of these aspects, and their implications for the origin of Earth's water and prebiotic organics

Engineering planetary lasers for interstellar communication

Spacefaring skills evolved in the twenty-first century will enable missions of unprecedented complexity. One such elaborate project might be to develop tools for efficient interstellar data transfer. Informational links to other star systems would facilitate eventual human expansion beyond our solar system, as well as intercourse with potential extraterrestrial intelligence. This paper reports the major findings of a 600-page, 3-year, NASA-funded study examining in quantitative detail the requirements, some seemingly feasible methods, and implications of achieving reliable extrasolar communications

Infrared monitoring of the Space Station environment

The measurement and monitoring of infrared emission in the environment of the Space Station has a twofold importance - for the study of the phenomena itself and as an aid in planning and interpreting Station based infrared experiments. Spectral measurements of the infrared component of the spacecraft glow will, along with measurements in other spectral regions, provide data necessary to fully understand and model the physical and chemical processes producing these emissions. The monitoring of the intensity of these emissions will provide background limits for Space Station based infrared experiments and permit the determination of optimum instrument placement and pointing direction. Continuous monitoring of temporal changes in the background radiation (glow) will also permit better interpretation of Station-based infrared earth sensing and astronomical observations. The primary processes producing infrared emissions in the Space Station environment are: (1) Gas phase excitations of Station generated molecules ( e.g., CO2, H2O, organics...) by collisions with the ambient flux of mainly O and N2. Molecular excitations and generation of new species by collisions of ambient molecules with Station surfaces. They provide a list of resulting species, transition energies, excitation cross sections and relevant time constants. The modeled spectrum of the excited species occurs primarily at wavelengths shorter than 8 micrometer. Emissions at longer wavelengths may become important during rocket firing or in the presence of dust

Infrared remote sensing of cometary parent volatiles from the ground, air, and space

A balanced view of the present generation of infrared instruments for cometary compositional studies is presented. Ground-based instruments are compared with airborne and spaceborne capabilities. An attempt to give examples of the unique science achievable with each is made, and particular emphasis is on the unique aspects of a dedicated Cometary Composition Telescope in earth orbit for investigating the chemical and structural heterogeneity of the cometary nucleus