Towards a statistical theory of transport by strongly-interacting lattice fermions

We present a study of electric transport at high temperature in a model of strongly interacting spinless fermions without disorder. We use exact diagonalization to study the statistics of the energy eigenvalues, eigenstates, and the matrix elements of the current. These suggest that our nonrandom Hamiltonian behaves like a member of a certain ensemble of Gaussian random matrices. We calculate the conductivity $\sigma(\omega)$ and examine its behavior, both in finite size samples and as extrapolated to the thermodynamic limit. We find that $\sigma(\omega)$ has a prominent non-divergent singularity at $\omega=0$ reflecting a power-law long-time tail in the current autocorrelation function that arises from nonlinear couplings between the long-wavelength diffusive modes of the energy and particle number

Size dependent magnetic properties and cation inversion in chemically synthesized MnFe2O4 nanoparticles

MnFe2O4nanoparticles with diameters ranging from about 4to50nm were synthesized using a modified coprecipitation method. X-ray diffractograms revealed a pure phase spinel ferrite structure for all samples. Transmission electron microscopy showed that the particles consist of a mixture of both spherical (smaller) and cubic (larger) particles dictated by the reaction kinetics. The Néel temperatures (TN) of MnFe2O4 for various particle sizes were determined by using high temperature magnetometry. The ∼4nm MnFe2O4 particles showed a TN of about 320°C whereas the ∼50nm particles had a TN of about 400°C. The high Néel temperature, compared with the bulk MnFe2O4 TN of 300°C, is due to a change in cation distribution between the tetrahedral and octahedral sites of the spinel lattice. Results of extended x-ray absorption fine structure measurements indicate a systematic change in the cation distribution dependent on processing conditions

Rapid thermal analysis of energetic materials with microfabricated differential scanning calorimeters

Abstract not provide

On the cyclotron line in Cepheus X-4

Context. Accreting X-ray pulsars provide us with laboratories for the study of extreme gravitational and magnetic fields, hence accurate descriptions of their observational properties contribute to our understanding of this group of objects. Aims. We aim to detect a cyclotron resonance scattering feature in the Be/X-ray binary Cep X-4 and to investigate pulse profile and spectral changes through the outburst. Methods. Spectral fitting and timing analysis are employed to probe the properties of Cep X-4 during an outburst in 2002 June. Results. A previously announced cyclotron feature at 30.7 keV is confirmed, while the source shows spectral behaviour and luminosity related changes similar to those observed in previous outbursts. The long-term X-ray lightcurve shows a periodicity at 20.85 d, which could be attributed to the orbit in this Be system

Pt-Sn/C as a possible methanol-tolerant cathode catalyst for DMFC

An effective method was developed for preparing highly dispersed nano-sized Pt–Sn/C electrocatalyst synthesised by a modified polyol reduction method. From XRD patterns, the Pt–Sn/C peaks shifted slightly to lower 2θ angles when compared with commercial Pt/C catalyst, suggesting that Sn formed alloy with Pt. Based on HR-TEM images, the Pt–Sn/C nanoparticles showed small particle sizes and well dispersed onto the carbon support with a narrow particle distribution. The methanol oxidation reaction on the as-prepared Pt–Sn/C catalyst appeared at lower currents (+7.08 mA at +480 mV vs. Ag/AgCl) compared to the commercial Pt/C (+8.25 mA at +480 mV vs. Ag/AgCl) suggesting that the Pt–Sn/C catalyst has ‘methanol tolerance capabilities’. Pt–Sn/C HA Slurry pH3 catalysts showed better activity towards the oxygen-reduction reaction (ORR) than commercial Pt/C which could be attributed to smaller particle sizes. In our study, the Pt–Sn/C catalyst appears to be a promising methanol-tolerant catalyst with activity towards the ORR in the DMFC.Web of Scienc

Preference-Based Trajectory Generation

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/76820/1/AIAA-36214-892.pd

Palladium-Ceria Catalysts with Enhanced Alkaline Hydrogen Oxidation Activity for Anion Exchange Membrane Fuel Cells

International audienc

Entanglement, combinatorics and finite-size effects in spin-chains

We carry out a systematic study of the exact block entanglement in XXZ spin-chain at Delta=-1/2. We present, the first analytic expressions for reduced density matrices of n spins in a chain of length L (for n<=6 and arbitrary but odd L) of a truly interacting model. The entanglement entropy, the moments of the reduced density matrix, and its spectrum are then easily derived. We explicitely construct the "entanglement Hamiltonian" as the logarithm of this matrix. Exploiting the degeneracy of the ground-state, we find the scaling behavior of entanglement of the zero-temperature mixed state.Comment: 5 pages, 4 figures, one mathematica file attache