Effects of impurities on the ice microstructure of Monte Perdido Glacier, Central Pyrenees, NE Spain

Monte Perdido Glacier, located in the central Pyrenees, is one of the southernmost glaciers in Europe. Due to climate change, this glacier is suffering an accelerated mass loss, especially in the last decades. If the current trends persist, this glacier is expected to disappear in the next 50 years. As part of the efforts of the scientific community to increase the knowledge about this glacier, this research presents the first microstructural characterization of the Monte Perdido Glacier, focused on a high-impurity concentration segment that belongs to an ice core drilled in 2017. The results reveal the ice has a layering defined by air bubbles and non-soluble impurities. The bubble-defined layering exhibits features of both a primary (sedimentary) and a secondary (strain-induced) origin. We found a clear inverse correspondence between the particle concentration and the grains' size and roundness index. A preliminary micro-Raman characterization of the particles shows the occurrence of atacamite, anatase (likely related to ancient mining activities in the vicinity of the glacier) and quartz. The latter could be an indicator of mineral dust, probably suggesting the arrival of dust-laden air masses from the north of the African continent.This research was supported by the Spanish Government through the María de Maeztu excellence accreditation 2018–2022 (MDM-2017-0714) and by the Spanish Agencia Estatal de Investigación (AEI Spain) through the projects PaleoICE EXPLORA (CGL2015-72167-EXP) and iMechPro (RTI2018-100696-B-I00). NGS acknowledges a PhD grant from the Basque Government (PRE-2018-1-0116). We thank the directorate of the Parque Nacional de Ordesa y Monte Perdido (Spain) for permission to investigate the Monte Perdido glacier. We also thank Ibai Rico ( https://basquemountainguides.com/ , UPV/EHU), Maria Leunda (UPV/EHU), and Juan Ignacio López-Moreno (IPE-CSIC) for their help during the sampling of the MP1 ice core, and Pedro Sanchez Navarrete (IPE-CSIC) for transporting the ice samples. Finally, we would like to extend our appreciation to the anonymous reviewers, the Scientific Editor, Christine Hvidberg, and the Chief Editor, Hester Jiskoot, for their valuable comments on this manuscript

Development of a low-temperature immersion microscopy technique for ice research

Perennial ice can be studied for many purposes, including paleoclimate records or rheological properties. For most of those purposes, the ice microstructure must be studied, often through optical microscopy. The aim of this work is to assess the viability of immersion microscopy for the study of ice microstructures. It consists of using an oil between the objective lens and the specimen, to increase image resolution. Immersion microscopy is a technique well-developed for the investigation of diverse materials, but it has so far not been explored for ice research. Here we investigate the challenges and advantages of that technique. The main challenge is related to the selection of the immersion oil itself, which must satisfy a number of criteria, ranging from refractive index and viscosity to toxicity and reactivity. We identify pure silicone oil (dimethicone) as a simple and safe option for immersion microscopy of inner ice structures. Among its advantages, it provides higher resolution (compared to standard 'dry' microscopy) and it can be simultaneously used as a long-term coating to prevent undesired sublimation of the ice-sample surfaces. For the observation of surface structures, however, another type of oil with higher refractive index should be used. Copyright © The Author(s), 2024. Published by Cambridge University Press on behalf of The International Glaciological Society.Perennial ice can be studied for many purposes, including paleoclimate records or rheological properties. For most of those purposes, the ice microstructure must be studied, often through optical microscopy. The aim of this work is to assess the viability of immersion microscopy for the study of ice microstructures. It consists of using an oil between the objective lens and the specimen, to increase image resolution. Immersion microscopy is a technique well-developed for the investigation of diverse materials, but it has so far not been explored for ice research. Here we investigate the challenges and advantages of that technique. The main challenge is related to the selection of the immersion oil itself, which must satisfy a number of criteria, ranging from refractive index and viscosity to toxicity and reactivity. We identify pure silicone oil (dimethicone) as a simple and safe option for immersion microscopy of inner ice structures. Among its advantages, it provides higher resolution (compared to standard 'dry' microscopy) and it can be simultaneously used as a long-term coating to prevent undesired sublimation of the ice-sample surfaces. For the observation of surface structures, however, another type of oil with higher refractive index should be used. Copyright © The Author(s), 2024. Published by Cambridge University Press on behalf of The International Glaciological Society