3,972 research outputs found
Nonlinear Conduction by Melting of Stripe-Type Charge Order in Organic Conductors with Triangular Lattices
We theoretically discuss the mechanism for the peculiar nonlinear conduction
in quasi-two-dimensional organic conductors \theta-(BEDT-TTF)2X
[BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene] through the melting of
stripe-type charge order. An extended Peierls-Hubbard model attached to
metallic electrodes is investigated by a nonequilibrium Green's function
technique. A novel current-voltage characteristic appears in a coexistent state
of stripe-type and nonstripe 3-fold charge orders, where the applied bias melts
mainly the stripe-type charge order through the reduction of lattice
distortion, whereas the 3-fold charge order survives. These contrastive
responses of the two different charge orders are consistent with the
experimental observations.Comment: 5 pages, 4 figures, to appear in J. Phys. Soc. Jp
Multi-Orbital Molecular Compound (TTM-TTP)I_3: Effective Model and Fragment Decomposition
The electronic structure of the molecular compound (TTM-TTP)I_3, which
exhibits a peculiar intra-molecular charge ordering, has been studied using
multi-configuration ab initio calculations. First we derive an effective
Hubbard-type model based on the molecular orbitals (MOs) of TTM-TTP; we set up
a two-orbital Hamiltonian for the two MOs near the Fermi energy and determine
its full parameters: the transfer integrals, the Coulomb and exchange
interactions. The tight-binding band structure obtained from these transfer
integrals is consistent with the result of the direct band calculation based on
density functional theory. Then, by decomposing the frontier MOs into two
parts, i.e., fragments, we find that the stacked TTM-TTP molecules can be
described by a two-leg ladder model, while the inter-fragment Coulomb energies
are scaled to the inverse of their distances. This result indicates that the
fragment picture that we proposed earlier [M.-L. Bonnet et al.: J. Chem. Phys.
132 (2010) 214705] successfully describes the low-energy properties of this
compound.Comment: 5 pages, 4 figures, published versio
The Origin of the Charge Ordering and Its Relevance to Superconductivity in -(BEDT-TTF)X: The Effect of the Fermi Surface Nesting and the Distant Electron-Electron Interactions
The origin of the charge ordering in organic compounds -(BEDT-TTF) ((SCN), Tl,Rb,Co, Cs,Zn) is studied using an extended
Hubbard model. Calculating the charge susceptibility within random phase
approximation (RPA), we find that the charge
ordering observed at relatively high temperatures can be considered as a
consequence of a cooperation between the Fermi surface nesting, controlled by
the hopping integral in the direction, and the electron-electron
interactions, where the distant (next nearest neighbor) interactions that have
not been taken into account in most of the previous studies play an important
role.Mean field analysis at T=0 also supports the RPA results, and further
shows that in the charge ordered state, some portions of the Fermi
surface remain ungapped and are nested with a nesting vector close to the
modulation wave vector of the horizontal stripe ordering observed at low
temperatures in (SCN). We further study the possibility of
superconductivity by taking into account the distant off-site repulsions and
the band structure corresponding to I, in which superconductivity is
experimentally observed. We find that there is a close competition between
-wave-like singlet pairing and -wave-like triplet pairing due
to a cooperation between the charge and the spin fluctuations. The present
analysis provides a possible unified understanding of the experimental phase
diagram of the -(BEDT-TTF) family, ranging from a charge ordered
insulator to a superconductor.Comment: 13 pages, 18 figures (Figs.5,6,7,14,15,18 compressed using jpeg2ps
Growth Dynamics of Photoinduced Domains in Two-Dimensional Charge-Ordered Conductors Depending on Stabilization Mechanisms
Photoinduced melting of horizontal-stripe charge orders in
quasi-two-dimensional organic conductors
\theta-(BEDT-TTF)2RbZn(SCN)4[BEDT-TTF=bis(ethylenedithio)tetrathiafulvalene]
and
\alpha-(BEDT-TTF)2I3 is investigated theoretically. By numerically solving
the time-dependent Schr\"odinger equation, we study the photoinduced dynamics
in extended Peierls-Hubbard models on anisotropic triangular lattices within
the
Hartree-Fock approximation. The melting of the charge order needs more energy
for \theta-(BEDT-TTF)2RbZn(SCN)4 than for \alpha-(BEDT-TTF)2I3, which is a
consequence of the larger stabilization energy in \theta-(BEDT-TTF)2RbZn(SCN)4.
After local photoexcitation in the charge ordered states, the growth of a
photoinduced domain shows anisotropy. In \theta-(BEDT-TTF)2RbZn(SCN)4, the
domain hardly expands to the direction perpendicular to the horizontal-stripes.
This is because all the molecules on the hole-rich stripe are rotated in one
direction and those on the hole-poor stripe in the other direction. They
modulate horizontally connected transfer integrals homogeneously, stabilizing
the charge order stripe by stripe. In \alpha-(BEDT-TTF)2I3, lattice distortions
locally stabilize the charge order so that it is easily weakened by local
photoexcitation. The photoinduced domain indeed expands in the plane. These
results are consistent with recent observation by femtosecond reflection
spectroscopy.Comment: 9 pages, 8 figures, to appear in J. Phys. Soc. Jpn. Vol. 79 (2010)
No.
Charge Order with Structural Distortion in Organic Conductors: Comparison between \theta-(ET)2RbZn(SCN)4 and \alpha-(ET)2I3
Charge ordering with structural distortion in quasi-two-dimensional organic
conductors \theta-(ET)2RbZn(SCN)4 (ET=BEDT-TTF) and \alpha-(ET)2I3 is
investigated theoretically. By using the Hartree-Fock approximation for an
extended Hubbard model which includes both on-site and intersite Coulomb
interactions together with Peierls-type electron-lattice couplings, we examine
the role of lattice degrees of freedom on charge order. It is found that the
experimentally observed, horizontal charge order is stabilized by lattice
distortion in both compounds. In particular, the lattice effect is crucial to
the realization of the charge order in \theta-(ET)2RbZn(SCN)4, while the
peculiar band structure whose symmetry is lower than that of
\theta-(ET)2RbZn(SCN)4 in the metallic phase is also an important factor in
\alpha-(ET)2I3 together with the lattice distortion. For \alpha-(ET)2I3, we
obtain a phase transition from a charge-disproportionated metallic phase to the
horizontal charge order with lattice modulations, which is consistent with the
latest X-ray experimental result.Comment: 10 pages, 13 figures, to appear in J. Phys. Soc. Jpn. Vol. 77 (2008)
No.
Theory of the beta-type Organic Superconductivity under Uniaxial Compression
We study theoretically the shift of the superconducting transition
temperature (Tc) under uniaxial compression in beta-type organic
superconductors, beta-(BEDT-TTF)2I3 and beta-(BDA-TTP)2X[X=SbF6,AsF6], in order
to clarify the electron correlation, the spin frustration and the effect of
dimerization. The transfer integrals are calculated by the extended Huckel
method assuming the uniaxial strain and the superconducting state mediated by
the spin fluctuation is solved using Eliashberg's equation with the
fluctuation-exchange approximation. The calculation is carried out on both the
dimerized (one-band) and nondimerized (two-band) Hubbard models. We have found
that (i) the behavior of Tc in beta-(BEDT-TTF)2I3 with a stronger dimerization
is well reproduced by the dimer model, while that in weakly dimerized
beta-BDA-TTP salts is rather well reproduced by the two-band model, and (ii)
the competition between the spin frustration and the effect induced by the
fluctuation is important in these materials, which causes nonmonotonic shift of
Tc against uniaxial compression.Comment: 18 pages, 16 figures, 2 tabl
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