3,111 research outputs found
Performance of alumina-supported Pt catalysts in an electron-beam-sustained CO2 laser amplifier
The performance of an alumina-supported Pt catalyst system used to maintain the gas purity in an electron-beam-sustained (636) isotope CO2 laser amplifier has been tested. The system characteristics using the two-zone, parallel flow reactor were determined for both continuous- and end-of-day reactor operation using on-line mass spectrometric sampling. The laser amplifier was run with an energy loading of typically 110 J-l/atm and an electron-beam current of 4 mA/sq cm. With these conditions and a pulse repetition frequency of 10 Hz for up to 10,000 shots, increases on the order of 100 ppm O2 were observed with the purifier on and 150 ppm with it off. The 1/e time recovery time was found to be approximately 75 minutes
On the effect of Ti on Oxidation Behaviour of a Polycrystalline Nickel-based Superalloy
Titanium is commonly added to nickel superalloys but has a well-documented
detrimental effect on oxidation resistance. The present work constitutes the
first atomistic-scale quantitative measurements of grain boundary and bulk
compositions in the oxide scale of a current generation polycrystalline nickel
superalloy performed through atom probe tomography. Titanium was found to be
particularly detrimental to oxide scale growth through grain boundary
diffusion
Aortic calcification and femoral bone density are independently associated with left ventricular mass in patients with chronic kidney disease
Background
Vascular calcification and reduced bone density are prevalent in chronic kidney disease and linked to increased cardiovascular risk. The mechanism is unknown. We assessed the relationship between vascular calcification, femoral bone density and left ventricular mass in patients with stage 3 non-diabetic chronic kidney disease in a cross-sectional observational study.
Methodology and Principal Findings
A total of 120 patients were recruited (54% male, mean age 55±14 years, mean glomerular filtration rate 50±13 ml/min/1.73 m2). Abdominal aortic calcification was assessed using lateral lumbar spine radiography and was present in 48%. Mean femoral Z-score measured using dual energy x-ray absorptiometry was 0.60±1.06. Cardiovascular magnetic resonance imaging was used to determine left ventricular mass. One patient had left ventricular hypertrophy. Subjects with aortic calcification had higher left ventricular mass compared to those without (56±16 vs. 48±12 g/m2, P = 0.002), as did patients with femoral Z-scores below zero (56±15 vs. 49±13 g/m2, P = 0.01). In univariate analysis presence of aortic calcification correlated with left ventricular mass (r = 0.32, P = 0.001); mean femoral Z-score inversely correlated with left ventricular mass (r = −0.28, P = 0.004). In a multivariate regression model that included presence of aortic calcification, mean femoral Z-score, gender and 24-hour systolic blood pressure, 46% of the variability in left ventricular mass was explained (P<0.001).
Conclusions
In patients with stage 3 non-diabetic chronic kidney disease, lower mean femoral Z-score and presence of aortic calcification are independently associated with increased left ventricular mass. Further research exploring the pathophysiology that underlies these relationships is warranted
The weight of water
Leonardo da Vinci’s pioneering work on hydrostatics combined traditional knowledge and innovative empiricism in an attempt to understand an object fraught with paradox: the water-filled container
Affine extension of noncrystallographic Coxeter groups and quasicrystals
Unique affine extensions H^{\aff}_2, H^{\aff}_3 and H^{\aff}_4 are
determined for the noncrystallographic Coxeter groups , and .
They are used for the construction of new mathematical models for quasicrystal
fragments with 10-fold symmetry. The case of H^{\aff}_2 corresponding to
planar point sets is discussed in detail. In contrast to the cut-and-project
scheme we obtain by construction finite point sets, which grow with a model
specific growth parameter.Comment: (27 pages, to appear in J. Phys. A
Random fields on model sets with localized dependency and their diffraction
For a random field on a general discrete set, we introduce a condition that
the range of the correlation from each site is within a predefined compact set
D. For such a random field omega defined on the model set Lambda that satisfies
a natural geometric condition, we develop a method to calculate the diffraction
measure of the random field. The method partitions the random field into a
finite number of random fields, each being independent and admitting the law of
large numbers. The diffraction measure of omega consists almost surely of a
pure-point component and an absolutely continuous component. The former is the
diffraction measure of the expectation E[omega], while the inverse Fourier
transform of the absolutely continuous component of omega turns out to be a
weighted Dirac comb which satisfies a simple formula. Moreover, the pure-point
component will be understood quantitatively in a simple exact formula if the
weights are continuous over the internal space of Lambda Then we provide a
sufficient condition that the diffraction measure of a random field on a model
set is still pure-point.Comment: 21 page
Comparison of surface and column measurements of aerosol scattering properties over the western North Atlantic Ocean at Bermuda
Light scattering by size-resolved aerosols in near-surface air at Tudor
Hill, Bermuda, was measured between January and June 2009. Vertical
distributions of aerosol backscattering and column-averaged aerosol optical
properties were characterized in parallel with a micro-pulse lidar (MPL) and
an automated sun–sky radiometer. Comparisons were made between extensive
aerosol parameters in the column, such as the lidar-retrieved extinction at
400 m and the aerosol optical depth (AOD), and scattering was measured with a
surface nephelometer. Comparisons were also made for intensive parameters
such as the Ångström exponent and calculations using
AERONET(Aerosol Robotic Network)-derived
aerosol physical parameters (size distribution, index of refraction) and Mie
theory, and the ratio of submicron scattering to total scattering for size-segregated
nephelometer measurements. In these comparisons the <i>r</i><sup>2</sup> was
generally around 0.50. Data were also evaluated based on back trajectories.
The correlation between surface scattering and lidar extinction was highest
for flows when the surface scattering was dominated by smaller particles and
the flow had a longer footprint over land then over the ocean. The
correlation of AOD with surface scatter was similar for all flow regimes.
There was also no clear dependence of the atmospheric lapse rate, as
determined from a nearby radiosonde station, on flow regime. The
Ångström exponent for most flow regimes was 0.9–1.0, but for the
case of air originating from North America, but with significant time over
the ocean, the Ångström exponent was 0.57 ± 0.18. The submicron
fraction of aerosol near the surface (<i>R</i><sub>sub-surf</sub>) was significantly
greater for the flows from land (0.66 ± 0.11) than for the flows which
spent more time over the ocean (0.40 ± 0.05). When comparing
<i>R</i><sub>sub-surf</sub> and the column-integrated submicron scattering fraction,
<i>R</i><sub>sub-col</sub>, the correlation was similar, <i>r</i><sup>2</sup> = 0.50, but
<i>R</i><sub>sub-surf</sub> was generally less than <i>R</i><sub>sub-col</sub>, indicating more large
particles contributing to light scattering at the surface, contrary to
conditions over continents and for polluted continental transport over the
ocean. In general, though, the marginal correlations indicate that the column
optical properties are weakly correlated with the surface optical
measurements. Thus, if it is desired to associate aerosol chemical/physical
properties with their optical properties, it is best to use optical and
chemical/physical measurements with both collected at the surface or both
collected in the column
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