2 research outputs found
Sustainable Growth and Lipid Production from <i>Chlorella pyrenoidosa</i> Using N‑Doped Carbon Nanosheets: Unravelling the Role of Graphitic Nitrogen
The
advent of novel carbonaceous nanomaterials (CMs) associated
with microalgae paved an alternate way for the bioeconomic production
of biofuels as well as high value added compounds. Herein, we for
the first time, present a holistic approach for sustainable biomass
and lipid production from Chlorella pyrenoidosa, wherein CMs, namely N-doped carbon nanosheets (CNS) and N-doped
graphene nanosheets (NGS) were used as one of the algal growth supporting
factors. Doping carbon nanomaterials with nitrogen can effectively
tune its electronic structure and other intrinsic properties for efficient
photocatalysis. The utilization of CNS and NGS in this process lead
to rapid, environment friendly, and facile assimilation of biomass
and lipids for the development of nutraceuticals, pharmaceuticals,
and other bioenergy associated applications. Employing a suite of
characterization methods, the intrinsic structural and morphological
properties of CMs were revealed. Compared with control, the lipid
content obtained in the presence of undoped carbonized carbon materials
(CCM), CNS, and NGS were found to be around 1.5-, 2-, and 6-fold higher,
respectively, at similar growth conditions. We, therefore, envisage
that graphitic nitrogen rich NGS plays a pivotal role in enhancing
the lipid production from algae. This finding, therefore, exhibits
a promising potential to bring about a paradigm shift in the field
of bioenergy frameworks
Carbon Nanosheets Infused with Gold Nanoparticles as an Ultrasensitive Nose for Electrochemical Arsenic Sensing
Herein, we introduce
an eco-friendly electrochemical sensor based
on melamine-enriched nitrogen-doped carbon nanosheets decorated with
gold nanoparticles (Au-CNSm) for arsenic sensing. An extremely facile,
low-toxicity, biocompatible, and affordable hydrothermal technique
was adopted for the synthesis of the Au-CNSm nanocomposite. The Au-CNSm-integrated
sensing platform was optimized for electrode composition by cyclic
voltammetry (CV). Owing to the synergistic effects of melamine-enriched
carbon nanosheets (CNSm) and gold nanoparticles (AuNPs), the anodic
peak current increased in the Au-CNSm-modified sensing electrode as
compared to the CNSm-decorated platform. A wide linear range of 0.0001–100
μM and a low detection limit of 0.0001 μM were obtained.
The visual signals can be measured at a very minute concentration
of 0.0001 μM (0.1 ppb) on a screen-printed carbon electrode
(SPCE) modified with Au-CNSm. Hence, this electrode system clearly
outperformed the previously reported studies in terms of linear range,
limit of detection (LOD), and electrocatalytic activity for arsenic
sensing. Interestingly, the fabricated biosensor can be developed
as a point-of-care device for real-time environmental monitoring for
public safety. Henceforth, owing to exceptional attributes such as
portability, selectivity, and sensitivity, this device offers great
promise in modeling a revolutionary new class of electrochemical sensing
platforms for an ultrasensitive and reliable detection strategy for
arsenite (As(III))