2D/3D Metallic Nano-objects Self-Organized in an Organic Molecular Thin Film

We present the fabrication and investigation of the properties of nanocomposite structures consisting of two-dimensional (2D) and three-dimensional (3D) metallic nano-objects self-organized on the surface and inside of organic molecular thin-film copper tetrafluorophthalocyanine (CuPcF4). Metallic atoms, deposited under ultrahigh vacuum (UHV) conditions onto the organic ultrathin film, diffuse along the surface and self-assemble into a system of 2D metallic overlayers. At the same time, the majority of the metal atoms diffuse into the organic matrix and self-organize into 3D nanoparticles (NPs) in a well-defined manner. The evolution of the morphology and electronic properties of such structures as a function of nominal metal content is studied under UHV conditions using transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HR-TEM), and photoelectron spectroscopy (PES) techniques. Using HR-TEM, we have observed the periodicity of atomic planes of individual silver NPs. The steady formation of agglomerates from individual single nanocrystallites with intercrystallite boundaries is observed as well. PES reveals generally weak chemical interactions between silver and the organic matrix and n-doping of CuPcF4 at the initial stages of silver deposition, which is associated with charge transfer from the 2D wetting layer on the basis of core-level spectra shift analysis. Copyright © 2020 American Chemical Society

Measuring the thermal resistance of typical multi-layer building walls using the accelerated measurement method

This paper considers the application of accelerated thermal resistance measurement to typical constructions of multi-layer walls of buildings with thermal insulation. It is shown that it is possible to reduce the measurement time considering the results of preliminary modelling. The required calculations for some typical constructions of building walls were made. The examples of simulation results shown in this paper allow to reduce the thermal resistance measurement time by 15-20%. There can be made calculations for other structures of building walls, following the presented method

Method of Hydrogenous Fuel Usage to Increase the Efficiency in Tandem Diverse Temperature Oxidation System

This paper presents the results of estimation energy efficiency, the collation data of thermodynamic calculations and data on material balance for an assessment of electric and thermal components in considered ways to use convention products, performance enhancement in the tandem system containing the high-temperature fuel cell and the low-temperature fuel cell with full heat regeneration for hydrogenous fuel (CH4). The overall effective efficiency (ηΣef. making full use of the recovered heat) considered tandem system depends on the efficiency of its constituent fuel cells. The overall effective efficiency of the tandem installation including the fuel converter, separating system, high-temperature oxidation system, and hydrogen disposal system in case of fuel use in the low-temperature fuel cell, is higher than for each of the fuel cell elements separately

Method of Hydrogenous Fuel Usage to Increase the Efficiency in Tandem Diverse Temperature Oxidation System

This paper presents the results of estimation energy efficiency, the collation data of thermodynamic calculations and data on material balance for an assessment of electric and thermal components in considered ways to use convention products, performance enhancement in the tandem system containing the high-temperature fuel cell and the low-temperature fuel cell with full heat regeneration for hydrogenous fuel (CH4). The overall effective efficiency (ηΣef. making full use of the recovered heat) considered tandem system depends on the efficiency of its constituent fuel cells. The overall effective efficiency of the tandem installation including the fuel converter, separating system, high-temperature oxidation system, and hydrogen disposal system in case of fuel use in the low-temperature fuel cell, is higher than for each of the fuel cell elements separately

The simulation model for a flood management by flood control facilities

The rapid spread of storm floods over large areas requires flood management throughout the river basin by the creation an innovative system of flood control facilities of various functional purposes distributed in the area. The central part of the system is the hydro system with hydro power plant. In addition, the flood control facilities on the side tributaries with self-regulating reservoir are included in the system. To assess the effect of controlling extreme water discharges by flood control facilities, it is necessary to develop special mathematical models reflecting the specifics of their operation. Unified mathematical models of the operation modes of a hydro complex with hydroelectric power station and flood control facility are created. They are implemented in a computer program that provides the ability to determine the main parameters and operating characteristics of hydro systems when performing multivariate calculations in a wide range of initial data. This makes possible specifying the parameters and operation modes of each hydro system with the current economic and environmental requirements, to assess the energy-economic and environmental consequences in the operation of the system of flood control facilities distributed in the area. The article analyses the results of the extreme water discharge’s regulation by the hydro system on the main river and flood control facilities on the side tributaries, considering environmental requirements

The simulation model for a flood management by flood control facilities

The rapid spread of storm floods over large areas requires flood management throughout the river basin by the creation an innovative system of flood control facilities of various functional purposes distributed in the area. The central part of the system is the hydro system with hydro power plant. In addition, the flood control facilities on the side tributaries with self-regulating reservoir are included in the system. To assess the effect of controlling extreme water discharges by flood control facilities, it is necessary to develop special mathematical models reflecting the specifics of their operation. Unified mathematical models of the operation modes of a hydro complex with hydroelectric power station and flood control facility are created. They are implemented in a computer program that provides the ability to determine the main parameters and operating characteristics of hydro systems when performing multivariate calculations in a wide range of initial data. This makes possible specifying the parameters and operation modes of each hydro system with the current economic and environmental requirements, to assess the energy-economic and environmental consequences in the operation of the system of flood control facilities distributed in the area. The article analyses the results of the extreme water discharge’s regulation by the hydro system on the main river and flood control facilities on the side tributaries, considering environmental requirements

Biogas Potential Assessment of the Composite Mixture from Duckweed Biomass

The article presents the research results of anaerobic digestion processes in bioreactors of composite mixtures based on initial and residual biomass of Lemna minor duckweed and additives: inoculum (manure), food waste, and spent sorbents to determine biogas potential (biogas volume, methane content). Duckweed Lemna minor, which is widespread in freshwater reservoirs, is one of the promising aquatic vegetation species for energy use. Residual biomass is obtained by chemically extracting valuable components from the primary product. The purpose of the research was to evaluate the possibility of the energy potential of residual biomass of Lemna minor to reduce the consumption of fossil fuels and reduce greenhouse gas emissions. This is in line with the International Energy Agency (IEA) scenarios for the reduction of environmental impact. The obtained results confirm the feasibility of using this type of waste for biogas/biomethane production. The recommendations on the optimal composition of the mixture based on the residual biomass of Lemna minor, which will allow for an increase in biogas production, are given. The obtained data can be used in the design of bioreactors

Biogas Potential Assessment of the Composite Mixture from Duckweed Biomass

The article presents the research results of anaerobic digestion processes in bioreactors of composite mixtures based on initial and residual biomass of Lemna minor duckweed and additives: inoculum (manure), food waste, and spent sorbents to determine biogas potential (biogas volume, methane content). Duckweed Lemna minor, which is widespread in freshwater reservoirs, is one of the promising aquatic vegetation species for energy use. Residual biomass is obtained by chemically extracting valuable components from the primary product. The purpose of the research was to evaluate the possibility of the energy potential of residual biomass of Lemna minor to reduce the consumption of fossil fuels and reduce greenhouse gas emissions. This is in line with the International Energy Agency (IEA) scenarios for the reduction of environmental impact. The obtained results confirm the feasibility of using this type of waste for biogas/biomethane production. The recommendations on the optimal composition of the mixture based on the residual biomass of Lemna minor, which will allow for an increase in biogas production, are given. The obtained data can be used in the design of bioreactors

Technological Decision to Renewable Energy Usage Biogas for Off-grid Systems Consumption

This paper presents the results of the energy experiments based on electrochemical researches and the thermodynamic calculations, which are carried out on the hydrogenous fuel with the residual content of methane obtained from biogas selected organic waste. Energy indicators are examined in comparison to electrolysis hydrogen. The use of technical and electro physical indicators together with parameters of the fuel operating allowed assessing energy efficiency the module reformer - fuel cell running on a non-standard hydrogenous fuel. Numerical characteristic the efficiency of workflows fuel system reformer – fuel cell is about 39%. To operate the power installation with a predetermined capacity amount used of hydrogenous fuel is comparable to required electrolysis hydrogen amount. Shown the possibility of creation the systems of power supply based on new hydrogen technologies using renewable energy resources local waste. Confirms the relatively high efficiency the usage of hydrogenous fuel for the tasks of off-grid systems consumption

Technological Decision to Renewable Energy Usage Biogas for Off-grid Systems Consumption

This paper presents the results of the energy experiments based on electrochemical researches and the thermodynamic calculations, which are carried out on the hydrogenous fuel with the residual content of methane obtained from biogas selected organic waste. Energy indicators are examined in comparison to electrolysis hydrogen. The use of technical and electro physical indicators together with parameters of the fuel operating allowed assessing energy efficiency the module reformer - fuel cell running on a non-standard hydrogenous fuel. Numerical characteristic the efficiency of workflows fuel system reformer – fuel cell is about 39%. To operate the power installation with a predetermined capacity amount used of hydrogenous fuel is comparable to required electrolysis hydrogen amount. Shown the possibility of creation the systems of power supply based on new hydrogen technologies using renewable energy resources local waste. Confirms the relatively high efficiency the usage of hydrogenous fuel for the tasks of off-grid systems consumption