40 research outputs found
New cyclotetrasiloxanes bearing sila-alkyl substituted side chains and their applications as templates for gold nanowires
Get PDFX-ray crystal structures of [(Cy<sub>2</sub>NH<sub>2</sub>)]<sub>3</sub> [C<sub>6</sub>H<sub>3</sub>(CO<sub>3</sub>)]<sup>_</sup>4H<sub>2</sub>O and [<em>i</em>-Bu<sub>2</sub>NH<sub>2</sub>][(Me<sub>3</sub> SnO<sub>2</sub>C)2C6H<sub>3</sub>CO<sub>2</sub>]
Get PDFTwo new benzene tricarboxylato derivatives [(Cy2NH2)]3[C6H3(CO2)3]路4H2O (1) and [i-Bu2NH2][(Me3SnO2C)2 C6H3CO2] (2) have been synthesized and characterized by X-ray crystallography. In the solid state, compound 1 shows a three-dimensional structure involving intra- and intermolecular hydrogen bonds, whereas the X-ray structure of 2 consists of pentacoordinated Sn centers bonded to three methyl groups and two O atoms in a trans-O2SnC3 environment, bridged by oxyanions leading to a layered structure; the cation is involved in intramolecular hydrogen bonds
Synthesis of heterobimetallic tungsten acetylacetonate/alkoxide complexes and their application as molecular precursors to metal tungstates
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Reactivity of bis(cyclohexylammonium) 4-nitrophenylphosphate with SnMe<sub>3</sub>Cl. X-ray structure of 4-NO<sub>2 </sub>C<sub>6</sub> H<sub>4</sub> PO<sub>4</sub>(SnMe<sub>3</sub>)<sub>2路</sub>H<sub>2</sub>O
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Crystal and molecular structure of bis(di-<em>n-</em>propylammonium) dioxalatodiphenylstannate, [<em>n</em>-Pr<sub>2</sub>NH<sub>2</sub>]<sub>2</sub>[(C<sub>2</sub>O<sub>4</sub>)<sub>2</sub>SnPh<sub>2</sub>]
Get PDFThe first crystallographically-characterised Cu(II) xanthate
Get PDFAbstractThe copper(II) xanthate Cu(S2COEt)2路TMEDA (1) (TMEDA=N,N-tetramethylethylenediamine) has been synthesised and is the first structurally-characterised xanthate of copper in the +2 oxidation state. 1 has an octahedral cis, cis, cis-ligand arrangement about the metal, in which xanthate chelation is markedly asymmetric. Both bulk thermal decomposition and film growth by aerosol-assisted chemical vapour deposition (AACVD) using 1 as precursor lead to the formation of Cu2S
Synthesis, characterisation and crystal structure of [(CH<sub>3</sub>)<sub>2</sub>CH]<sub>2</sub>NH<sub>2</sub>(PhPO<sub>3</sub>H)<sub>2</sub>SnPh<sub>3</sub>
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