1 research outputs found
Rh(II)-Catalyzed Transannulation of <i>N</i>‑Sulfonyl-1,2,3-Triazoles with 2,1-Benzisoxazoles or 1,2-Benzisoxazoles
A RhÂ(II)-catalyzed
transannulation of <i>N</i>-sulfonyl-1,2,3-triazoles
with 2,1-benzisoxazoles has been developed, which affords an efficient
method for the synthesis of quinazoline derivatives. The transformation
represents an unprecedented example which utilizes <i>N</i>-sulfonyl-1,2,3-triazole as an aza-[2C]-component in cycloadditions.
Meanwhile, a RhÂ(II)-catalyzed formal [3 + 2] cycloaddition of <i>N</i>-sulfonyl-1,2,3-triazoles with 1,2-benzisoxazoles is also
presented, which enables the rapid synthesis of functionalized imidazole
derivatives