48 research outputs found
Bis(2,6-diaminopyridin-1-ium) hexaaquacobalt(II) disulfate dihydrate
In the title compound, (C5H8N3)2[Co(H2O)6](SO4)2·2H2O, the complete complex cation is generated by crystallographic inversion symmetry, such that the CoII cation is octahedrally coordinated by six water molecules. The organic cation is essentially planar, with a maximum deviation of 0.013 (1) Å. In the crystal structure, the ions and molecules are linked into a pseudo-layered three-dimensional supramolecular network via O—H⋯O and N—H⋯O hydrogen bonds. Weak intermolecular π–π interactions further stabilize the crystal structure [centroid–centroid distance = 3.5231 (4) Å]
Diguanidinium bis(μ-2-hydroxypropane-1,2,3-tricarboxylato)bis[diaquazincate(II)] dihydrate
The asymmetric unit of the title compound, (CH6N3)2[Zn2(C6H5O7)2(H2O)2]·2H2O, contains one-half of a centrosymmetric dizinc(II) complex anion, one guanidinium cation and one water molecule. Each ZnII ion is hexacoordinated by two citrate anions, one in a bidentate fashion and the second monodentate, and two water molecules in a distorted octahedral geometry. Intramolecular O—H⋯O hydrogen bonds add further stability to the molecular structure. In the crystal structure, molecules are linked into a three-dimensional framework by intermolecular N—H⋯O, O—H⋯O and C—H⋯O hydrogen bonds
N,N′-(Ethane-1,2-diyl)dibenzenesulfonamide
In the title compound, C14H16N2O4S2, the dihedral angle between the terminal phenyl rings is 77.07 (13)°. The geometries around the S atoms are distorted tetrahedral, with O—S—O angles of 120.66 (12) and 119.44 (11)°. In the crystal, molecules are stacked in columns along the a axis via intermolecular N—H⋯O and C—H⋯O hydrogen bonds
Tetrakis(2,6-diaminopyridinium) diphthalate 2,6-diaminopyridine
In the title compound, 4C5H8N3
+·2C8H4O4
2−·C5H7N3, the asymmetric unit consists of two protonated diaminopyridine cations, one phthalate anion and one half of a diaminopyridine molecule, which has twofold rotation symmetry and is disordered over two positions with a site-occupancy ratio of 0.534 (3):0.466 (3). In the disordered structure, both pyridine rings are essentially planar, with maximum deviations of 0.011 (2) and 0.006 (2) Å, and these two rings are inclined to one another at a dihedral angle of 79.86 (10)°. In the crystal structure, intermolecular N—H⋯O and C—H⋯O hydrogen bonds link the ions and molecules into a three-dimensional network. The structure is further stabilized by C—H⋯π interactions
Bis(2,6-diaminopyridinium) bis(hydrogen oxalate) monohydrate
The asymmetric unit of the title compound, 2C5H8N3
+·2C2HO4
−·H2O, contains two crystallographically independent 2,6-diaminopyridinium cations, a pair of hydrogen oxalate anions and a water molecule. Both 2,6-diaminopyridinium cations are planar, with maximum deviations of 0.011 (2) and 0.015 (1) Å, and are protonated at the pyridine N atoms. The hydrogen oxalate anions adopt twisted conformations and the dihedral angles between the planes of their carboxyl groups are 31.01 (11) and 63.48 (11)°. In the crystal, the cations, anions and water molecules are linked via O—H⋯O and N—H⋯O hydrogen bonds, forming a three-dimensional network
Bis(2,6-diaminopyridinium) tartrate monohydrate
In the title compound, 2C5H8N3
+·C4H4O6
2−·H2O, the two cations are essentially planar [maximum deviations = 0.023 (1) and 0.026 (1) Å]. In one of the cations, the protonated N atom and one of the amino group H atoms are hydrogen bonded to one of the carboxyl groups of the dianion through a pair of N—H⋯O hydrogen bonds, forming an R
2
2(8) ring motif. In the crystal structure, the tartrate anions and water molecules are linked into chains along the c axis by intermolecular O—H⋯O and C—H⋯O hydrogen bonds. The cations further link the anions and water molecules into a three-dimensional extended structure by a network of N—H⋯O hydrogen bonds. The crystal structure is also stabilized by weak intermolecular π–π interactions [centroid–centroid distance = 3.6950 (6) Å]
Tetraguanidinium bis[citrato(3−)]cuprate(II) dihydrate
The asymmetric unit of the title compound, (CH6N3)4[Cu(C6H5O7)2]·2H2O, contains one-half of a centrosymmetric CuII complex anion, two guanidinium cations and a water molecule. The CuII ion, lying on a crystallographic inversion center, is hexacoordinated with two citrate anions in a distorted octahedral geometry. An intramolecular O—H⋯O hydrogen bond generates an S(6) ring motif. In the crystal structure, molecules are linked into a three-dimensional framework by intermolecular N—H⋯O and O—H⋯O hydrogen bonds
Naphthalen-1-aminium chloride
In the crystal structure of the title compound, C10H10N+·Cl−, the two components are connected via N—H⋯Cl hydrogen bonds, forming a layer parallel to the bc plane
2,6-Diaminopyridinium 2-carboxybenzoate
In the crystal of the title molecular salt, C5H8N3
+·C8H5O4
−, the diaminopyridine cation and the phthalate anion are linked by a pair of N—H⋯O hydrogen bonds. Within the phthalate anion, an almost symmetrical O—H⋯O hydrogen bond is observed. The ion pairs are linked by further N—H⋯O hydrogen bonds, generating a two-dimensional network lying parallel to (10)
2-Amino-4,6-dimethylpyridinium chloride dihydrate
In the title hydrated molecular salt, C7H11N2
+·Cl−·2H2O, the pyridine N atom of the 2-amino-4,6-dimethylpyridine molecule is protonated. The cation is essentially planar, with a maximum deviation of 0.006 (2) Å. In the crystal, the components are linked by N—H⋯O, N—H⋯Cl and O—H⋯Cl hydrogen bonds, thereby forming sheets lying parallel to (100). The crystal structure is further stabilized by aromatic π–π stacking interactions between the pyridinium rings [centroid–centroid distance = 3.4789 (9) Å]