Boric Acid Catalyzed Convenient Synthesis of Benzimidazoles in Aqueous Media

Synthesis of benzimidazoles has been developed by the o-phenylenediamine with aldehydes using boric acid an efficient catalyst under mild reaction conditions in aqueous media. The product is applicable to aryl and heteroaryl aldehydes. This reaction led to the formation of benzimidazoles new derivatives in good yields. The FT-IR, 19F-NMR, 1H-NMR, 13C-NMR spectra and elemental analysis confirm the structure of compounds

Efficient Knoevenagel Condensation Reactions Catalyzed by Activated Gel Zirconium(IV) Oxide

The condensation reaction has been carried out very conveniently to obtain the corresponding substituted 2,2′-(arylmethylene)bis(3-hydroxy-5,5-dimethylcyclohex-2-enone) in excellent yields. The reaction conditions are very mild and applicable to various aldehydes as well as active methylene compounds