6 research outputs found
Influence of operating parameters on electrocoagulation of C.I. disperse yellow 3
This work deals with the electrocoagulation (EC) process for an organic dye removal. The chosen organic dye is C.I. disperse yellow 3 (DY) which is used in textile industry. Experiments were performed in batch mode using Al electrodes and for comparison purposes Fe electrodes. The experimental set-up was composed of 1 L beaker, two identical electrodes which are separated 2 cm from each other. The main operating parameters influencing EC process were examined such as pH, supporting electrolyte concentration CNaCl, current density i, and DY concenÂtration. High performance EC process was shown during 45 min for 200 mg/L dye concentration at i = 350 A m-2 (applied voltage 12 V) and CNaCl = 1 g L-1 reaching 98 % for pHs 3 and 10 and 99 % for pH 6. After 10 min, DY was also efficiently removed (86 %) showing that EC process may be conveniently applied for textile industry wastewater treatment. EC using Fe electrodes exhibited slightly lower performance comparing EC using Al electrodes
Poly(styrene-co-butadiene)/Maghnia-Organo-Montmorillonite Clay Nanocomposite. Preparation, Properties and Application as Membrane in the Separation of Methanol/Toluene Azeotropic Mixture by Pervaporation
In order to improve the thermal and mechanical properties of poly(styrene-co-butadiene) (SBR) to use it as a pervaporation membrane in the separation of the azeotropic mixture toluene/methanol, poly(styrene-co-butadiene) crosslinked Maghnia-organo-montmonrillonite (CSBR/OMMT), a nanocomposite of different compositions was first prepared by a solvent casting method. SBR was crosslinked in situ in the presence of OMMT nanoparticles by an efficient vulcanization technique using sulfur as a crosslinking agent and zinc diethyldithiocarbamate as a catalyst. The structure and morphology of the hybrid materials obtained were characterized by Fourier transform infrared spectroscopy, X-ray diffraction, and scanning electron microscope analysis. The thermal properties of these hybrid materials were studied by differential scanning calorimetry and thermogravimetric analysis/thermal differential analysis. The mechanical properties were studied by strength measurements. The results obtained occurred when the OMMT was incorporated in the CSBR matrix; a significant increase in the glass transition temperature of the SBR was observed which passed from â27 °C for virgin SBR to â21.5 °C for that containing 12 wt% of OMMT. The addition of OMMT nanoparticles to CSBR also improved the mechanical properties of this copolymer. When the OMMT content in the CSBR varied from 0 to 15% by weight, the tensile strength, the elongation at the nose and the modulus at 100% elongation increased from 3.45 to 6.25 MPa, from 162, 17 to 347.20% and 1.75 to 3.0 MPa, respectively. The results of pervaporation revealed that when the OMMT content varied between 3% and 12%, a significant increase in the total flux, the separation factor and the separation index by pervaporation increased from 260.67 to g mâ2 hâ1, 0.31 to 1.43, and 0.47 to 113.81 g mâ2 hâ1, respectively