EFFECT OF THE GAS MEDIA AND TEMPERATURE REGIMES OF ANNEALING ON THE PHASE COMPOSITION OF IRON BORATE FeBO3

Iron borate FeBO3 crystals are annealed in neutral, oxidizing, and reducing gas media on a specially designed setup. The effect of the chemical medium and annealing modes on the surface morphology and phase composition of the samples is established.Исследования выполнены при финансовой поддержке РФФИ, проект № 19-29-12016-мк, в части разработки экспериментальной установки и получения кристаллических образцов. Рентгеновские и электронно-микроскопические измерения проведены при под-держке Министерства науки и высшего образования РФ в рамках выполнения работ по Государственному заданию ФНИЦ «Кристаллография и фотоника» с использованием оборудования ЦКП (проект RFMEFI62119X0035)

Anisotropic energy gap of low-frequency AFMR mode in Fe x Ga 1-x BO 3 single crystals

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Iron borate films: Synthesis and characterization

We report the first successful synthesis of iron borate films. FeBO 3 films on GaBO 3 single crystal sub strates have been prepared by a liquid phase epitaxy route. In order to determine optimal crystallization regimes, a series of experiments has been carried out. Electron microscope studies have allowed mon itoring different phases of the film formation. The compositions of the film and of the substrate have been determined by energy dispersive spectroscopy. X ray diffraction analysis has allowed an accurate determination of a mismatch between the lattice parameters of the film and of the substrate. Electron magnetic resonance studies of the FeBO 3 film confirm the existence of magnetic ordering. The values of the effective Dzyaloshinskii field as well as the Néel temperature are in good accordance with those previously determined for FeBO 3 single crystal