Mode coupling theory in the FDR-preserving field theory of interacting Brownian particles

We develop a renormalized perturbation theory for the dynamics of interacting Brownian particles, which preserves the fluctuation-dissipation relation order by order. We then show that the resulting one-loop theory gives a closed equation for the density correlation function, which is identical with that in the standard mode coupling theory.Comment: version to be published in Fast Track Communication in Journal of Physics A:Math. Theo

Spontaneous and induced dynamic correlations in glass-formers II: Model calculations and comparison to numerical simulations

We study in detail the predictions of various theoretical approaches, in particular mode-coupling theory (MCT) and kinetically constrained models (KCMs), concerning the time, temperature, and wavevector dependence of multi-point correlation functions that quantify the strength of both induced and spontaneous dynamical fluctuations. We also discuss the precise predictions of MCT concerning the statistical ensemble and microscopic dynamics dependence of these multi-point correlation functions. These predictions are compared to simulations of model fragile and strong glass-forming liquids. Overall, MCT fares quite well in the fragile case, in particular explaining the observed crucial role of the statistical ensemble and microscopic dynamics, while MCT predictions do not seem to hold in the strong case. KCMs provide a simplified framework for understanding how these multi-point correlation functions may encode dynamic correlations in glassy materials. However, our analysis highlights important unresolved questions concerning the application of KCMs to supercooled liquids.Comment: 23 pages, 12 fig

Nonlinear viscoelasticity of metastable complex fluids

Many metastable complex fluids such as colloidal glasses and gels show distinct nonlinear viscoelasticity with increasing oscillatory-strain amplitude; the storage modulus decreases monotonically as the strain amplitude increases whereas the loss modulus has a distinct peak before it decreases at larger strains. We present a qualitative argument to explain this ubiquitous behavior and use mode coupling theory (MCT) to confirm it. We compare theoretical predictions to the measured nonlinear viscoelasticity in a dense hard sphere colloidal suspensions; reasonable agreement is obtained. The argument given here can be used to obtain new information about linear viscoelasticity of metastable complex fluids from nonlinear strain measurements.Comment: 7 pages, 3 figures, accepted for publication in Europhys. Let

Cross-correlating the Thermal Sunyaev-Zel'dovich Effect and the Distribution of Galaxy Clusters

We present the analytical formulas, derived based on the halo model, to compute the cross-correlation between the thermal Sunyaev-Zel'dovich (SZ) effect and the distribution of galaxy clusters. By binning the clusters according to their redshifts and masses, this cross-correlation, the so-called stacked SZ signal, reveals the average SZ profile around the clusters. The stacked SZ signal is obtainable from a joint analysis of an arcminute-resolution cosmic microwave background (CMB) experiment and an overlapping optical survey, which allows for detection of the SZ signals for clusters whose masses are below the individual cluster detection threshold. We derive the error covariance matrix for measuring the stacked SZ signal, and then forecast for its detection from ongoing and forthcoming combined CMB-optical surveys. We find that, over a wide range of mass and redshift, the stacked SZ signal can be detected with a significant signal to noise ratio (total S/N \gsim 10), whose value peaks for the clusters with intermediate masses and redshifts. Our calculation also shows that the stacking method allows for probing the clusters' SZ profiles over a wide range of scales, even out to projected radii as large as the virial radius, thereby providing a promising way to study gas physics at the outskirts of galaxy clusters.Comment: 11 pages, 6 figures, 3 tables, minor revisions reflect PRD published versio

A Molecular Hydrodynamic Theory of Supercooled Liquids and Colloidal Suspensions under Shear

We extend the conventional mode-coupling theory of supercooled liquids to systems under stationary shear flow. Starting from generalized fluctuating hydrodynamics, a nonlinear equation for the intermediate scattering function is constructed. We evaluate the solution numerically for a model of a two dimensional colloidal suspension and find that the structural relaxation time decreases as $\dot{\gamma}^{-\nu}$ with an exponent $\nu \leq 1$, where $\dot{\gamma}$ is the shear rate. The results are in qualitative agreement with recent molecular dynamics simulations. We discuss the physical implications of the results.Comment: 5 pages, 1 figur

CIRCULAR DICHROISM OF LIGHT-HARVESTING COMPLEXES FROM PURPLE PHOTOSYNTHETIC BACTERIA

The CD spectra of a range of antenna complexes from several different species of purple photosynthetic bacteria were recorded in the wavelength range of 190 to 930 nm. Analysis of the far UV CD (190 to 250 nm) showed that in each case except for the B800-850 from Chr. vinosum the secondary structure of the light-harvesting complexes contains a large amount of α-helix (50%) and very little 0-pleated sheet. This confirms the predictions of the group of Zuber of a high a-helical content based upon consideration of the primary structures of several antenna apoproteins. The CD spectra from the carotenoids and the bacteriochlorophylls show considerable variations depending upon the type of antenna complex. The different amplitude ratios in the CD spectrum for the bacteriochlorophyll Qy, Qx and Soret bands indicate not only different degrees of exciton coupling, but also a strong and variable hyperchromism (Scherz and Parson, 1984a, b)