1,404 research outputs found
Recommended from our members
Direct introduction of nitrogen and oxygen functionality with spatial control using copper catalysis.
Synthetic chemists have spent considerable effort optimizing the synthesis of nitrogen and oxygen containing compounds through a number of methods; however, direct introduction of N- and O-functionality remains challenging. Presented herein is a general method to allow for the simultaneous installation of N- and O-functionality to construct unexplored N-O heterocyclic and amino-alcohol scaffolds. This transformation uses earth abundant copper salts to facilitate the formation of a carbon-centered radical and subsequent carbon-nitrogen bond formation. The intermediate aminoxyl radical is terminated by an intramolecularly appended carbon-centered radical. We have exploited this methodology to also access amino-alcohols with a range of aliphatic and aromatic linkers
Role of Disorder on the Quantum Critical Point of a Model for Heavy Fermions
A zero temperature real space renormalization group (RG) approach is used to
investigate the role of disorder near the quantum critical point (QCP) of a
Kondo necklace (XY-KN) model. In the pure case this approach yields
implying that any coupling between the local moments and the
conduction electrons leads to a non-magnetic phase. We also consider an
anisotropic version of the model (), for which there is a quantum phase
transition at a finite value of the ratio between the coupling and the
bandwidth, . Disorder is introduced either in the on-site interactions
or in the hopping terms. We find that in both cases randomness is irrelevant in
the model, i.e., the disorder induced magnetic-non-magnetic quantum
phase transition is controlled by the same exponents of the pure case. Finally,
we show the fixed point distributions at the atractors of the
disordered, non-magnetic phases.Comment: 5 pages, 3 figure
Non-Fermi liquid behavior and Griffiths phase in {\it f}-electron compounds
We study the interplay among disorder, RKKY and Kondo interactions in {\it
f}-electron alloys. We argue that the non-Fermi liquid behavior observed in
these systems is due to the existence of a Griffiths phase close to a quantum
critical point. The existence of this phase provides a unified picture of a
large class of materials. We also propose new experiments that can test these
ideas.Comment: 4 pages, 1 Figure. NEW version of the original manuscript. A single
framework for NFL behavior in different kinds of alloys is presented. Final
version finally allowed to appear on the glorious Physical Review Letter
OPS-γδ: allogeneic opsonin-secreting γδT cell immunotherapy for solid tumours mediates direct and bystander immunity
MSW mediated neutrino decay and the solar neutrino problem
We investigate the solar neutrino problem assuming simultaneous presence of
MSW transitions in the sun and neutrino decay on the way from sun to earth. We
do a global -analysis of the data on total rates in Cl, Ga and
Superkamiokande (SK) experiments and the SK day-night spectrum data and
determine the changes in the allowed region in the \dm - \tan^2\theta plane
in presence of decay. We also discuss the implications for unstable neutrinos
in the SNO experiment.Comment: Final version to appear in Phys. Rev.
Rare region effects at classical, quantum, and non-equilibrium phase transitions
Rare regions, i.e., rare large spatial disorder fluctuations, can
dramatically change the properties of a phase transition in a quenched
disordered system. In generic classical equilibrium systems, they lead to an
essential singularity, the so-called Griffiths singularity, of the free energy
in the vicinity of the phase transition. Stronger effects can be observed at
zero-temperature quantum phase transitions, at nonequilibrium phase
transitions, and in systems with correlated disorder. In some cases, rare
regions can actually completely destroy the sharp phase transition by smearing.
This topical review presents a unifying framework for rare region effects at
weakly disordered classical, quantum, and nonequilibrium phase transitions
based on the effective dimensionality of the rare regions. Explicit examples
include disordered classical Ising and Heisenberg models, insulating and
metallic random quantum magnets, and the disordered contact process.Comment: Topical review, 68 pages, 14 figures, final version as publishe
Quantum Griffiths effects and smeared phase transitions in metals: theory and experiment
In this paper, we review theoretical and experimental research on rare region
effects at quantum phase transitions in disordered itinerant electron systems.
After summarizing a few basic concepts about phase transitions in the presence
of quenched randomness, we introduce the idea of rare regions and discuss their
importance. We then analyze in detail the different phenomena that can arise at
magnetic quantum phase transitions in disordered metals, including quantum
Griffiths singularities, smeared phase transitions, and cluster-glass
formation. For each scenario, we discuss the resulting phase diagram and
summarize the behavior of various observables. We then review several recent
experiments that provide examples of these rare region phenomena. We conclude
by discussing limitations of current approaches and open questions.Comment: 31 pages, 7 eps figures included, v2: discussion of the dissipative
Ising chain fixed, references added, v3: final version as publishe
Clinical Manifestations and Case Management of Ebola Haemorrhagic Fever caused by a newly identified virus strain, Bundibugyo, Uganda, 2007-2008
A confirmed Ebola haemorrhagic fever (EHF) outbreak in Bundibugyo, Uganda, November 2007-February 2008, was caused by a putative new species (Bundibugyo ebolavirus). It included 93 putative cases, 56 laboratory-confirmed cases, and 37 deaths (CFR = 25%). Study objectives are to describe clinical manifestations and case management for 26 hospitalised laboratory-confirmed EHF patients. Clinical findings are congruous with previously reported EHF infections. The most frequently experienced symptoms were non-bloody diarrhoea (81%), severe headache (81%), and asthenia (77%). Seven patients reported or were observed with haemorrhagic symptoms, six of whom died. Ebola care remains difficult due to the resource-poor setting of outbreaks and the infection-control procedures required. However, quality data collection is essential to evaluate case definitions and therapeutic interventions, and needs improvement in future epidemics. Organizations usually involved in EHF case management have a particular responsibility in this respect
Local fluctuations in quantum critical metals
We show that spatially local, yet low-energy, fluctuations can play an
essential role in the physics of strongly correlated electron systems tuned to
a quantum critical point. A detailed microscopic analysis of the Kondo lattice
model is carried out within an extended dynamical mean-field approach. The
correlation functions for the lattice model are calculated through a
self-consistent Bose-Fermi Kondo problem, in which a local moment is coupled
both to a fermionic bath and to a bosonic bath (a fluctuating magnetic field).
A renormalization-group treatment of this impurity problem--perturbative in
, where is an exponent characterizing the spectrum
of the bosonic bath--shows that competition between the two couplings can drive
the local-moment fluctuations critical. As a result, two distinct types of
quantum critical point emerge in the Kondo lattice, one being of the usual
spin-density-wave type, the other ``locally critical.'' Near the locally
critical point, the dynamical spin susceptibility exhibits scaling
with a fractional exponent. While the spin-density-wave critical point is
Gaussian, the locally critical point is an interacting fixed point at which
long-wavelength and spatially local critical modes coexist. A Ginzburg-Landau
description for the locally critical point is discussed. It is argued that
these results are robust, that local criticality provides a natural description
of the quantum critical behavior seen in a number of heavy-fermion metals, and
that this picture may also be relevant to other strongly correlated metals.Comment: 20 pages, 12 figures; typos in figure 3 and in the main text
corrected, version as publishe
Thermodynamic analysis of the Quantum Critical behavior of Ce-lattice compounds
A systematic analysis of low temperature magnetic phase diagrams of Ce
compounds is performed in order to recognize the thermodynamic conditions to be
fulfilled by those systems to reach a quantum critical regime and,
alternatively, to identify other kinds of low temperature behaviors. Based on
specific heat () and entropy () results, three different types of
phase diagrams are recognized: i) with the entropy involved into the ordered
phase () decreasing proportionally to the ordering temperature
(), ii) those showing a transference of degrees of freedom from the
ordered phase to a non-magnetic component, with their jump
() vanishing at finite temperature, and iii) those ending in a
critical point at finite temperature because their do not decrease
with producing an entropy accumulation at low temperature.
Only those systems belonging to the first case, i.e. with as
, can be regarded as candidates for quantum critical behavior.
Their magnetic phase boundaries deviate from the classical negative curvature
below \,K, denouncing frequent misleading extrapolations down to
T=0. Different characteristic concentrations are recognized and analyzed for
Ce-ligand alloyed systems. Particularly, a pre-critical region is identified,
where the nature of the magnetic transition undergoes significant
modifications, with its discontinuity strongly
affected by magnetic field and showing an increasing remnant entropy at . Physical constraints arising from the third law at are discussed
and recognized from experimental results
- …