3,727 research outputs found
A note on Wigner-Yanase skew information-based uncertainty of quantum channels
The variance of quantum channels involving a mixed state gives a hybrid of
classical and quantum uncertainties. We seek certain decomposition of variance
into classical and quantum parts in terms of the Wigner-Yanase skew
information. Generalizing the uncertainty relations for quantum observables to
quantum channels, we introduce a new quantity with better quantum mechanical
nature to describe the uncertainty relations for quantum channels. We derive
several uncertainty relations for quantum channels via variances and the
Wigner-Yanase skew information.Comment: 11 pages, 1 figur
Parameterized Multi-observable Sum Uncertainty Relations
The uncertainty principle is one of the fundamental features of quantum
mechanics and plays an essential role in quantum information theory. We study
uncertainty relations based on variance for arbitrary finite quantum
observables. We establish a series of parameterized uncertainty relations in
terms of the parameterized norm inequalities, which improve the exiting
variance-based uncertainty relations. The lower bounds of our uncertainty
inequalities are non-zero unless the measured state is the common eigenvector
of all the observables. Detailed examples are provided to illustrate the
tightness of our uncertainty relations.Comment: 12 pages, 3 figure
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Anodic electrochemistry of mono- and dinuclear aminophenylferrocene and diphenylaminoferrocene complexes
Two related three-membered series of nonlinear aminophenylferrocene and diphenylaminoferrocene
complexes were prepared and characterized by 1H and 13C NMR spectroscopy. The first series consists of
4-(diphenylamino)phenylferrocene (TPA-Fc, 1a), its dimethoxy-substituted tetraphenylphenylenediamine
derivative (M2TPPD-Fc, 1c), and the triphenylamine-bridged bis(ferrocenyl) complex (Fc-TPA-Fc, 1b). The
second series involves bis(4-methoxyphenyl)aminoferrocene (M2DPA-Fc, 1d), 4-methoxyphenylaminoferrocene
(MPA-Fc) with N-phenyl-appended terminal TPA (1e), and the corresponding bis(MPA-Fc)
complex with bridging TPA (1f). The structure of complex 1d was further confirmed by single crystal X-ray
diffraction. Combined investigations, based on anodic voltammetry, UV-vis-NIR spectroelectrochemistry
and density functional theory (DFT) calculations, were conducted to illustrate the influence of the integration
of multiple redox-active components on the sequential oxidation of these complexes. The first
anodic steps in 1aâ1f are localized preferentially on the ferrocenyl units, followed by oxidation of the TPA
or TPPD moieties (absent in 1d). Irreversible oxidation of the ferrocene-appended strong donor DPA/MPA
units in 1dâ1f terminates the anodic series. The one-electron oxidation of the triphenylamine-bridged
diferrocenyl (1b) and bis(phenylaminoferrocenyl) (1f) complexes triggers their facile redox disproportionation
to dicationic bis(ferrocenium) product
Theoretical calculations of proton emission half-lives based on a deformed Gamow-like model
In the present study, proton emission half-lives have been investigated for
the deformed proton emitters with in the deformed Gamow-like
model, where the deformation effect has been included in the Coulomb potential.
The experimental half-lives of proton emitters can be reproduced within a
factor of 3.45. For comparison, other results from the universal decay law and
the new Geiger-Nuttall law are presented as well. Furthermore, the relevance of
the half-lives to the angular momentum for La, Pr,
Tb and Ho has been analyzed, and corresponding possible values
of has been put forward: 3, 3, 4, 4
Effects of grafting on the morphology, physiology, and aerenchyma of balsam pear aboveground under waterlogging stress
The effects of grafting on the morphology, physiology, and aerenchyma of balsam pear aboveground under waterlogging stress were studied using a two-factor randomized block design. At 8 and 16Â days, the degree of reduction of grafted balsam pear was lower than those of self-rooted balsam pear, although the height and leaf number of self-rooted and grafted balsam pears were remarkably reduced under waterlogging stress. Compared with self-rooted balsam pear, grafting considerably decreased the malondialdehyde content of balsam pear leaves but substantially increased the activities of antioxidant enzymes (superoxide dismutase, peroxidase, and catalase) and the contents of osmosis-regulating substances (soluble sugar, soluble protein, and proline) in the leaves of balsam pear under waterlogging stress at 4, 8, and 16Â days. The stem of grafted balsam pear formed aerenchyma (pith cavity) at 0 days, whereas the stem of self-rooted balsam pear formed aerenchyma at 4Â days. The aerenchyma of the stem formed by grafted balsam pear was more developed than that formed by the self-rooted balsam pear under waterlogging stress. The petiole of self-rooted and grafted balsam pears formed aerenchyma at 16 days, and the aerenchyma of grafted balsam pear was more developed than that of self-rooted balsam pear. These results indicated that grafting improved the antioxidant and osmotic regulation ability of balsam pear and enhanced the tolerance of balsam pear to waterlogging stress by enlarging the pith cavity of the stem and petiole of balsam pear
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