1 research outputs found
Rapid Dye Adsorption via Surface Modification of TiO<sub>2</sub> Photoanodes for Dye-Sensitized Solar Cells
A facile method for increasing the
reaction rate of dye adsorption,
which is the most time-consuming step in the production of dye-sensitized
solar cells (DSSCs), was developed. Treatment of a TiO<sub>2</sub> photoanode with aqueous nitric acid solution (pH 1) remarkably reduced
the reaction time required to anchor a carboxylate anion of the dye
onto the TiO<sub>2</sub> nanoparticle surface. After optimization
of the reaction conditions, the dye adsorption process became 18 times
faster than that of the conventional adsorption method. We studied
the influence of the nitric acid treatment on the properties of TiO<sub>2</sub> nanostructures, binding modes of the dye, and adsorption
kinetics, and found that the reaction rate improved via the synergistic
effects of the following: (1) electrostatic attraction between the
positively charged TiO<sub>2</sub> surface and ruthenium anion increases
the collision frequency between the adsorbent and the anchoring group
of the dye; (2) the weak anchoring affinity of NO<sub>3</sub><sup>–</sup> in nitric acid with metal oxides enables the rapid
coordination of an anionic dye with the metal oxide; and (3) sufficient
acidity of the nitric acid solution effectively increases the positive
charge density on the TiO<sub>2</sub> surface without degrading or
transforming the TiO<sub>2</sub> nanostructure. These results demonstrate
the developed method is effective for reducing the overall fabrication
time without sacrificing the performance and long-term stability of
DSSCs