29 research outputs found
Collective Charge Fluctuations in Single-Electron Processes on Nano-Networks
Using numerical modeling we study emergence of structure and
structure-related nonlinear conduction properties in the self-assembled
nanoparticle films. Particularly, we show how different nanoparticle networks
emerge within assembly processes with molecular bio-recognition binding. We
then simulate the charge transport under voltage bias via single-electron
tunnelings through the junctions between nanoparticles on such type of
networks. We show how the regular nanoparticle array and topologically
inhomogeneous nanonetworks affect the charge transport. We find long-range
correlations in the time series of charge fluctuation at individual
nanoparticles and of flow along the junctions within the network. These
correlations explain the occurrence of a large nonlinearity in the simulated
and experimentally measured current-voltage characteristics and non-Gaussian
fluctuations of the current at the electrode.Comment: 10 pages, 7 figure
Transport Processes on Homogeneous Planar Graphs with Scale-Free Loops
We consider the role of network geometry in two types of diffusion processes:
transport of constant-density information packets with queuing on nodes, and
constant voltage-driven tunneling of electrons. The underlying network is a
homogeneous graph with scale-free distribution of loops, which is constrained
to a planar geometry and fixed node connectivity . We determine properties
of noise, flow and return-times statistics for both processes on this graph and
relate the observed differences to the microscopic process details. Our main
findings are: (i) Through the local interaction between packets queuing at the
same node, long-range correlations build up in traffic streams, which are
practically absent in the case of electron transport; (ii) Noise fluctuations
in the number of packets and in the number of tunnelings recorded at each node
appear to obey the scaling laws in two distinct universality classes; (iii) The
topological inhomogeneity of betweenness plays the key role in the occurrence
of broad distributions of return times and in the dynamic flow. The
maximum-flow spanning trees are characteristic for each process type.Comment: 14 pages, 5 figure
Magnetisation Processes in Geometrically Frustrated Spin Networks with Self-Assembled Cliques
Functional designs of nanostructured materials seek to exploit the potential of complex morphologies and disorder. In this context, the spin dynamics in disordered antiferromagnetic materials present a significant challenge due to induced geometric frustration. Here we analyse the processes of magnetisation reversal driven by an external field in generalised spin networks with higher-order connectivity and antiferromagnetic defects. Using the model in (Tadić et al. Arxiv:1912.02433), we grow nanonetworks with geometrically constrained self-assemblies of simplexes (cliques) of a given size n, and with probability p each simplex possesses a defect edge affecting its binding, leading to a tree-like pattern of defects. The Ising spins are attached to vertices and have ferromagnetic interactions, while antiferromagnetic couplings apply between pairs of spins along each defect edge. Thus, a defect edge induces n − 2 frustrated triangles per n-clique participating in a larger-scale complex. We determine several topological, entropic, and graph-theoretic measures to characterise the structures of these assemblies. Further, we show how the sizes of simplexes building the aggregates with a given pattern of defects affects the magnetisation curves, the length of the domain walls and the shape of the hysteresis loop. The hysteresis shows a sequence of plateaus of fractional magnetisation and multiscale fluctuations in the passage between them. For fully antiferromagnetic interactions, the loop splits into two parts only in mono-disperse assemblies of cliques consisting of an odd number of vertices n. At the same time, remnant magnetisation occurs when n is even, and in poly-disperse assemblies of cliques in the range n ∈ [ 2 , 10 ] . These results shed light on spin dynamics in complex nanomagnetic assemblies in which geometric frustration arises in the interplay of higher-order connectivity and antiferromagnetic interactions