Modelling of Electroluminescence in Polymers Using a Bipolar Charge Transport Model

Electroluminescence (EL) in polymeric materials is thought to occur due to the energy dissipation process from the recombination of opposite polarity charge carriers. It is considered as an indication of storage and transport of charge carriers in cable insulation subject to electrical stresses and may indicate the change in charge movement due to aging or degradation processes. Under ac electric fields, the interaction of opposite polarity charge carriers at the interface of polymer/conductor is enhanced compared with dc conditions, and seems to contribute a lot to the electroluminescence rather than the charge behaviours in the bulk of polymers. The dynamics of charge carriers both at the interface of polymer/conductor and in the bulk of polymers is investigated through a simulation work using a bipolar charge transport model. Figure 1 compares experimental electroluminescence results with simulated data from the recombination of injected charge carriers. The paper will give more details on EL model and comparison under various waveforms and frequencies

A Comparison between Electroluminescence Models and Experimental Results

Electrical insulation ages and degrades until its eventual failure under electrical stress. One cause of this relates to the movement and accumulation of charge within the insulation. The emission of a low level of light from polymeric materials while under electrical stressing occurs before the onset of currently detectable material degradation. This light is known as electroluminescence (EL) and under an ac electric field is thought to relate to the interaction of charge in close proximity to the electrode-polymer interface. Understanding the cause of this light emission gives a very high-resolution method of monitoring charge interaction and its influence on material ageing. A possible cause of this light emission is the bipolar charge recombination theory. This theory involves the injection, trapping and recombination of charge carriers during each half cycle of the applied field [1]. This work compares two models that to simulate the EL emission according to this bipolar charge recombination theory. Model 1 assumes a fixed space charge region and all injected charge is uniformly distributed in this region with charges able to either become trapped or to recombine with opposite polarity charge carriers [2]. This recombination relates directly the excitation needed for the emission of a photon of light as measured in experiments. Model 2 develops on this by accounting for the transport and extraction of charge with an exponential distribution of trap levels rather than a uniform distribution [3]. Figure 1 shows a good correlation between the two models and experimental data. The full paper will describe the models in more detail and present results comparing the simulated and experimental results under various applied waveforms. Model 1 and model 2 both provide a good correlation with experimental data but model 2 allows a greater understanding of the space charge profile in the region close to the electrodes as well as the shape of the conduction current. Further work involves developing these models to support changes in the charge trapping profiles due to material ageing and supporting simulated results with measured conduction current

Macrospin Models of Spin Transfer Dynamics

The current-induced magnetization dynamics of a spin valve are studied using a macrospin (single domain) approximation and numerical solutions of a generalized Landau-Lifshitz-Gilbert equation. For the purpose of quantitative comparison with experiment [Kiselev {\it et al.} Nature {\bf 425}, 380 (2003)], we calculate the resistance and microwave power as a function of current and external field including the effects of anisotropies, damping, spin-transfer torque, thermal fluctuations, spin-pumping, and incomplete absorption of transverse spin current. While many features of experiment appear in the simulations, there are two significant discrepancies: the current dependence of the precession frequency and the presence/absence of a microwave quiet magnetic phase with a distinct magnetoresistance signature. Comparison is made with micromagnetic simulations designed to model the same experiment.Comment: 14 pages, 14 figures. Email [email protected] for a pdf with higher quality figure

Ghana coastal fisheries governance dialogue: developing options for a legal framework for fisheries co-management in Ghana

The Third National Fisheries Governance Dialogue was a direct follow up on the Second National Fisheries Governance Dialogue held in Elmina in April 2012. It was agreed at the Second dialogue that co-management was the way forward for sustaining Ghana’s fisheries and that its success would depend on a supportive legal framework. The two day dialogue meeting consisted of four key presentations focusing on: the current status of fisheries in Ghana; co-management as a fresh approach to fisheries; outcomes from the regional stakeholder consultations on co-management structure; and outcomes from the research on the legal framework. The presentations were followed by four breakout groups that generated ideas for co-management structures for different species namely pelagic fish or Sardinella, near shore demersal, Volta lake, and lagoons and estuaries. Key elements for co-management structures and elements of a co-management legal framework were later identified during plenary discussions

TAP reactor investigation of methane coupling over samarium oxide catalysts

The adsorption and reaction characteristics of a Ba/Sr/Sm2O3 catalyst for methane coupling has been investigated using the TAP (Temporal Analysis of Products) reactor system. Pulsed adsorption experiments using methane, oxygen and krypton at temperatures ranging from 17°C to 800°C show that the transient response of methane is similar to that of Kr and is either not adsorbed, or weakly adsorbed on the catalyst. By contrast, oxygen is strongly adsorbed at temperatures above 500°C which suggests incorporation into the lattice with possible formation of surface anions. Pump-probe experiments in which methane and oxygen are introduced over the catalyst were also performed to investigate the effect of lifetimes of suspected surface intermediates on the relative yields of ethane and ethene. It is shown that the relative yields of both species increase with increasing values of the pulse valve time delay between introduction of the oxygen and methane. An explanation of these results using current knowledge and reasonable speculation of the mechanism is provided

Decay rate and other properties of the positronium negative ion

A new method for detecting the positronium minus ion is described, and the possibility of a long positronium mean free path in a solid is discussed

Radio Observations of the Supernova Remnant Candidate G312.5-3.0

The radio images from the Parkes-MIT-NRAO (PMN) Southern Sky Survey at 4850 MHz have revealed a number of previously unknown radio sources. One such source, G312.5-3.0 (PMN J1421-6415), has been observed using the multi-frequency capabilities of the Australia Telescope Compact Array (ATCA) at frequencies of 1380 MHz and 2378 MHz. Further observations of the source were made using the Molonglo Observatory Synthesis Telescope (MOST) at a frequency of 843 MHz. The source has an angular size of 18 arcmin and has a distinct shell structure. We present the reduced multi-frequency observations of this source and provide a brief argument for its possible identification as a supernova remnant.Comment: 5 pages, 5 figures, Accepted for publication in MNRA

Body Image concerns of Male Rugby Players, with specific focus on Muscularity and Body Fat

Introduction: Despite the high numbers of participants in both rugby league and union, literature on body image of male rugby players is somewhat limited. However researchers have theorized that the exercise adopted by males may reflect different levels of dissatisfaction, especially in activities that require a large body build, or lean aesthetic physique [1]. Therefore, this study aimed to explore the prevalence of body (dis)satisfaction in terms of muscularity and body fat, and secondly to identify areas of the body that require a change (in either increase/decrease in musculature or body fat) to improve body image. Method: A volunteer sample of n = 93 male University Rugby Union and League participants between the ages 18 – 25 years of age were targeted via social media. An online survey was taken using a mixture of multiple choice and Likert scaled questions from an adaptation of the Bodybuilders Image Grid (BIG-O) [2]. Participants identified areas for increased muscularity and areas of the body for body fat changes and statistical analyses used to assess the difference between current and ideal body size. Results: Participants were mostly dissatisfied (49.46%) with their current body image. All participants highlighted at least one muscle group for increased muscularity. 88.44% of participants desired no increase in body fat, whilst 86.41% wished to reduce body fat in at least one area. Pectorals (50.52%), quadriceps (43.01%) and abdominals (34.41%) were the most common areas for increased muscle mass. Main areas targeted for reduced body fat were stomach (86.02%), chest (39.78%) and back (24.73%). Conclusion: Although body image is complex and easily influenced, the majority of participant’s were dissatisfied with their body and desired a reduction in body fat levels and increased muscularity. Recommendations would allow researchers to compare body (dis)satisfaction between those with a performance focus and those focused on societies ideal. Furthermore, to recruit varying rugby playing standards, such as international and club level players and compare if there are differences in body (dis)satisfaction