Nano-droplets deposited in microarrays by femtosecond Ti:sapphire laser-induced forward transfer

The authors present the deposition of nanoscale droplets of Cr using femtosecond Ti:Sapphire Laser-Induced Forward Transfer. Deposits around 300 nm in diameter, significantly smaller than any previously reported, are obtained from a 30 nm thick source film. Deposit size, morphology, and adhesion to a receiver substrate as functions of applied laser fluence are investigated. We show that deposits can be obtained from previously irradiated areas of the source material film with negligible loss of deposition quality, allowing sub-spot size period microarrays to be produced without the need to move the source film

Advancing leadership in sport: Time to 'actually' take the blinkers off?

In a recent article entitled Advancing Leadership in Sport: Time to Take off the Blinkers?’ Cruickshank and Collins presented what they deemed to be a critical analysis of extant leadership research in sport, attempting to establish a rationale for a greater emphasis on both the cognitive and ‘darker’ (i.e., socially undesirable) sides of leadership. The purpose of the present article is to challenge and clarify a number of misrepresentations in the arguments made in the foundation article, and to question some of the resultant recommendations made. Specifically, the present response will focus on Cruickshank and Collins’ (a) lack of specificity regarding the actual ‘dark’ traits they are apparently purporting to be effective leadership traits, (b) the dearth of theoretical and empirical support for their claims relating to the benefits of ‘dark’ leadership (c) misrepresentation of transformational leadership theory, (d) decision to ignore other relevant theoretical frameworks when presenting their arguments, and (e) apparent confirmation bias in the selective use of literature to support their arguments. Leadership research in sport may well benefit from new directions and methodological advancements and on this level we concur with the aims of Cruickshank and Collins’ article. However, we believe their misrepresentations and inappropriate recommendations do little to advance this area of research, and potentially serve to take it backwards not forwards

Development and initial validation of an indirect measure of transformational leadership integrity

An indirect measure of transformational leadership integrity was developed across three studies. In Study 1, the transformational leadership integrity implicit association test (TLI-IAT) was developed and tested with 65 leaders across heterogeneous organizational contexts. Study 2 involved 51 coaches from 18 sports. Results from Studies 1 and 2 supported the construct validity of the instrument, providing evidence of the instrument's convergent and discriminant validity. Study 3 involved 32 coaches and 133 players from six sports. Findings supported the criterion validity of the measure, providing evidence for the instrument's predictive validity. In sum, evidence is presented that supports the TLI-IATs construct and criterion validity. As such, the present research has made significant advancements to the transformational leadership integrity literature and provides researchers with an indirect measure of automatic transformational leadership integrity self-attitudes

NMR analysis of Nile Blue (C. I. Basic Blue 12) and Thionine (C. I. 52000) in solution

The dyes Nile Blue (C. I. Basic Blue 12, NB) and Thionine (C. I. 52000, TH) were examined in both ionic and neutral forms in different solvents using NMR and UV-visible Spectroscopy to firmly establish the structures of the molecules and to assess the nature and extent of their aggregating characteristics. 1H and 13C NMR assignments and chemical shift data were used along with (for NB) nuclear Overhauser effect information enabling a structure for self-assembly to be proposed. In both cases these data were supplemented with variable temperature, dilution and diffusion-based experimental results using 1H NMR spectroscopy thereby enabling the extended aggregate structures to be assessed in terms of the relative strength of self-association and the extent to which extended aggregates could form. Full and detailed solution phase NMR analysis of such dyes, especially the two studied in this context, have either not been widely reported or have not been studied to the depth presented here. The data and their interpretation form an important addition to the analysis of this class of dye compounds and provide additional insight into the effects of self-assembly on the behaviour of such molecules in various solution-phase environments

0103-72.6: A New Oxygen-Rich Supernova Remnant in the Small Magellanic Cloud

0103$-$72.6, the second brightest X-ray supernova remnant (SNR) in the Small Magellanic Cloud (SMC), has been observed with the {\it Chandra X-Ray Observatory}. Our {\it Chandra} observation unambiguously resolves the X-ray emission into a nearly complete, remarkably circular shell surrounding bright clumpy emission in the center of the remnant. The observed X-ray spectrum for the central region is evidently dominated by emission from reverse shock-heated metal-rich ejecta. Elemental abundances in this ejecta material are particularly enhanced in oxygen and neon, while less prominent in the heavier elements Si, S, and Fe. We thus propose that 0103$-$72.6 is a new ``oxygen-rich'' SNR, making it only the second member of the class in the SMC. The outer shell is the limb-brightened, soft X-ray emission from the swept-up SMC interstellar medium. The presence of O-rich ejecta and the SNR's location within an H{\small II} region attest to a massive star core-collapse origin for 0103$-$72.6. The elemental abundance ratios derived from the ejecta suggest an $\sim$18 M$_{\odot}$ progenitor star.Comment: 6 pages (ApJ emulator format), including 5 figures and 2 tables. For high quality Figs.1,2, & 3, contact [email protected]. Accepted by the ApJ Letter

Transformational leader integrity: an investigation of coach social cognition

The majority of psychological research investigating leader integrity has relied on self or other report methods as the primary means of data collection. While such an approach has advanced the literature, due to the theorised deceptive and manipulative nature of leaders lacking in integrity, prominent theorists (Barling, Christie and Turner, 2008) have called for alternative measures that are less prone to socially desirable responding. As no prior research had examined the integrity of sporting leaders, the present thesis began by examining the antecedent cognitive processes of expert football managers. Building upon this exploration, an implicit association test was developed within studies two and three. Results suggest that the instrument is capable of assessing automatic attitudes towards leader integrity, is more sensitive than existing measures, offers support for concurrent and convergent validity, demonstrates good test-retest reliability, good internal consistency, and is a predictor of player reported commitment. In sum, the present research has sought to understand the phenomena of leader integrity from the perspective of social cognition. The result of these investigations is a robust, sensitive, and complimentary measure of leader integrity, which will assist researchers to better understand the processes that underpin leader integrity

Tubulin and Neurofilament Proteins Are Transported Differently in Axons of Chicken Motoneurons

1. We previously showed that actin is transported in an unassembled form with its associated proteins actin depolymerizing factor, cofilin, and profilin. Here we examine the specific activities of radioactively labeled tubulin and neurofilament proteins in subcellular fractions of the chicken sciatic nerve following injection of L-[35S]methionine into the lumbar spinal cord. 2. At intervals of 12 and 20 days after injection, nerves were cut into 1-cm segments and separated into Triton X-100-soluble and particulate fractions. Analysis of the fractions by high-resolution two-dimensional gel electrophoresis, immunoblotting, fluorography, and computer densitometry showed that tubulin was transported as a unimodal wave at a slower average rate (2–2.5 mm/day) than actin (4–5 mm/day). Moreover, the specific activity of soluble tubulin was five times that of its particulate form, indicating that tubulin is transported in a dimeric or small oligomeric form and is assembled into stationary microtubules. 3. Neurofilament triplet proteins were detected only in the particulate fractions and transported at a slower average rate (1 mm/day) than either actin or tubulin. 4. Our results indicate that the tubulin was transported in an unpolymerized form and that the neurofilament proteins were transported in an insoluble, presumably polymerized form

Tubulin and Neurofilament Proteins Are Transported Differently in Axons of Chicken Motoneurons

1. We previously showed that actin is transported in an unassembled form with its associated proteins actin depolymerizing factor, cofilin, and profilin. Here we examine the specific activities of radioactively labeled tubulin and neurofilament proteins in subcellular fractions of the chicken sciatic nerve following injection of L-[35S]methionine into the lumbar spinal cord. 2. At intervals of 12 and 20 days after injection, nerves were cut into 1-cm segments and separated into Triton X-100-soluble and particulate fractions. Analysis of the fractions by high-resolution two-dimensional gel electrophoresis, immunoblotting, fluorography, and computer densitometry showed that tubulin was transported as a unimodal wave at a slower average rate (2–2.5 mm/day) than actin (4–5 mm/day). Moreover, the specific activity of soluble tubulin was five times that of its particulate form, indicating that tubulin is transported in a dimeric or small oligomeric form and is assembled into stationary microtubules. 3. Neurofilament triplet proteins were detected only in the particulate fractions and transported at a slower average rate (1 mm/day) than either actin or tubulin. 4. Our results indicate that the tubulin was transported in an unpolymerized form and that the neurofilament proteins were transported in an insoluble, presumably polymerized form

Empathic and Self-Regulatory Processes Governing Doping Behavior

Evidence associating doping behavior with moral disengagement (MD) has accumulated over recent years. However, to date, research examining links between MD and doping has not considered key theoretically grounded influences and outcomes of MD. As such, there is a need for quantitative research in relevant populations that purposefully examines the explanatory pathways through which MD is thought to operate. Toward this end, the current study examined a conceptually grounded model of doping behavior that incorporated empathy, doping self-regulatory efficacy (SRE), doping MD, anticipated guilt and self-reported doping/doping susceptibility. Participants were specifically recruited to represent four key physical-activity contexts and consisted of team- (n = 195) and individual- (n = 169) sport athletes and hardcore- (n = 125) and corporate- (n = 121) gym exercisers representing both genders (nmale = 371; nfemale = 239); self-reported lifetime prevalence of doping across the sample was 13.6%. Each participant completed questionnaires assessing the aforementioned variables. Structural equation modeling indicated strong support for all study hypotheses. Specifically, we established: (a) empathy and doping SRE negatively predicted reported doping; (b) the predictive effects of empathy and doping SRE on reported doping were mediated by doping MD and anticipated guilt; (c) doping MD positively predicted reported doping; (d) the predictive effects of doping MD on reported doping were partially mediated by anticipated guilt. Substituting self-reported doping for doping susceptibility, multisample analyses then demonstrated these predictive effects were largely invariant between males and females and across the four physical-activity contexts represented. These findings extend current knowledge on a number of levels, and in doing so aid our understanding of key psychosocial processes that may govern doping behavior across key physical-activity contexts

The Physics of Supernova Remnant Blast Waves. I. Kinematics of DEM L71 in the Large Magellanic Cloud

We present the results from Fabry-Perot imaging spectroscopy of the Balmer-dominated supernova remnant DEM L71 (0505-67.9) in the LMC. Spectra extracted from the entire circumference of the blast wave reveal the broad and narrow component H-alpha line emission characteristic of non-radiative shocks in partially neutral gas. The new spectra of DEM L71 include portions of the rim that have not been previously observed. We find that the broad component width varies azimuthally along the edge of DEM L71, ranging from 450+/-60 km/s along the eastern edge to values as high as 985 (+210)(-165) km/s along the faint western edge. In part of the faint northern rim the broad component is not detected, possibly indicating a lower density in these regions and/or a broad component width in excess of 1000 km/s. Between the limits of zero and full electron-ion temperature equilibration at the shock front, the allowed range of shock velocities is 430-560 km/s along the east rim and 700-1250 km/s along other parts of the blast wave. The H-alpha broad-to-narrow flux ratios vary considerably around the remnant, ranging from 0.4 to 0.8. These ratios lie below the values predicted by our shock models. We find that narrow component H-alpha emission from a cosmic ray precursor may be the cause of the discrepancy. The least decelerated portions of the blast wave (i.e., regions excluding the brightest filaments) are well characterized by Sedov models with a kinetic energy E_51= (0.37+/-0.06)*D_50**(5/2), where D_50 is the LMC distance in units of 50 kpc. The corresponding age for DEM L71 is (4360+/-290)*D_50 yr. This is the first time that velocity information from the entire blast wave has been utilized to study the global kinematics of a non-radiative SNR at a known distance.Comment: 21 pages, including 8 postscript figures and 4 tables, LaTeX, accepted to ApJ; see companion pape