237 research outputs found
Charge, Orbital and Magnetic Order in Nd0.5Ca0.5MnO3
In the manganite Nd0.5Ca0.5MnO3, charge ordering occurs at much higher
temperature than the antiferromagnetic order (TCO=250K,TN=160K).
The magnetic behavior of the phase TN<T<TCO is puzzling: its magnetization
and susceptibility are typical of an antiferromagnet while no magnetic order is
detected by neutron diffraction.We have undertaken an extensive study of the
cristallographic, electric and magnetic properties of Nd0.5Ca0.5MnO3 and
established its phase diagram as a function of temperature and magnetic field.
The charge disordered, paramagnetic phase above TCO present ferromagnetic
correlations. An antiferromagnetic CE phase prevails below TN, with complete
charge and orbital ordering. In the intermediate temperature range, charge
ordering occurs while orbital ordering sets in progressively, with no magnetic
order. Strong magnetic fields destroy the charge ordered phases in a fisrt
order transition towards a ferromagnetic state.Comment: 17 pages, 11 Figures to appear in Phys. Rev.
Influence of Nd on the magnetic properties of Nd1-xCaxMnO3
The role played by the Nd ions in the magnetic properties of Nd0.5Ca0.5MnO3
and Nd0.7Ca0.3MnO3 is studied using static magnetization, neutron diffraction
and high frequency (9.4-475GHz) Electron Spin Resonance. We show that the Nd
ions are weakly coupled to the Mn ions via ferromagnetic exchange and are
responsible for the peculiar ferromagnetic resonance observed in the FM phase
of both compounds (ground state below 120K for x=0.3, high field state for
x=0.5). We then use ESR to look for magnetic phase separation in the low field,
CO phase of Nd0.5Ca0.5MnO3. We show that there is no trace of the FM phase
imbedded in the CO phase, contrary to what is observed in La0.5Ca0.5MnO3 or
Pr0.5Sr0.5MnO3.Comment: to be published in phys.Rev.B as a Rapid Com
Structures and Electromagnetic Properties of New Metal-Ordered Manganites; RBaMn_{2}O_{6} (R = Y and Rare Earth Elements)
New metal-ordered manganites RBaMn_{2}O_{6} have been synthesized and
investigated in the structures and electromagnetic properties. RBaMn_{2}O_{6}
can be classified into three groups from the structural and electromagnetic
properties. The first group (R = La, Pr and Nd) has a metallic ferromagnetic
transition, followed by an A-type antiferromagnetic transition in
PrBaMn_{2}O_{6}. The second group (R = Sm, Eu and Gd) exhibits a charge-order
transition, followed by an antiferromagnetic long range ordering. The third
group (R = Tb, Dy and Ho) shows successive three phase transitions, the
structural, charge/orbital-order and magnetic transitions, as observed in
YBaMn_{2}O_{6}. Comparing to the metal-disordered manganites
(R^{3+}_{0.5}A^{2+}_{0.5})MnO_{3}, two remarkable features can be recognized in
RBaMn_{2}O_{6}; (1) relatively high charge-order transition temperature and (2)
the presence of structural transition above the charge-order temperature in the
third group. We propose a possible orbital ordering at the structural
transition, that is a possible freezing of the orbital, charge and spin degrees
of freedom at the independent temperatures in the third group. These features
are closely related to the peculiar structure that the MnO_{2} square-lattice
is sandwiched by the rock-salt layers of two kinds, RO and BaO with extremely
different lattice-sizes.Comment: 5 pages, 4 figures, submitted to J. Phys. Soc. Jp
Electron- and Hole-Doping Effects on -site Ordered NdBaMnO
We have investigated electron- and hole-doping effects on -site ordered
perovskite manganite NdBaMnO, which has the -type (layered)
antiferromagnetic (AFM) ground state. Electrons (holes) are introduced by
partial substitution of Ba (Nd) with Nd (Ba).
Electron-doping generates ferromagnetic (FM) clusters in the -type AFM
matrix. With increasing the electron-doping level, the volume fraction of the
FM phase or the number of the FM clusters is abruptly increasing. In contrast,
the -type AFM phase is robust against the hole-doping, and no FM correlation
is observed in the hole-doped NdBaMnO.Comment: 8 pages, 5 figures, to be published in Journal of the Physical
Society of Japa
A-site Randomness Effect on Structural and Physical Properties of Ba-based Perovskite Manganites
The discovery of novel structural and physical properties in the -site
ordered manganite BaMnO ( = Y and rare earth elements) has
demanded new comprehension about perovskite manganese oxides. In the present
study, the -site disordered form, BaMnO, has been
investigated and compared with both BaMnO and
MnO (: Sr, Ca) in the structures and electromagnetic
properties. BaMnO has a primitive cubic perovskite cell
in the structure and magnetic glassy states are dominant as its ground state,
in contrast to the ordinary disordered MnO (: Sr, Ca).
In Pr-compounds with various degrees of Pr/Ba randomness at the -sites, the
-site disorder gradually suppresses both ferromagnetic and A-type
antiferromagnetic transitions and finally leads to a magnetic glassy state in
PrBaMnO. A peculiar behavior, multi-step magnetization
and resistivity change, has been observed in PrBaMnO.
These properties could be closely related to any spatial heterogeneity caused
by the random distribution of Ba and with much different
ionic radius.Comment: 9 pages, to be published in J. Phys. Soc. Jpn. 73 Aug. (2004
Pressure induced transition from a spin glass to an itinerant ferromagnet in half doped manganite Ln0.5Ba0.5MnO3 (Ln=Sm and Nd) with quenched disorder
The effect of quenched disorder on the multiphase competition has been
investigated by examining the pressure phase diagram of half doped manganite
Ln0.5B0.5MnO3 (Ln = Sm and Nd) with A-site disorders. Sm0.5Ba0.5MnO3, a spin
glass insulator at ambient pressure, switches to a ferromagnetic metal with
increasing pressure, followed by a rapid increase of the ferromagnetic
transition temperature Tc. The rapid increase of Tc was confirmed also for
Nd0.5Ba0.5MnO3. These observations indicate that the unusual suppression of the
multicritical phase boundary in the A-site disordered system, previously
observed as a function of the averaged A-site ionic radius, is essentially
controlled by the pressure and hence the band width. The effect of quenched
disorder is therefore much enhanced with approaching the multicritical region.Comment: 4 pages including 3 figure
Charge and Orbital Ordering and Spin State Transition Driven by Structural Distortion in YBaCo_2O_5
We have investigated electronic structures of antiferromagnetic YBaCo_2O_5
using the local spin-density approximation (LSDA) + U method. The charge and
orbital ordered insulating ground state is correctly obtained with the strong
on-site Coulomb interaction. Co^{2+} and Co^{3+} ions are found to be in the
high spin (HS) and intermediate spin (IS) state, respectively. It is considered
that the tetragonal to orthorhombic structural transition is responsible for
the ordering phenomena and the spin states of Co ions. The large contribution
of the orbital moment to the total magnetic moment indicates that the
spin-orbit coupling is also important in YBaCo_2O_5.Comment: 4 pages including 4 figures, Submitted to Phys. Rev. Let
Specific heat and magnetic measurements in Nd0.5Sr0.5MnO3, Nd0.5Ca0.5MnO3 and Ho0.5Ca0.5MnO3 samples
We studied the magnetization as a function of temperature and magnetic field
in the compounds Nd0.5Sr0.5MnO3, Nd0.5Ca0.5MnO3 and Ho0.5Ca0.5MnO3. It allowed
us to identify the ferromagnetic, antiferromagnetic and charge ordering phases
in each case. The intrinsic magnetic moments of Nd3+ and Ho3+ ions experienced
a short range order at low temperatures. We also did specific heat measurements
with applied magnetic fields between 0 and 9 T and temperatures between 2 and
300 K in all three samples. Close to the charge ordering and ferromagnetic
transition temperatures the specific heat curves showed peaks superposed to the
characteristic response of the lattice oscillations. Below 10 K the specific
heat measurements evidenced a Schottky-like anomaly for all samples. However,
we could not successfully fit the curves to either a two level nor a
distribution of two-level Schottky anomaly. Our results indicated that the peak
temperature of the Schottky anomaly was higher in the compounds with narrower
conduction band.Comment: submitted to PR
An Origin of CMR: Competing Phases and Disorder-Induced Insulator-to-Metal Transition in Manganites
We theoretically explore the mechanism of the colossal magnetoresistance in
manganese oxides by explicitly taking into account the phase competition
between the double-exchange ferromagnetism and the charge-ordered insulator. We
find that quenched disorder causes a drastic change of the multicritical phase
diagram by destroying the charge-ordered state selectively. As a result, there
appears a nontrivial phenomenon of the disorder-induced insulator-to-metal
transition in the multicritical regime. On the contrary, the disorder induces a
highly-insulating state above the transition temperature where charge-ordering
fluctuations are much enhanced. The contrasting effects provide an
understanding of the mechanism of the colossal magnetoresistance. The obtained
scenario is discussed in comparison with other theoretical proposals such as
the polaron theory, the Anderson localization, the multicritical-fluctuation
scenario, and the percolation scenario.Comment: 16 pages, 7 figures, submitted to Wandlitz Days on Magnetism:
Local-Moment Ferromagnets: Unique Properties for Modern Application
Unusual magnetic relaxation behavior in La0.5Ca0.5MnO3 and Nd0.5Sr0.5MnO3
We have carried out a systematic magnetic relaxation study, measured after
applying and switching off a 5 T magnetic field to polycrystalline samples of
La0.5Ca0.5MnO3 and Nd0.5Sr0.5MnO3. The long time logarithmic relaxation rate
(LTLRR), decreased from 10 K to 150 K and increased from 150 K to 195 K in
La0.5Ca0.5MnO3. This change in behavior was found to be related to the complete
suppression of the antiferromagnetic phase above 150 K and in the presence of a
5 T magnetic field. At 195 K, the magnetization first decreased, and after a
few minutes increased slowly as a function of time. Moreover, between 200 K and
245 K, the magnetization increased throughout the measured time span. The
change in the slope of the curves, from negative to positive at about 200 K was
found to be related to the suppression of antiferromagnetic fluctuations in
small magnetic fields. A similar temperature dependence of the LTLRR was found
for the Nd0.5Sr0.5MnO3 sample. However, the temperature where the LTLRR reached
the minimum in Nd0.5Sr0.5MnO3 was lower than that of La0.5Ca0.5MnO3. This
result agrees with the stronger ferromagnetic interactions that exist in
Nd0.5Sr0.5MnO3 in comparison to La0.5Ca0.5MnO3. The above measurements
suggested that the general temperature dependence of the LTLRR and the
underlying physics were mainly independent of the particular charge ordering
system considered. All relaxation curves could be fitted using a logarithmic
law at long times. This slow relaxation was attributed to the coexistence of
ferromagnetic and antiferromagnetic interactions between Mn ions, which
produced a distribution of energy barriers.Comment: Accepted to PRB as a regular article, 10 figures, Scheduled Issue: 01
June 200
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