2 research outputs found
Bonding and Electronic Nature of the Anionic Framework in LaPd<sub>3</sub>S<sub>4</sub>
Double Dirac materials are a topological phase of matter
in which
a non-symmorphic symmetry enforces greater electronic degeneracy than
normally expected – up to eightfold. The cubic palladium bronzes
NaPd3O4 and LaPd3S4 are
built of Pd3X4 (X = O, S) anionic frameworks
that are ionically bonded to A cations (A = Na, La). These materials
were recently identified computationally as harboring eightfold fermions.
Here we report the preparation of single crystals and electronic properties
of LaPd3S4. Measurements down to T = 0.45 K and in magnetic fields up to μ0H = 65 T are consistent with normal Fermi liquid physics
of a Dirac metal in the presence of dilute magnetic impurities. This
interpretation is further confirmed by analysis of specific heat,
magnetization measurements and comparison to density functional theory
(DFT) calculations. Through a bonding analysis of the DFT electronic
structure of NaPd3O4 and LaPd3S4, we identify the origin of the stability of the anionic Pd3X4 framework at higher electron counts for X =
S than X = O, and propose chemical tuning strategies to enable shifting
the 8-fold fermion points to the Fermi level
Dumbbells of Five-Connected Silicon Atoms and Superconductivity in the Binary Silicides MSi<sub>3</sub> (M = Ca, Y, Lu)
The new metastable binary silicides MSi<sub>3</sub> (M
= Ca, Y,
Lu) have been synthesized by high-pressure, high-temperature reactions
at pressures between 12(2) and 15(2) GPa and temperatures from 900(100)
to 1400(150) K. The atomic patterns comprise intricate silicon layers
of condensed molecule-like Si<sub>2</sub> dimers. The alkaline-earth
element adopts the oxidation state +2, while the rare-earth and transition
metals realize +3. All of the compounds exhibit BCS-type superconductivity
with weak electron–phonon coupling below critical temperatures
of up to 7 K