2 research outputs found
N-(2-Bromobenzyl)cinchoninium bromide
The title compound {systematic name: 1-(2-bromobenzyl)-5-
ethenyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azabicyclo[2.2.2]-
octan-1-ium bromide}, C
26
H
28
BrN
2
O
+
Br
, is a chiral quater-
nary ammonium salt of one of the
Cinchona
alkaloids. The
planes of the quinoline and of the bromobenzyl substituent
are inclined to one another by 9.11 (9)
. A weak intra-
molecular C—H
O hydrogen bond occurs. The crystal
structure features strong O—H
Br hydrogen bonds and
weak C—H
Br interactions.The title compound {systematic name: 1-(2-bromobenzyl)-5-ethenyl-2-[hydroxy(quinolin-4-yl)methyl]-1-azabicyclo[2.2.2]octan-1-ium bromide}, C26H28BrN2O+·Br-, is a chiral quaternary ammonium salt of one of the Cinchona alkaloids. The planes of the quinoline and of the bromobenzyl substituent are inclined to one another by 9.11 (9)°. A weak intramolecular C-H...O hydrogen bond occurs. The crystal structure features strong O-H...Br hydrogen bonds and weak C-H...Br interactions