Amorphous crystalline silicon heterojunction solar cells with black silicon texture

Excellent passivation of black silicon surfaces by thin amorphous silicon layers deposited with plasma enhanced chemical vapor deposition is demonstrated. Minority charge carrier lifetimes of 1.3 milliseconds, enabling an implied open circuit voltage of 714 mV, were achieved. The influence of amorphous silicon parasitic epitaxial growth and thickness, as well as of the texture depth is investigated. Furthermore quantum efficiency gains for wavelenghts above 600 ,nm, as compared to random textured solar cells, are demonstrated in 17.2 efficient amorphous crystalline silicon heterojunction solar cells with black silicon textur

In system photoelectron spectroscopy study of tin oxide layers produced from tetrakis dimethylamino tin by plasma enhanced atomic layer deposition

Tin oxide SnO2 layers were deposited using plasma enhanced atomic layer deposition with tetrakis dimethylamino tin precursor and oxygen plasma. The deposited layers were analyzed by spectral ellipsometry, conductivity measurements, and in system photoelectron spectroscopy. Within a deposition temperature range of 90 210 amp; 8201; C, the resistivity of the SnO2 layers decreases by 5 orders of magnitude with increasing deposition temperature. At the same time, the refractive index at 632.8 amp; 8201;nm increases from 1.7 to 1.9. These changes in bulk layer properties are connected to results from photoelectron spectroscopy. It is found that decreasing carbon and nitrogen contaminations in the tin oxide layers lead to decreasing optical band gaps and increasing refractive index. Additionally, for the deposited SnO2 layers, a shoulder in the O 1s core level spectrum is observed that decreases with the deposition temperature and thus is proposed to be related to hydroxyl group

A Review of Brittleness Index Correlations for Unconventional Tight and Ultra-Tight Reservoirs

Brittleness is a key parameter in the development of the unconventional shale and tight carbonate reservoirs as it plays a role in the design of the hydraulic fractures as well as the selection of the sweet-spot locations for perforation and fracture initiation. The brittleness index (BI) is utilized to indicate if the formation rocks are brittle, which are preferable to form a complex network of fractures, or ductile, which are occasionally desirable to seal the fractures from growing. However, there is a wide variety of BI methods in the literature that lead to inconclusive BI values. The Mineral-based brittleness index (MBI), which is a method based on the mineral composition of the formation, can be derived from mineral well logging data or laboratory core testing. Another approach in describing the brittleness is the Fracability Index (FI), which is a combination of Young’s modulus and Poisson’s ratio. Differentiation is also made between the dynamic FI, which is calculated from well logging data, and the static FI, which is derived from laboratory core testing such as uniaxial compressive strength, Brazilian tensile strength and triaxial testing. Hence, to understand the complexity of the brittleness, it is crucial to consider all dependencies such as the lithology, mineral composition, TOC, porosity, temperature and pressure amongst others. In this work, a comprehensive review and analysis of the existing equations and correlations for the calculation of the MBI and FI was conducted. These methods were applied on different low porosity and low permeability rocks. A thorough comparison has also been conducted between the MBI and FI correlations as well as between the dynamic FI and the static FI to ultimately clarify and improve the definition of brittleness as a function of lithology. High content of quartz and carbonates result in high values of MBI, and high Young’s modulus values yield high FI values. On the other hand, high clay content and high porosity lead to low MBI values